• Title/Summary/Keyword: mass transfer effect

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Effect of Partial Flow Reductions on DNAPL Source Dissolution Rate

  • Park, Eung-Yu;ParKer, Jeck C.
    • Proceedings of the KSEEG Conference
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    • 2005.04a
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    • pp.148-151
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    • 2005
  • Field-scale DNAPL dissolution is controlled by the topology of DNAPL distributions with respect to the velocity field. A high resolution percolation model was developed and employed to simulate the distribution of DNAPL within source zones. Statistically anisotropic permeability values and capillary parameters were generated for 10${\times}$10${\times}$10 m domains at a resolution of 0.05 to 0.1 m for various statistical properties. TCE leakage was simulated at various rates and the distribution of residual DNAPL in 'fingers' and 'lenses' was computed. Variations in finger and lens geometries, frequencies, average DNAPL saturations, and overall source topology were predicted to be strongly influenced by statistical properties of the medium as well as by injection rate and fluid properties. Model results were found to be consistent with observations from controlled DNAPL release experiments reported in the literature. The computed distributions of aquifer properties and DNAPL were utilized to perform high-resolution numerical simulations of groundwater flow and dissolved transport. Simulations were performed to assess the effect of grout or foam injection in bore holes within the source zone and of shallow point-releases of fluids with various properties on dissolution in DNAPL dissolution rate, even for widely spaced injection points. The results indicate that measures that induced partial flow reductions through DNAPL source zones can significantly decrease dissolution rates from residual DNAPL. The benefit from induced partial flow reductions is two-fold: 1) local flow reduction in DNAPL contaminated zones reduces mass transfer rates, and 2) contaminant flux reductions occur due to the decrease in groundwater velocity

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Ammonia Removal Model Based on the Equilibrium and Mass Transfer Principles

  • Yoon, Hyein;Lim, Ji-Hye;Chung, Hyung-Keun
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.555-561
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    • 2008
  • In air stripping of ammonia from the aqueous solution, a new removal model was presented considering the equilibrium principles for the ammonia in aqueous solution and between the aqueous and air phase. The effects of pH, temperature and airflow rate on the ammonia removal were evaluated with the model. In addition, the saturation degree of ammonia in air was defined and used to evaluate the effect of each experimental factor on the removal rate. As pH (8.9 to 11.9) or temperature (20 to 50 oC) was increased, the overall removal rate constants in all cases were appeared to be increased. Our presented model shows that the degrees of saturation were about the same (0.45) in all cases when the airflow condition remains the same. This result indicates that the effect of pH and temperature were directly taken into consideration in the model equation. As the airflow increases, the overall removal rate constants were increased in all cases as expected. However, the saturation degree was exponentially decreased with increasing the airflow rate in the air phase (or above-surface) aeration. In the subsurface aeration the saturation degree remains a constant value of 0.65 even though the airflow rate was increased. These results indicate that the degree of saturation is affected mainly by the turbulence of the aqueous solution and remains the same above a certain airflow rate.

A Study on Characteristics of Driver's Visual Time-varying on the Message Disply Form (VMS 표출형태별 운전자 주시시간 특성에 관한 연구)

  • Kim, Myung Soo
    • International Journal of Highway Engineering
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    • v.15 no.1
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    • pp.163-169
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    • 2013
  • PURPOSES: The urban traffic problems can be defined as general problems for smooth traffic flow including maintenance of mass transportation system according to suddenly increased population, traffic regulations for vehicles and pollution problem. As a method for solving traffic jams, one of the traffic problems of late, interest in Intelligent Traffic System(ITS) is increasing sharply, which is a system managing traffic demand by providing passers with information on traffic state of path and road conditions before they pass the road through ATIS, a field of ITS. METHODS: Variable message signs(VMS) is used on the roads as a method for providing information to promote smooth traffic flow and safety and prevent traffic accidents in advance by providing drivers with various information while driving. RESULTS: Recently, as ITS industry has been vitalized and technical factors of VMS have developed, various kinds of information is provided but the effect of VMS has not been maximized due to its limited type. CONCLUSIONS: Therefore, this study intends to provide methods for effective information transfer by analyzing driver's visual behavior characteristics for VMS and presenting a basis for maximizing VMS effect after considering read by expression type.

Numerical Simulation of the Oscillating Flow Effect in the Channel of Polymer Electrolyte Membrane Fuel Cell (왕복 유동을 통한 확산증대 효과가 연료전지 성능에 미치는 영향에 대한 수치해석)

  • Kim, Jongmin;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.20 no.4
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    • pp.7-13
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    • 2018
  • This study investigates the enhancement of the oxygen diffusion rate in the cathode channel of a proton exchange membrane fuel cell (PEMFC) by pure oscillating flow, which is the same as the mechanism of human breathe. Three-dimensional numerical simulation, which has the full model of the fuel cell including electrochemical reaction, ion and electronic conduction, mass transfer and thermal variation and so on, is performed to show the phenomena in the channel at the case of a steady state. This model could analysis the oscillating flow as a moving mesh calculation coupled with electrochemical reaction on the catalyst layer, however, it needs a lot of calculation time for each case. The two dimensional numerical simulation has carried on for the study of oscillating flow effect in the cathode channel of PEMFC in order to reduce the calculation time. This study shows the diffusion rate of the oxygen increased and the emission rate of the water vapor increased in the channel by oscillating flow without any forced flow.

Mathematical modeling of the local temperature effect on the deformation of the heat-shielding elements of the aircraft

  • Antufiev, Boris A.;Sun, Ying;Egorova, Olga V.;Bugaev, Nikolay M.
    • Advances in aircraft and spacecraft science
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    • v.9 no.1
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    • pp.59-68
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    • 2022
  • The physical and mathematical foundations of the heat-shielding composite materials functioning under the conditions of aerodynamic heating of aircraft, as well as under the conditions of the point effect of high-energy radiation are considered. The problem of deformation of a thin shallow shell under the action of a local temperature field is approximately solved. Such problems arise, for example, in the case of local destruction of heat-protective coatings of aircraft shells. Then the aerodynamic heating acts directly on the load-bearing shell of the structure. Its destruction inevitably leads to the death of the entire aircraft. A methodology has been developed for the numerical solution of the entire complex problem on the basis of economical absolutely stable numerical methods. Multiple results of numerical simulation of the thermal state of the locally heated shallow shell under conditions of its thermal destruction at high temperatures have been obtained.

Adoption of Mobile Peer-to-Peer Payment: Enabling Role of Substitution and Social Aspects

  • Clement Jun Feng Lim;Byungwan Koh;Dongwon Lee
    • Asia pacific journal of information systems
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    • v.29 no.4
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    • pp.571-590
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    • 2019
  • Despite the growing amount of mobile peer-to-peer (P2P) payment applications available on mobile app stores, these applications are still in their infancy and have yet to see mass adoption. This study aims to explore the factors that influence the adoption of such mobile P2P payment applications by using a large-scale data set based on the tracking of users' actual mobile application usage behavior. Our main findings reveal that the duration of each session that users use of traditional bank application has a significant relationship with their adoption of mobile P2P payment applications. In addition, we explore the social aspect of such mobile P2P payment applications by analyzing their social network applications usage and found that the amount of social network service applications used and usage duration positively impacted one's adoption of mobile P2P payment applications. These findings have important theoretical and practical implications for stakeholders of mobile P2P payment solution providers as well as intermediaries/banks who provide their own payment applications to their customers.

Time-dependent Evolution of Accretion Disk Mass in a Black Hole Microquasar Candidate A0620-00 (블랙홀 마이크로퀘이사 후보 A0620-00의 강착원반 질량의 시간적 진화)

  • Kim, Soon-Wook
    • Journal of the Korean earth science society
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    • v.29 no.7
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    • pp.579-585
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    • 2008
  • The time-dependent evolution of disk mass for outburst limit cycle in a black hole microquasar is calculated based on the non-linear hydrodynamic model of thermally unstable accretion disk. The physical parameters such as black hole mass, disk size and mass transfer rate are adopted to reproduce the historical 1975 outburst observed in a prototype black hole X-ray nova A0620-00. The time-dependent effect of irradiation from the central hot region to the disk is considered in two ways: direct irradiation and indirect irradiation reflected from hot accretion flow above the disk. The accretion disk thermal instability model can account for the bolometric luminosity appropriate to typical characteristics of system luminosity observed in X-ray transients during the whole cycle of the outburst evolution. The maximum mass of the accretion disk, ${\sim}4.03{\times}10^{24}g$, is achieved at the ignition of an outburst, and the minimum value, ${\sim}8.54{\times}10^{23}g$, is reached during the cooling decay to quiescence. The disk mass varies ${\sim}5$ times during outburst limit cycle.

Nitrogen Fixation of Legumes and Transfer to Grasses in Spring Paddy Soil (춘계답리작 토양에서 두과의 질소고정과 이의 화본과로의 이동)

  • Lee, Hyo-Won
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.27 no.3
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    • pp.167-172
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    • 2007
  • Manure recycle is an emerging issue in agriculture in Korea these days. Farmers are keeping eye on legume mixture with grasses for nitrogen fixation and transfer to companion crops by legumes. We had a trial to investigate the effect of different legume mixtures on nitrogen fixation and transfer in spring soil. The treatment was arranged in a randomized complete block design with three replications. Three different mixtures were used(rye+hairy vetch, Italian ryegrass+crimson clover, oat+pea) and sowed in pots with paddy soil from western part of Korea(Seo Chon County). Pots with rye+vetch were transplanted from field of RDA(rural development administration) in Suwon on 2 February 2007 and other mixture treatments were sowed on early March with different sowing rate(7:3=Italian:crimson, 6:4=oat:pea). $(^{15}NH_4)_2SO_4$ solution at. $99.8\;atom%^{15}N$ was applied to the each pot at the rate of $2kg\;N\;ha^{-1}$. Application was done on 6 April at rye+vetch pots and remainder were applied on April 16. Forage were harvested from each pot at ground level in heading stage and separated into legume and grass. Total N content and $^{15}N$ value were determined using a continuous flow stable isotope ratio mass spectrometry. DM yield of rye+vetch, Italian+crimson and oat+pea were 6,607, 3,213 and 4,312 kg/ha, respectively. Proportion of N from fixation was 0.73(rye+vetch), 0.42(Italian+crimson) and 0.93(oat+pea). The percentages of N transfer from legume to grass were from 61% to 24% in different method by treatment and -35% to 21% in isotope dilution method.

Oxygen Transfer Rate from Liquid Free Surface in Reciprocally Shaking Vessel (왕복요동 교반조의 자유 표면에서의 산소흡수속도)

  • Koh, Seung-Tae
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.276-280
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    • 2021
  • The oxygen transfer rate at the liquid surface of the reciprocally shaking vessel was studied. The required power of the reciprocally shaking vessel was not proportional to the shaking frequency, unlike the rotational shaking vessel, and the liquid level suddenly fluctuated greatly at a certain frequency as the flow pattern in the vessel was a left and right wave flow different from that of the rotational shaking that has a rotational flow. The effect of the shaking frequency on the required power in the reciprocally shaking vessel was very complex, such as less power required than the rotational shaking vessel when the shaking frequency is more than 3 s-1, but the required power for the range of the generated rotational flow in the reciprocally shaking vessel could be correlated with the equation that was reported for the rotational shaking vessel. The kLa (mass transfer capacity coefficient) in the reciprocally shaking vessel also increased in a complex pattern because the required power for shaking was not consumed in a simple pattern, unlike kLa in the rotational shaking vessel, which increases linearly with increasing frequency. The kLa of the reciprocally shaking vessel was larger than the kLa of the rotational shaking vessel, and as the kLa value increased, the difference between them increased sharply. As a result, the oxygen transfer rate in the reciprocal motion was greater than that of the rotational motion, and could be correlated with the required power per unit volume.

Evaluation of Efficiency of SVE from Lab-scale Model Tests and Numerical Analysis (실내모형시험과 수치해석을 통한 SVE의 효율성 평가)

  • Suk, Heejun;Seo, Min Woo;Ko, Kyung-Seok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1B
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    • pp.137-147
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    • 2008
  • Soil Vapor Extraction (SVE) has been extensively used to remove volatile organic compounds (VOCs) from the vadoze zone. In order to investigate the removal mechanism during SVE operation, laboratory modeling experiments were carried out and tailing effect could be observed in later stage of the experiment. Tailing effect means that removal rate of contaminants gets significantly to decrease in later stage of SVE operation. Also, mathematical model simulating the tailing effect was used, which considers rate-limited diffusion in a water film during mass transfer among gas, liquid, and solid phases. Measurement data obtained through the experiment was used as input data of the numerical analyses. Sensitivity analysis was performed to examine the effect of each parameter on required time to reach final target concentration. Finally, it was found that the concentration in the soil phase decreased significantly with a liquid and gas diffusion coefficient larger, actual path length shorter, and water saturation smaller.