• 제목/요약/키워드: mass spectrometry$HN(C_2H_5)_3$ cations

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FAB/MS를 이용한 Benzoxazolo Carbocyanine계 화합물의 분석 (Analysis of Benzoxazolo Carbocyanine Compounds using FAB/Mass Spectrometry)

  • 김영찬
    • 한국응용과학기술학회지
    • /
    • 제23권2호
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    • pp.125-129
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    • 2006
  • Benzoxazolo carbocyanine compounds were synthesized by condensation of a suitable ortho-ester with an appropriately substituted 2-methylbenzoxazole in the presence of triethylamine. This compounds used as green sensitizing dyes in photographic emulsions. The compounds are characterized by fast atom bombardment mass spectrometry. The values(m/z) of structurally significant ions observed in FAB spectra. It was showed tentative fragmentation pattern in FAB spectroscopy of $HN(C_2H_5)_3$ cations in glycerol/trifluoroacetic acid matrix.