• Title/Summary/Keyword: maximum absorption

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Photocatalytic and Adsorption Properties of WO3 Nanorods Prepared by Hydrothermal Synthesis (수열합성법으로 제조된 나노막대 구조 WO3의 광촉매 효과 및 염료 흡착 반응)

  • Yu, Su-Yeol;Nam, Chunghee
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.483-488
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    • 2017
  • Transition-metal oxide semiconductors have various band gaps. Therefore, many studies have been conducted in various application fields. Among these, methods for the adsorption of organic dyes and utilization of photocatalytic properties have been developed using various metal oxides. In this study, the adsorption and photocatalytic effects of $WO_3$ nanomaterials prepared by hydrothermal synthesis are investigated, with citric acid added in the hydrothermal process as a structure-directing agent. The nanostructures of $WO_3$ are studied using transmission electron microscopy and scanning electron microscopy images. The crystal structure is investigated using X-ray diffraction patterns, and the changes in the dye concentrations adsorbed on $WO_3$ nanorods are measured with a UV-visible absorption spectrophotometer based on Beer-Lambert's law. The methylene blue (MB) dye solution is subjected to acid or base conditions to monitor the change in the maximum adsorption amount in relation to the pH. The maximum adsorption capacity is observed at pH 3. In addition to the dye adsorption, UV irradiation is carried out to investigate the decomposition of the MB dye as a result of photocatalytic effects. Significant photocatalytic properties are observed and compared with the adsorption effects for dye removal.

P3HT:PCBM-based on Polymer Photovoltaic Cells with PEDOT:PSS-pentacene as a Hole Conducting Layer

  • Kim, Hyun-Soo;Hwang, Jong-Won;Park, Su-Jin;Chae, Hyun-Hee;Choe, Young-Son
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.313-313
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    • 2010
  • The performance of polymer photovoltaic cells based on blends of poly(3-hexylyhiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) is strongly influenced by blend composition and thickness. Polymer photovoltaic cells based on bulk-heterojunction have been fabricated with a structure of ITO/poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)-pentacene/poly (3-hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM)/Al. We have prepared PEDOT:PSS by dissolving pentacene in N-methylpyrrolidine (NMP) and mixing with PEDOT:PSS. Pentacene was added a maximum concentration of approximately 5.5mg to the PEDOT:PSS solution and sonicated for 10 min. Active layer (P3HT:PCBM) (1:1) was strongly influenced by PEDOT:PSS-pentacene. We have investigated the performance of photovoltaic device with different concentration of P3HT:PCBM (1:1) 2.0wt%, 2.2wt%, 2.4wt% and 2.6wt%, respectively. The photocurrent and power conversion efficiency (PCE) showed a maximum between 2.0wt% and 2.2wt% concentration of P3HT:PCBM. This implied that both morphology and electron transport properties of the layer influenced the performance of the present photovoltaic cells. As the concentration of P3HT:PCBM blends as an active layer was increased, the power conversion efficiency was decreased. P3HT:PCBM layer and PEDOT:PSS-pentacene layer were characterized by work function, UV-visible absorption, atomic force microscopy (AFM), X-ray diffraction (XRD) and scanning electron microscope (SEM).

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Studies on the Bioavailability of Berberine Preparations(II) : Antibacterial Activity and Bioavailability of Coprecipitate of Coptidis Rhizoma and Glycyrrhizae Radix (베르베린 제제의 생체이용율에 관한 연구(II): 황련과 감초 공침물의 항균효과 및 생체이용율)

  • Yang, Jae-Heon;Eun, Jae-Soon;Lee, Nam-Hee
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.185-192
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    • 1995
  • Precipitation reaction occured between berberine in Coptidis Rhizoma and glycyrrhizin in Glycyrrhizae Radix when they were boiled together in aqueous solution and the supernatant solution thus obtained did not show any antibacterial activity which was derived from berberine. The content of berberine in BG and CGP by HPLC analysis were 41.1%, 8.3% respectively. BG was occured mostly at pH 5.0. The solubility of berberine was 0.15%, while that of BG and CGP was 0.07%, 0.12%, respectively. CGP shown more increased antibacterial activity to gram positive bacteria, S. dysenteriae and K. pneumoniae than berberine. The absorption rates of CGP in stomach, duodenum and jejunum of rats were compared with those of Coptidis Rhizoma water extracts (CR), which were increased more than CR. The time required for the maximum serum concentration of berberine from CGP in mice was 90 minutes after oral administration. The maximum serum concentration of berberine from CGP was higher than that from CR. The dissolution of CGP was increased more than berberine and BG in both artificial gastric and intestinal fluids. The dissolution of CGP pill made from gelatin was 63.4% in artificial gastric fluids and that made from CMC was 76.0% in artificial intestinal fluids.

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The Coloration Properties of Alkyl-substituted Anthraquinoid Dyes for Pure Polypropylene Fiber (순수 폴리프로필렌 섬유용 알킬치환 안트라퀴논계 염료의 색상발현 특성)

  • Kim, Tae-Kyeong;Jung, Jong-Suc;Yoon, Seok-Han;Kim, Mi-Kyung;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.6
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    • pp.28-34
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    • 2007
  • The optical and physical properties of alkyl-substituted anthraquinoid dyes were investigated in terms of dyeing of pure polypropylene fiber. The length of alkyl substituents of the dyes did not affect the molar extinction coefficient and maximum absorption wavelength of them. The use of a double-tailed cationic surfactant, didodecyldimethylammonium bromide(DDDMAB), could make the hydrophobic dyes dispersed in water effectively. As the amount of DDDMAB increased, the average particle size of dye dispersion decreased. Maximum color strength of the fabrics was shown in the case that 1.5 molar ratio of DDDMAB was used. As for the fastness properties, commercially acceptable result was obtained in general.

Optical Properties of Poly(N-arylcarbazole-alt-aniline) Copolymers For Polymer Light Emitting Devices

  • Wang, Hui;Ryu, Jeong-Tak;Kim, Yeon-Bo;Kwon, Young-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.55-60
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    • 2006
  • Thermally stable and solution-processable poly(N-arylcarbazole-alt-aniline) copolymers with high structural integrity were synthesized in good yields via palladium-catalyzed polycondensation of aniline with corresponding N-arylcarbazole monomers such as N-(2-ethylhexyloxyphenyl)-3,6-dibromocarbazole,bis[6-bromo-N-(2-ethylhexyloxyphenyl)carbazole-3-yl] and N-(4-(2-ethylhexyl)-3,5-dibromomethylene-phenyl) carbazole, respectively. The optical and electrochemical properties of these copolymers were measured and compared with those of poly(N-alkylcarbazole-alt-aniline) copolymer. All synthesized poly(N-arylcarbazole-alt-aniline) copolymers showed maximum UV-Vis absorption peaks at around 300 nm in THF solution, and exhibited maximum photoluminescence peaks in the blue emission range from 430 to 460 nm. It was also found that poly(N-arylcarbazole-alt-aniline) copolymers had wider band gap energy than poly(N-alkylcarbazole-alt-aniline) copolymer.

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Generation of Real Sea Waves based on Spectral Method and Wave Direction Analysis (스펙트럴 방법에 의한 실해역파 재현 및 파 방향 해석)

  • Lee, Jin-Ho;Choi, Jae-Woong;Kang, Yun-Tae;Ha, Mun-Keun
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.3
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    • pp.212-219
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    • 2005
  • Real sea waves in a towing wave basin have been generated using random periodic motion of the segmented wave makers and the wave reflections of sidewalls. Theoretically, the real sea waves can be described by the superposition of many random oblique waves. This paper introduces numerical real sea wave generation in a rectangular wave basin using spectral method that uses a superposition of orthogonal functions which have to satisfy the Laplace equation. Oblique regular waves, long crested irregular waves and real sea waves were simulated and met the requirement of sidewall wave reflection and wave absorption. MLM (Maximum Likelihood Method) and Spatial Fourier Transform were used in order to obtain propagated wave direction characteristics. The estimated results proved the usefulness of the method and the performances showed reasonable directional patterns comparing with generating patterns.

Characterization of Pigment-Producing Kocuria sp. K70 and the Optimal Conditions for Pigment Production and Physical Stability (색소생성 균주 Kocuria sp. K70의 특징과 색소생성 최적 조건 및 물리적 안정성)

  • Kim, Young-Sook;Park, Jin-Sook
    • KSBB Journal
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    • v.25 no.6
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    • pp.513-519
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    • 2010
  • Marine bacterium producing pigment was isolated from the solar saltern of Mijo-myeon, Namhae, Korea. Based on phenotypic characteristics and 16S rRNA sequence analysis, the strain was identified as Kocuria sp., which produced a yellow pigment. The pigment showed UV absorption maximum at 469nm. The bacterial strain grew well on Marine broth 2216 culture medium. Productivity of the pigment reached the maximum value after 44 hours at $30^{\circ}C$, 2% NaCl and pH 6.0. The pigment was produced best when supplied by 1% lactose as a carbon source and 1% beef extract as a nitrogen source. The result of the color stability study showed that pigment extracted from the strain by ethanol was stable at $-20-25^{\circ}C$ and also showed higher stability over 70% for 14 days in light conditions at $25^{\circ}C$. The pigment extract was also stable for all metal ions tested, except for $FeCl_2$.

An Experimental Study on the Cooling Characteristics of the Liquid Cooling Radiator of the Natural Convection Type by Using the PCM (PCM을 적용한 자연대류형 수냉식 방열기의 냉각특성에 관한 실험적 연구)

  • Sung, Dae-Hoon;Kim, Joung-Ha;Yun, Jae-Ho;Kim, Woo-Seung;Peck, Jong-Hyeon
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.324-329
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    • 2008
  • The liquid cooling effect of a natural convection type radiator by using the PCM has been investigated experimentally. The radiator size is $423{\times}295{\times}83$ mm and PCM container size is $398{\times}270{\times}26$ mm. The objective is elapsed time higher than maximum time to reach for maximum operating temperature of a general liquid cooling radiator. This study, in order to study on the effects of the phase-change phenomenon, carried out the various mass flow rate, input electric power, ambient and melting point of three type PCM. For the above experimental parameter, the melting time was performed about 180/250/560 min at input power 150 W and ambient $30^{\circ}C$ from using the three type PCM(PCM_S1/S2/S3) respectively. Furthermore, the effects of the thermal dissipation was decreased higher input power than lower input power at heating block and melting time of PCM. However, the effects of mass flow rate did not nearly affect of the thermal performance especially.

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Production of Red Pigment from Marine Bacterium Utilizing Colloidal Chitin. (Colloidal Chitin을 자화하는 해양세균으로부터 적색색소의 생산)

  • 류병호;김민정
    • Microbiology and Biotechnology Letters
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    • v.28 no.5
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    • pp.264-269
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    • 2000
  • This study is that of providing a fairly practical practival guide to the use of natural pigment in food industry. A strain isolated from marine resources was carried out the production of red pigment. The pigment showed UV absorption maxima at 520 and 550 nm. The color intensity in aqueous solution was fairly stable in the ranges of pH 5~8. The strain KS-97 produced a maximum yield of red pigment at$ 25^{\circ}C$ for 72 hrs with pH 7.0. The strain KS-97 was iden-tified a Bacillus sp. based on morphological and biochemical characterization such as a rod from, motility, spore for-mation, Gram positive and catalase production. The production of red pigment indicated that the strain Ks-97 utilized at thigh concentration of colloidal chitin as carbon sources obtained maximum yield of red pigment at $25^{\circ}C$ for 72 hrs. The highest production of red pigment was observed with cultivation in medium containing 20% colloi-dal chitin, 2.5g polypeptone, 2.5g yeast extract, 1.0g $KH_2$$PO_4$, 0.01g $MgSO_4$.$6H_2$O, 0.01g $ZnSO_4$, 0.01 g $MnSO_4$(per 1).

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Extensive investigations of photon interaction properties for ZnxTe100- x alloys

  • Singh, Harinder;Sharma, Jeewan;Singh, Tejbir
    • Nuclear Engineering and Technology
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    • v.50 no.8
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    • pp.1364-1371
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    • 2018
  • An extensive investigation of photon interaction properties has been made for $Zn_xTe_{100-x}$ alloys (where x = 5, 20, 30, 40, 50) to explore its possible use in sensing and shielding gamma radiations. The results show better and stable response of ZnTe alloys for various photon interaction properties over the wide energy range, with an additional benefit of ease in fabrication due to lower melting points of Zn and Te. Mass attenuation coefficient values show strong dependence on photon energy as well as composition. Effective atomic number has maximum value for $Zn_5Te_{95}$ and lowest for $Zn_{50}Te_{50}$ in the entire energy region. The alloy sample with maximum $Z_{eff}$ shows minimal value of $N_e$ and vice versa. Mean free path follows inverse trend as observed for mass attenuation coefficient. The exposure and energy absorption buildup factors depend upon photon energy, penetration thickness and composition (effective atomic number) of $Zn_xTe_{100-x}$ alloys. It finds its application for sensing and shielding from highly energetic and highly penetrating photons at sites where radioactive materials were used and visibility of material is not a big constraint. Further, energy down conversion property of ZnTe alloys with subsequent emission in green band suggests its potential use in sensing gamma photons.