• Korean Journal of Materials Research
• /
• v.26 no.4
• /
• pp.173-181
• /
• 2016

In order to use coal tar pitch (CTP) as a raw material for carbon fibers, it should have suitable properties such as a narrow range of softening point, suitable viscosity and uniform optical properties. In this study, raw CTP was modified by heat treatment with three types of polymer additives (PS, PET, and PVC) to make a spinnable pitch for carbon fibers. The yield, softening point, C/H ratio, insoluble yield, and meso-phase content of various modified CTPs with polymer additives were analyzed by changing the type of polymer additive and the heat treatment temperature. The purpose of this study was to compare the properties of CTPs modified by polymer addition with those of a commercial CTP. After the pitch spinning, the obtained green fibers were stabilized and carbonized. The properties of the respective fibers were analyzed to compare their uniformity, diameter change, and mechanical properties. Among three polymer additives, PS220 and PET261 pitches were found to be spinnable, but the carbon fibers from PET261 showed mechanical properties comparable with those of a commercial CTP produced by an air-blowing method (OCI284). The CTPs modified with polymer additive had higher ${\beta}$-resin fractions than the CTP with only thermal treatment indicating a beneficial effect of carbon fiber application.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.20 no.5
• /
• pp.60-69
• /
• 2016

This paper presents a numerical investigation on kerosene-air mixture detonation and behaviors of thermal elasto-plstic thin metal tube under detonation loading based on multi-material analysis. The detonation loading is modeled by the kerosene-air mixture detonation which is compared with Chapman-Jouguet (C-J) condition and experimental cell size. To conform the elasto-plastic model, plastic and elastic behaviors are verified by Taylor impact and plate bending motion, respectively. The numerical results are compared with the theory on burst pressure of tube. The critical deformable thickness with the thermal softening considered is good agreement with the theoretical value.

• Magazine of the Korea Concrete Institute
• /
• v.8 no.3
• /
• pp.187-195
• /
• 1996

A finite element formulation based on the CFT(Compression Field Theory), considering the effect of compression softening in cracked concrete, and macro-scopic and rotating crack models etc., was presented for the nonlinear behaviour of structural concrete. Considering the computational efficency and the ability of modelling the post-ultimate behaviour as major concerns, the Incremental displacement solution algorithm involving initial material stiffnesses and the relaxation procedure for fast convergence was adopted and formulated in a type of 8-noded quadrilateral isoparametric elements. The analysis program NASCOM(Non1inear Analysis of Structural Concrete by FEM : Monotonic Loading) developed in this way enables the predictions of strength and deformation capacities in a full range, crack patterns and their corresponding widths, and yield extents of reinforcement. As the verification purpose of NASCOM, the predictions were made for Bhide's Panel(PB21) and Leonhardt's deep beam tests. The predicted results shows somewhat stiff behaviour for the panel test, and vice versa for deep beam tests. More refining process would be necessary hereafter in terms of more accurately simulating the effects of tension-stiffening and compression softening in concrete.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.16 no.8
• /
• pp.1519-1529
• /
• 1992

A stepped specimen which is subjected to step loading is modeled to study the initiation and growth of adiabatic shear band using explicit time integration finite element code. The material model for specimen includes effects of thermal softening, strain hardening and strain rate hardening. Various mesh sizes are tested to check whether they are small enough to model highly localized discontinuous phenomena reasonably well. It is shown that the number of adiabatic shear band depends on impact velocity and it is also shown that the initiation and growth of adiabatic shear band inversely depends on prescribed velocity at the top of specimen.

• Korean Chemical Engineering Research
• /
• v.59 no.3
• /
• pp.410-416
• /
• 2021

To improve the capacity and stability of natural graphite, the electrochemical performances were investigated by using the prepared natural graphite coated with petroleum pitch for anode materials. The pitch coated natural graphite was prepared using a dry speed mixer by adjusting the rotation speed of the mixer, time, composition of graphite and softening point of the pitch. The physical properties of the anode material were analyzed using SEM, TEM, and PSD. The electrochemical performances were investigated by cycle, C-rate, EIS and CV test. When the pitch coated natural graphite was tested in the condition of 9000 RPM, 10 wt%, 2 h, and softening point of 150 ℃, it showed the highest capacity of 324.5 mAh/g at 0.1 C and a capacity retention rate of 98.9% after 50 cycles. In the test for evaluating rate performance, the capacity retention rate (5 C/0.1 C) was 80.3% and was improved by about 1.7 times over the pristine natural graphite.

• Journal of the Korean Geotechnical Society
• /
• v.22 no.2
• /
• pp.41-53
• /
• 2006

The brittle materials like rocks show complicated strain-softening behavior after the peak which is hard to model using the classical constitutive models based on the relation between strain and stress tensors. A kinematically constrained three-dimensional microplane constitutive model is developed for granite. The model is verified by fitting the experimented data of Westerly granite and Bonnet granite. The triaxial behavior of granite is well reproduced by the model as well as the uniaxial behavior. We studied the development of the fracture zone in granite during blasting impact using the model with the standard finite element method. All the results obtained from the microplane model developed are compared to those from the linear elasticity model which is commonly used in many researches and practices. It is found that the nonlinearity of rocks sigificantly affects the results of analysis.

• International Journal of Highway Engineering
• /
• v.16 no.5
• /
• pp.9-18
• /
• 2014

PURPOSES : The objective of this study is to evaluate the applicability of the pitch, which is produced during SDA petroleum upgrading process, as a pavement paving material. In order for the purpose, the physical and chemical properties of the pitch are analyzed, and then the various plasticizers are applied in the pitch. METHODS : Two types of pitch are selected from oil refinery companies, which are owned the SDA petroleum upgrading process. Also, two types of asphalt binders, PG 64-22 and PG 58-22, are employed to compare with the pitch because these two types of asphalt binders are currently used as paving materials. For the chemical property of the pitch, the composition of SARA (Saturate, Aromatic, Resin, Asphaltene), the elementary composition, and the functional group are analyzed. For the physical property of the pitch, the basic material property tests, such as penetration test, softening point test, flash point test, ductility test, and rotational viscometer test, are performed. Also, the DSR (Dynamic Shear Rheometer) test and the BBR (Bending Beam Rheometer) test are conducted using asphalt binder specimens obtained by both short term aging (Rolling Thin Film Oven, RTFO) and long term aging (Pressure Aging Vessel, PAV) processes. The rheological property of each pitch type is evaluated as a function of temperatures and loading cycles. PG 64-22 asphalt binder is used as a control material. RESULTS AND CONCLUSIONS : The Pitch may not be suitable for the pavement paving material without modifications, but the pitch can be used as alternatives of modified addictive or asphalt. If low molecular component, such as saturate and aromatic components, are added in the pitch based on the development of various plasticizers, it has a strong possibility for the pitch to be used as a alternative. However, in order to verify the performance property of the pitch, further research is needed.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.24 no.6 s.177
• /
• pp.1398-1407
• /
• 2000

The structural steels of power plant show the decrease of mechanical properties due to degradation such as temper embrittlement, creep damage and softening during long-term operation at high temper ature. The typical causes of material degradation damage are the creation and coarsening of carbides(M23C6, M6C) and the segregation of impurities(P, Sb and Sn) to grain boundary. It is also well known that material degradation induces the cleavage fracture and increases the ductile-brittle transition temperature of steels. So, it is very important to evaluate degradation damage to secure the reliable and efficient service condition and to prevent brittle failure in service. However, it would not be appropriate to sample a large test piece from in-service components. Therefore, it is necessary to develop a couple of new approaches to the non-destructive estimation technique which may be applicable to assessing the material degradation of the components with not to influence their essential strength. The purpose of this study is to propose and establish a new electrochemical technique for non-destructive evaluation of material degradation damage for Cr-Mo steels which is widely used in the high temperature structural components. And the electrochemical anodic polarization test results are compared with those of semi-nondestructive SP test.

• Journal of the Society of Naval Architects of Korea
• /
• v.48 no.3
• /
• pp.275-280
• /
• 2011

In the present study, a unified viscoplastic-damage model has been applied in order to describe the mechanical characteristics of fresh water ice such as nonlinear material behavior and volume fraction. The strain softening phenomenon of fresh water ice under quasi-static compressive loading has been evaluated based on unified viscoplastic model. The material degradation such as growth of slip/fraction has quite close relation with material inside damage. The volume fraction phenomenon of fresh water ice has been identified based on volume fraction (nucleation and growth of damage) model. The viscoplastic-damage model has been transformed to the fully implicit formulation and the discretized formulation has been implemented to ABAQUS user defined subroutine (User MATerial: UMAT) for the benefit of application of commercial finite element program. The proposed computational analysis method has been compared to uni-axial compression test of fresh water ice in order to validate the compatibilities, clarities and usefulness.

• Applied Biological Chemistry
• /
• v.47 no.1
• /
• pp.55-60
• /
• 2004

Changes of cell wall components and softening enzyme during the preparation of persimmon pickles with soy sauce and soy paste were investigated. The contents of alcohol insoluble substance and cell wall extracted from persimmon pickles in soy sauce and soy paste were gradually decreased to the 20th day of storage and then decreased rapidly, but the contents of water soluble material extracted from persimmon pickles in soy sauce and soy paste was increased during the storage time $(0{\sim}50\;days)$. The contents of lignin, pectin and acid-soluble hemicellulose of persimmon pickles in soy sauce and soy paste were decreased during the storage, but contents of alkali-soluble hemicellulose was increased. The contents of cellulose almost did not change during storage of pickles. The hardness of persimmon pickles in soy sauce and soy paste was gradually increased up to the 30th day of storage and then decreased. The activities of polygalacturonase and pectinesterase as softening enzyme in persimmon pickles with soy sauce and soy paste increased during storage. And ${\beta}-galactosidase$ activity was slightly increased to the 30th day of storage and after increased rapidly.