• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.106-111
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• 2008

Polypropylene (PP)/corn starch master batch (starch-MB)/silicate composites with different corn starch compositions of 10, 20, 30, 40 and 50 were prepared by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The content of silicate was fixed at 5 wt%. The composition of starch-MB in composites was confirmed by the existence of hydroxy group and peak intensity in fourier-transform-infrared (FT-IR) spectrum. The thermal properties of the PP/starch-MB/silicate composites were investigated by differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). There was no district change in melting temperature, and TGA curve indicates a decrease in degradation temperature with the increase of starch-MB content. The silicate dispersion of the composites was measured by X-ray diffraction (XRD) and transmission electron microscope (TEM). The degree of silicate dispersion in PP/starch-MB/silicate composites depended on the content of starch-MB. There was detectable change in d-spacing and peak intensity of the composite when the content of starch-MB was higher than 20 wt%. The rheological behavior of the composites was explained by both shear thinning effect and elastic property with the starch-MB amount. These effects were remarkable when the content of starch-MB was higher than 20 wt%. These were confirmed by an oscillatory viscometer at $200^{\circ}C$.

• Polymer(Korea)
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• v.31 no.2
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• pp.98-104
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• 2007

The expansion behavior of polystyrene (PS) chains with various molecular weights has been investigated above Flory $\Theta$temperature by viscometry after dissolving in the three different mixed solvents systems such as benzene/n-heptane, 1,4-dioxane/isopropanol, and 1,4-dioxane/n-heptane. Two different regimes are observed as increasing temperature: one regime is for the expansion of chain and the other is for the contraction. For the higher molecular weight sample of PS, the higher peak temperature showing its maximum expansion is obtained. Within a certain system of Ps/mixed solvents, the $\tau/\tau_c$ parameter shows universality for the variation of molecular weight. But while each system of Ps/mixed solvents has shown its own different slope, the universality breaks down in the overall system of mixed solvents. However after introducing a new empirical $b^{2/3}\tau/\tau_c$ parameter, all data points of three different systems have dropt on one master curve and the universality of chain expansion has recovered again. Here $\tau$ and $\tau_c$ are defined as $(T-\Theta)/\Theta$ and $(\Theta-T_c)/T_c$, respectively and $T_c$ is the critical solution temperature, and b of Schultz-Flory equation is corresponding to the effective slope in the plot of $1/T_c$ against $1/M_w^{1/2}$.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.8
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• pp.480-491
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• 2015

In this study, methods using LDC (Load Duration Curve) and watershed model were suggested to develope management targets and evaluate target achievement for non-point source pollution management considering watershed and runoff characteristics and possibility for achievement of target. These methods were applied for Saemangeum watershed which was designated as nonpoint source pollution management area recently. Flow duration interval of 5 to 40% was selected as flow range for management considering runoff characteristics and TP was selected as indicator for management. Management targets were developed based on scenarios for non-point source pollutant reduction of management priority areas using LDC method and HSPF model which was calibrated using 4 years data (2009~2012). In the scenario of LID, road sweeping and 50% reduction in CSOs and untreated sewage at Jeonju A20 and 30% reduction in fertilizer and 50% in livestock NPS at Mankyung C03, Dongjin A14 and KobuA14, management targets for Mangyung bridge, Dongjin bridge, Jeonju stream and Gunpo bridge were developed as TP 0.38, 0.18, 0.64 and 0.16 mg/L respectively. When TP loads at the target stations were assumed to have been reduced by a certain percentage (10%), management targets for those target stations were developed as TP 0.35, 0.17, 0.60 and 0.15 mg/L respectively. The result of this study is expected to be used as reference material for management master plan, implementation plan and implementation assessment for non-point source management area.