• Title/Summary/Keyword: matrix modification

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Modification of Hydroxyapatite/gelatin Nanocomposite with the Addition of Chondroitin Sulfate

  • Chang, Myung-Chul
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.573-578
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    • 2008
  • In the preparation of hydroxyapatite(HAp)/gelatin(GEL) nanocomposite, GEL matrix was modified by the introduction of chondroitin sulfate(ChS) to obtain a strongly organized composite body. The formation reaction of the HAp/GEL-ChS nanocomposite was then investigated via XRD, DT/TGA, FT-IR, TEM and SEM. The organic-inorganic interaction between HAp nanocrystallites and GEL molecules was confirmed from DT/TGA and FT-IR. According to the DT/TGA results, the exothermal temperature zone between 300 and $550^{\circ}C$ showed an additional peak temperature that indicated the decomposition of the combined organics of the GEL and ChS. From the FT-IR analysis, calcium phosphate(Ca-P) was covalently bound with the GEL macromolecules modified by ChS. From TEM and ED, the matrix of the GEL-ChS molecules was mineralized by HAp nanocrystallites and the dense dried nanocomposite body was confirmed from SEM micrographs.

Modification of the Reference Signal for Fast Convergence in LMS-based Adaptive Equalizers (LMS 기반 적응 등화기에서 빠른 수렴을 위한 기준신호 변형)

  • 이기헌;최진호;박래홍;송익호;박재혁;이병욱
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.19 no.5
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    • pp.939-951
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    • 1994
  • In adaptive equalizers based on least mean squares (LMS) algorithms, the convergence rate is determined by the convariance matrix of an input signal. When the eigenvalue spread of the convariance matrix is close to unity, the convergence rate is quite fast. In this paper, for fast convergence of LMS-based adaptive equalizers we propose a modified reference signal pertinent to the statistical channel. From the theoretical analysis and computer simulation, it is shown that the proposed modification method is quite effective for fast convergence of LMS-based adaptive equalizers.

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Evaluation of performance and seismic parameters of eccentrically braced frames equipped with dual vertical links

  • Mohsenian, Vahid;Nikkhoo, Ali
    • Structural Engineering and Mechanics
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    • v.69 no.6
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    • pp.591-605
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    • 2019
  • Investigations on seismic performance of eccentrically braced frames equipped with dual vertical links have received little attention. Therefore, the main goal of this paper is to describe design steps for such frames and evaluate nonlinear performance of this system according to the reliability analysis. In this study, four and eight story frame structures are analyzed and the response modification factors for different intensity and damage levels are derived in a matrix form based on a new approach. According to the obtained results, the system has high ductility and acceptable seismic performance. Moreover, it is concluded that using response modification factor equal to 8 in the design of system provides desirable seismic reliability under the design and maximum probable hazard levels. Due to desirable performance and significant advantages of the dual vertical links, this system can be used as a main lateral load bearing system, in addition to its application for rehabilitation of damaged structures.

Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

Modification of Hydroxyapatite-gelatin Nanocomposite using Side Group Reaction of Ca2+-RCOO-

  • Chang, Myung-Chul;Yang, Hae-Kwon
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.72-77
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    • 2012
  • In the preparation of a hydroxyapatite [HAp]/gelatin [GEL] nanocomposite, the GEL matrix in aqueous solution of $H_3PO_4$ was modified by the introduction of aspartic acid [Asp], asparagine [Asn], and glycine [Gly]. The addition of Asp, Asn and Gly greatly affected the slurry formation of HAp/GEL nanocomposite and the resulting dry body showed variations in toughness with the addition of the different amino acids. The introduction of Asn into HAp/GEL nanocomposite was effective for producing the organic-inorganic interaction between HAp and GEL, and caused the increase of toughness. The formation reaction of the modified HAP/GEL nanocomposites was investigated by using XRD and FT-IR. The organic-organic interaction between the GEL matrix and the additives of Asp, Asn and Gly was confirmed from FT-IR analysis, and the organic-inorganic interaction between HAp nanocrystallites and the modified GEL matrix was also discussed, using FT-IR spectra patterns. Nanocrystallites of HAp were covalently bound with the GEL macromolecules and differently influenced by the modification species of Asp, Asn, and Gly.

Surface Modification of Polyester by UV-irradiation with Oxidizing Agent, and Its Adhesion Property (자외선/산화제 처리에 의한 폴리에스테르의 표면개질 및 접착성)

  • 최창남;김종배;김상률
    • Textile Coloration and Finishing
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    • v.11 no.4
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    • pp.50-56
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    • 1999
  • The adhesive properties of polyester cord in rubber matrix were investigated according to the surface modification. The polyester cord was oxidized in sodium hypochlorite solution, and graft-polymerized with acrylic acid under the irradiation with ultraviolet light, and then coated with resorcinol-formaldehyde latex (RFL). The modified surface was checked with scanning electron microscope. The adhesive properties were measured by the full-Out method, and evaluated with regard to the energy of adhesion and the maximum load. The polyester was not oxidized in sodium hypochlorite solution, so the surface was not able to etch to produce the coarse topology. As the concentration of acrylic acid and the reaction time were increased, the graft yields were also increased. It was considered that the acrylic acid would swell the polyester and diffuse easily to the inner side of substrate. The adhesive properties of polyeser to rubber matrix were affected by the surface condition. Namely, the maximum load was almost same, but the energy of adhesion was rather higher In the polyester grafted with acrylic acid than in control one. We concluded that the flexible aliphatic chains of polyacrylic acid situated in the interface of cord and rubber matrix were distributed well the stress and strain all over the filler resulting the high energy of adhesion.

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A Computational Modification on EDMC Control Algorithm

  • Haeri, Mohammad;Beik, Hossein Zadehmorshed
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.444-447
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    • 2004
  • A new approach to compute the control moves in Extended Dynamic Matrix Control (EDMC) is presented. In this approach, the number of variables, determined in the inner loop of the control algorithm using iterative methods, is reduced from P , the prediction horizon to M , the control horizon. Since M is usually much smaller than P , this modifies the control algorithm from computational point of view. To justify the modification, the computational requirements are compared to those of the existing EDMC algorithm.

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Tribological Property of Surface Modified Carbon Nanotube Reinforced Polymer Matrix Composites (표면 개질화된 탄소나노튜브 강화 고분자 복합재료의 마모 특성)

  • Park, Joo-Hyuk;Abu Bakar, Sulong
    • Tribology and Lubricants
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    • v.21 no.6
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    • pp.302-305
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    • 2005
  • Various carbon nanotubes (CNTs) are added into the epoxy matrix as reinforcements to investigate the effect on the wear behavior. Effects to the tribological properties of different loading concentrations and types of surface modification are investigated by using a linear reciprocal wear tester. As increasing the concentration of CNTs shows the reduction of the wear loss. Moreover, surface modified CNTs give better tribological property than as produced CNTs. It is due that the functional groups on the surface of CNTs increase the interfacial bonding between CNTs and epoxy matrix through chemical bonding. Changes in worn surface morphology are observed by optical microscope and SEM to investigate the wear behavior. CNTs in the epoxy matrix near the surface are exposed and it becomes the lubricating working film on the worn surface. It reduces the friction and results in the lower surface roughness morphology in the epoxy matrix as increasing the contents of the CNTs.

An Affordable Implementation of Kalman Filter by Eliminating the Explicit Temporal Evolution of the Background Error Covariance Matrix (칼만필터의 자료동화 활용을 위한 배경오차 공분산의 명시적 시간 진전 제거)

  • Lim, Gyu-Ho;Suh, Ae-Sook;Ha, Ji-Hyun
    • Atmosphere
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    • v.23 no.1
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    • pp.33-37
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    • 2013
  • In meteorology, exploitation of Kalman filter as a data assimilation system is virtually impossible due to simultaneous requirements of adjoint model and large computer resource. The other substitute of utilizing ensemble Kalman filter is only affordable by compensating an enormous usage of computing resource. Furthermore, the latter employs ensemble integration sets for evolving the background error covariance matrix by compensating the dynamical feature of the temporal evolution of weather conditions. We propose a new implementation method that works without the adjoint model by utilizing the explicit expression of the background error covariance matrix in backward evolution. It will also break a barrier in the evolution of the covariance matrix. The method may be applied with a slight modification to the real time assimilation or the retrospective analysis.

An efficient method to structural static reanalysis with deleting support constraints

  • Liu, Haifeng;Yue, Shigang
    • Structural Engineering and Mechanics
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    • v.52 no.6
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    • pp.1121-1134
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    • 2014
  • Structural design is usually an optimization process. Numerous parameters such as the member shapes and sizes, the elasticity modulus of material, the locations of nodes and the support constraints can be selected as design variables. These variables are progressively revised in order to obtain a satisfactory structure. Each modification requires a fresh analysis for the displacements and stresses, and reanalysis can be employed to reduce the computational cost. This paper is focused on static reanalysis problem with modification of deleting some supports. An efficient reanalysis method is proposed. The method makes full use of the initial information and preserves the ease of implementation. Numerical examples show that the calculated results of the proposed method are the identical as those of the direct analysis, while the computational time is remarkably reduced.