• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2003.10a
• /
• pp.217-220
• /
• 2003

The effective thermoelastic properties of porous metals are discussed herein after each material forming process such as hot pressing or extrusion. The voids in metal matrix are assumed to be initially spherical in shape and to be distributed randomly. Once the porous material deforms plastically due to each material forming process, the voids change their shape from a sphere to an ellipsoid and align in one direction. Since the voids are compressible in nature, the void volume fraction is assumed to be decreasing during each material forming process.

• Transactions of the Korean hydrogen and new energy society
• /
• v.8 no.1
• /
• pp.11-21
• /
• 1997

$ZrV_{0.7}Mn_{0.5}Ni_{1.2}$ alloy is attractive for anode material in Ni/MH secondary battery because of its large hydrogen storage capacity in gas-solid reaction and long cycling durability in KOH electrolyte. In this work, in order to further improve the discharge performance of this alloy electrode, the alloy was annealed by optimal condition which is for 12 hours at $1000^{\circ}C$. The alloy annealed under optimal condition had higher rate capability and discharge capacity than as-cast one. The microstructure of the as-cast and annealed alloy was investigated by scanning electron microscopy and energy dispersive spectroscopy. Ni content in the matrix was increased, being this homogenized after annealing. Additionally, The measurement of the surface area by B.E.T. analysis showed that there was little difference as-cast and annealed alloy. Therefore, improvement in the rate capability of the annealed alloy is due to increase of Ni content in the matrix.

• 한국초전도학회:학술대회논문집
• /
• v.10
• /
• pp.230-235
• /
• 2000

The extrusion process for long-length multi-filaments of BSCCO 2223 superconductor tape has been investigated with aids of Finite Element Method and experimental inspection. Since the arrangement of filaments in matrix material has characteristic of rotational symmetry, a 2-dimensional commercial FEM package, DEFORM-2D, was adopted to simulate extrusion process with different variables such as hardness of sheath material, lengths of each filament and arrangement. From the FEM analysis, since the inner filaments move faster than the outer one, distribution of filaments is needed to be optimized. In the case of pure Ag matrix, undesirable non-uniform distribution of filament was obtained due to low hardness of sheath material. Dummy sample(brass (sheath) and talc powder(filament)), however, which has relatively high hardness of sheath material, had been produced with desirable results. Therefore, it is necessary to optimize hardness of sheath material, extrusion temperature and billet design.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.6
• /
• pp.561-565
• /
• 2007

Because of a good wear resistance and a stable contact resistance, Ag-CdO is widely used as electrical contact material. But, the Cd-oxide mainly exists as a coarse particle and adversely affected to environment. As a reason, $Ag-SnO_2$ alloy has been developed. The Sn-oxide maintains stable and fine particle even at high temperature. In order to investigate the effect of Misch metal (Mm) additional that affects the formation of the oxide and the formation of fine matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Mm) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. The Mm addition makes Ag matrix more fine than no Mm addition. The reason is that the addition of Misch metal decreased a latent heat of fusion of alloy, as a result the rapid solidification effect of alloy is increased. The maximum hardness shows at 0.3 wt%Mm. after that the hardness is decreased until 0.4 wt% Mm, but still larger than no Mm addition alloy. At 0.5 wt% Mm alloy, the precipitation of Misch metal causes a decrease of hardness than no Mm addition alloy.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 1994.04a
• /
• pp.57-64
• /
• 1994

The purpose of this paper is to find minimum surface shape of pneumatic structure using the finite element method. The pneumatic membrane structure is a kind of large deformation problem and very flexible composite material, which mean geomatric nonlinearity. It is not to resist for compression and resultant moment. As the displacement due to internal pressure is getting bigger, it should be considered the direction of forces. It becomes non-linear problem with the non-conservative force. The follower-force depends on the deformation and the direction of force is normal to each element. The solution process is obtained the new stiffness matrix (load correction matrix) depending on deformation through each iterated step. However, the stiffness matrix have not the symmetry and influence on the time of covergence. So in this paper Newton-Rhapson method for solving non-linear problem and for using symmetic matrix, the load direction is changed in each iterated step using the transformation matrix.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.05a
• /
• pp.38-41
• /
• 2001

A new 2-D braided textile metal matrix composite was developed and characterized. The constituent materials consist of PAN type carbon fiber as reinforcements and pure aluminum as matrices. The braided preforms of different braider yarn angles were fabricated. For a fixed bundle size of 12K, three braider yarn angles was selected: $30^{\circ}$, $45^{\circ}$, and $60^{\circ}$. The braided preforms were infiltrated with pure Al by vacuum assisted squeeze casting. Through the investigation of melt pressing methods and the effects of process parameters such as applied pressure, and pouring temperature, the optimal process conditions were identified as follows: applied pressure of 60MPa, pouring temperature of $800^{\circ}C$. Using the measured geometric parameters, 3-D engineering constants of metal matrix composites have been determined from the elastic model, which utilizes the coordinate transformation and the averaging of stiffened and compliance constants based upon the volume of each reinforcement and matrix material.

• The Korean Journal of Ceramics
• /
• v.2 no.4
• /
• pp.231-237
• /
• 1996

Mullite ceramics can be sintered by rf plasma sintering to densities as high as 97% compared to the theoretical density of the mullite, while SiC whisker-reinforced mullite matrix ceramic composites were not sintered by plasma sintering. Decomposition of mullite occurs in a superficial regins at the outside surface of the specimen by volatilization of SiO at elevated temperature by plasma. SiC whiskers were destroyed, and the matrix was converted to alumina from SiC-whisker reinforced mullite matrix ceramic composites during the plasma sintering. Accelerated volatilization from the SiC whisker in the mullite prevents sintering. The volatile species are mainly SiC and CO gas species. The effects of plasma on mullite and SiC-whisker reinforced mullite matrix composites are interpreted by thermodynamic simulation of the volatile species in the plasma environment. The thermodynamic results show that the decomposition will not occur during hot pressing.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.11
• /
• pp.1541-1544
• /
• 2002

The concentration of B in steels is important due to its influence on mechanical properties of steel such as hardenability, hot workability, and creep resistance. An analytical method has been developed to determine B in steel samples by high-resolution inductively coupled plasma mass spectrometry (HR-ICP-MS). National Institute of Standard and Technology Standard Reference Material (NIST SRM) 348a was analyzed to validate the analytical method. The steel sample was digested in a centrifuge bottle with addition of aqua regia and $^{10}B$ spike isotope. Sample pH was then adjusted to higher than 10 to precipitate most matrix elements such as Fe, Cr, and Ni. After centrifugation, the supernatant solution was passed through a cation exchange column to enhance the matrix separation efficiency. B recovery efficiency was about 37%, while matrix removal efficiency was higher than 99.9% for major matrix elements. The isotope dilution method was used for quantification and the determined B concentration was in good agreement with the certified value.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2002.10a
• /
• pp.131-134
• /
• 2002

Braided carbon fiber reinforced Al matrix composites were developed and characterized. Braided carbon fiber preforms with braiding angles of $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$ were manufactured by using a braiding machine. The manufactured braided carbon fibers were used as reinforcement to fabricate Al matrix composites by employing a pressure infiltration casting method. In the processing of pressure infiltration casting, important processing parameters such as melting temperature, preheating temperature of preform and applied pressure were optimized. Prediction of elastic constants on composites was performed by using the volume averaging method, which utilizes the coordinate transformation and the averaging of stiffeness and compliance constants based upon the volume of each reinforcement and matrix material. The elastic moduli of composites were evaluated by using Resonant Ultrasound Spectroscopy(RUS) method and compared with the elastic moduli obtained from static tensile test method.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.1
• /
• pp.35-40
• /
• 2010

A comprehensive comparative investigation of small carbohydrates in laser desorption ionization was performed on supporting materials composed of sodiated 2,5-dihydroxybenzoic acid (DHB), carbon nanotubes, an ionic liquid matrix of DHB-pyridine, a binary matrix of DHB-aminopyrazine, zinc oxide nanoparticles, and gold nanoparticles. The abundance of $[M+Na]^+$ ions, where M is glucose or sucrose, was compared for each supporting material. The highest sensitivity for both glucose and sucrose, with a detection limit of 3 pmol, was observed with carbon nanotubes. Both carbon nanotubes and the ionic liquid matrix exhibited the highest reproducibility.