• Title/Summary/Keyword: mass spectral method

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Characterization of Synthetic Polyamides by MALDI-TOF Mass Spectrometry

  • Choi, Hae-Young;Choe, Eun-Kyung;Yang, Eun-Kyung;Jang, Sung-Woo;Park, Chan-Ryang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2354-2358
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    • 2007
  • MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

Adaptive Beam Selection Method for Improvement of Spectral Efficiency in Millimeter-Wave MIMO (밀리미터파 대역의 다중입출력 안테나 시스템에서 스펙트럼 효율 향상을 위한 적응적 빔 선택 기법)

  • Kim, Jun-Ho;Byun, Youn-Shik
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.41 no.8
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    • pp.890-895
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    • 2016
  • As the wireless communication technique is developing rapidly, the use of smart devices is increasing. Due to gradually increasing data traffic, a new area, more than 6GHz of bandwidth to increase capacity of the network, has been studied. Millimeter Wave(MmWave) communications utilizes the bandwidth above 6GHz, which makes it possible to achieve one gigabit per second data rate. To overcome the path loss due to the smaller wavelength, the mass of the antenna arrangement is used. This paper presents an algorithm that maximizes the spectral efficiency of the system in the pre-coding process using a hybrid beamforming. Also it is suggested with the optimization of the number of beams that maximizes the spectral efficiency was maximized by the propose method.

A new study in designing MTMDs in SDOF and MDOF systems based on the spectral analysis method

  • Baigoly, Morteza;Shargh, Farzan H.;Rofooei, Fayaz R.
    • Earthquakes and Structures
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    • v.19 no.4
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    • pp.243-259
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    • 2020
  • This study aims to optimize, design, and predict the MTMDs performance in SDOF systems using spectral analysis, and then apply their results to MDOF structures. Given the importance of spectral analysis in the design of new engineering structures, achieving a method for designing TMDs based on this theory can be of great importance for structural designers. In this study, several convenient combinations of MTMDs in an SDOF system are first considered to minimize the maximum displacement. For calculating the frequency ratios of dampers, an innovative technique is adopted in which the values of different modal responses obtained from the spectral analysis are approached together. This procedure is done using a harmony search (HS) algorithm. Also, using the random vibration theory, the damping ratio of the dampers is obtained. Then, an equation is presented for predicting the performance of MTMDs. For evaluating this equation, three structures with different stories are designed. Some of the presented combinations of dampers are added to them. The time history analyses are employed to analyze the structures under 30 different accelerograms. The findings indicated that the proposed equation could efficiently predict the performance of the MTMDs. Furthermore, four different patterns of damper distribution along the height of the structures are defined. The effect of them on the maximum deformation of the structures in time history analyses is discussed, and an equation is presented to estimate this effect. The results indicated that the average and maximum error percentages of the proposed equations are about three and seven percent, respectively, compared to the time history analyses results, which are negligible values.

Highly Dispersed CuO Nanoparticles on SBA-16 Type Mesoporous Silica with Cyclam SBA-16 as a Precursor

  • Prasetyanto, Eko Adi;Sujandi, Sujandi;Lee, Seung-Cheol;Park, Sang-Eon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2359-2362
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    • 2007
  • MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

Power spectral density method performance in detecting damages by chloride attack on coastal RC bridge

  • Mehrdad, Hadizadeh-Bazaz;Ignacio J., Navarro;Victor, Yepes
    • Structural Engineering and Mechanics
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    • v.85 no.2
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    • pp.197-206
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    • 2023
  • The deterioration caused by chloride penetration and carbonation plays a significant role in a concrete structure in a marine environment. The chloride corrosion in some marine concrete structures is invisible but can be dangerous in a sudden collapse. Therefore, as a novelty, this research investigates the ability of a non-destructive damage detection method named the Power Spectral Density (PSD) to diagnose damages caused only by chloride ions in concrete structures. Furthermore, the accuracy of this method in estimating the amount of annual damage caused by chloride in various parts and positions exposed to seawater was investigated. For this purpose, the RC Arosa bridge in Spain, which connects the island to the mainland via seawater, was numerically modeled and analyzed. As the first step, each element's bridge position was calculated, along with the chloride corrosion percentage in the reinforcements. The next step predicted the existence, location, and timing of damage to the entire concrete part of the bridge based on the amount of rebar corrosion each year. The PSD method was used to monitor the annual loss of reinforcement cross-section area, changes in dynamic characteristics such as stiffness and mass, and each year of the bridge structure's life using sensitivity equations and the linear least squares algorithm. This study showed that using different approaches to the PSD method based on rebar chloride corrosion and assuming 10% errors in software analysis can help predict the location and almost exact amount of damage zones over time.

Stochastic vibration response of a sandwich beam with nonlinear adjustable visco-elastomer core and supported mass

  • Ying, Z.G.;Ni, Y.Q.;Duan, Y.F.
    • Structural Engineering and Mechanics
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    • v.64 no.2
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    • pp.259-270
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    • 2017
  • The stochastic vibration response of the sandwich beam with the nonlinear adjustable visco-elastomer core and supported mass under stochastic support motion excitations is studied. The nonlinear dynamic properties of the visco-elastomer core are considered. The nonlinear partial differential equations for the horizontal and vertical coupling motions of the sandwich beam are derived. An analytical solution method for the stochastic vibration response of the nonlinear sandwich beam is developed. The nonlinear partial differential equations are converted into the nonlinear ordinary differential equations representing the nonlinear stochastic multi-degree-of-freedom system by using the Galerkin method. The nonlinear stochastic system is converted further into the equivalent quasi-linear system by using the statistic linearization method. The frequency-response function, response spectral density and mean square response expressions of the nonlinear sandwich beam are obtained. Numerical results are given to illustrate new stochastic vibration response characteristics and response reduction capability of the sandwich beam with the nonlinear visco-elastomer core and supported mass under stochastic support motion excitations. The influences of geometric and physical parameters on the stochastic response of the nonlinear sandwich beam are discussed, and the numerical results of the nonlinear sandwich beam are compared with those of the sandwich beam with linear visco-elastomer core.

HI superprofiles of galaxies from THINGS and LITTLE THINGS

  • Kim, Minsu;Oh, Se-Heon
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.68.3-69
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    • 2021
  • We present a novel profile stacking technique based on optimal profile decomposition of a 3D spectral line data cube, and its performance test using the HI data cubes of sample galaxies from HI galaxy surveys, THINGS and LITTLE THINGS. Compared to the previous approach which aligns all the spectra of a cube using their central velocities derived from either moment analysis, single Gaussian or hermite h3 polynomial fitting, the new method makes a profile decomposition of the profiles from which an optimal number of single Gaussian components is derived for each profile. The so-called superprofile which is derived by co-adding all the aligned profiles from which the other Gaussian models are subtracted is found to have weaker wings compared to the ones constructed in a typical manner. This could be due to the reduced number of asymmetric profiles in the new method. A practical test made on the HI data cubes of the THINGS and LITTLE THINGS galaxies shows that our new method can extract more mass of kinematically cold HI components in the galaxies than the previous results. Additionally, we fit a double Gaussian model to the superprofiles whose S/N is boosted, and quantify not only their profile shapes but derive the ratio of the Gaussian model parameters, such as the intensity ratio and velocity dispersion ratio of the narrower and broader Gaussian components. We discuss how the superprofile properties of the sample galaxies are correlated with their other physical properties, including star formation rate, stellar mass, metallicity, and gas mass.

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Constraining Physical Properties of High-redshift Galaxies : Effects of Star-formation Histories

  • Lee, Seong-Kook
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.59.2-59.2
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    • 2011
  • Constraining physical (or stellar population) properties - such as stellar mass, star-formation rate, stellar population age, and dust-extinction - of galaxies from observation is crucial in the study of galaxy evolution. This is very challenging especially for high-redshift galaxies, and a widely-used method to estimate physical properties of high-redshift galaxies is to compare their photometric spectral energy distributions (SEDs) to spectral templates from stellar population synthesis models. I will show that the SED-fitting results of high-redshift galaxies are strongly dependent on the assumed forms of star-formation histories. I will also present the results of SED-fitting analysis of observed Lyman-break galaxies which show that parametric models with gradually increasing star-formation histories provide better estimates of physical parameters of high-redshift (z>3) star-forming galaxies than traditionally-used exponentially declining star-formation histories. This result is also consistent with the predictions from the modern galaxy formation models.

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Stochastic micro-vibration response characteristics of a sandwich plate with MR visco-elastomer core and mass

  • Ying, Z.G.;Ni, Y.Q.;Duan, Y.F.
    • Smart Structures and Systems
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    • v.16 no.1
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    • pp.141-162
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    • 2015
  • The magneto-rheological visco-elastomer (MRVE) is used as a smart core to control the stochastic micro-vibration of a sandwich plate with supported mass. The micro-vibration response of the sandwich plate with MRVE core and supported mass under stochastic support motion excitations is studied and compared to evaluate the vibration suppression capability. The effects of the supported mass and localized magnetic field on the stochastic micro-vibration response of the MRVE sandwich plate are taken into account. The dynamic characteristics of the MRVE core in micro-vibration are described by a non-homogeneous complex modulus dependent on vibration frequency and controllable by applied magnetic fields. The partial differential equations for the coupled transverse and longitudinal motions of the MRVE sandwich plate with supported mass are derived from the dynamic equilibrium, constitutive and geometric relations. The simplified ordinary differential equations are obtained for the transverse vibration of the MRVE sandwich plate under localized magnetic fields. A frequency-domain solution method for the stochastic micro-vibration response of sandwich plates with supported mass is developed based on the Galerkin method and random vibration theory. The expressions of frequency-response functions, response power spectral densities and root-mean-square velocity responses of the plate in terms of the one-third octave frequency band are obtained for micro-vibration evaluation. Finally, numerical results are given to illustrate the large response reduction capacity of the MRVE sandwich plate with supported mass under stochastic support motion excitations, and the influences of MRVE parameters, supported mass and localized magnetic field placement on the micro-vibration response.

Fluid-dynamic Forces Acting on the Rotating Inner Cylinder In Concentric Annulus (동심환내에서 회전하는 실린더에 작용하는 유체동하중)

  • 심우건
    • Journal of KSNVE
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    • v.11 no.3
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    • pp.428-436
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    • 2001
  • The rotating inner cylinder executes a periodic translational motion in concentric annulus while the outer one is stationary. In the study of flow-induced vibrations and relaxed instabilities, it is of interest to evaluate the fluid-dynamic forces acting on the rotating inner cylinder. In the present work, the governing equations for the confined flow are expressed as Navier-Stokes equations, including the steady and unsteady terms. The fluid parameters for steady flow generated by the rotating cylinder are determined analytically while the unsteady ones by the oscillatory motion are evaluates by a numerical method based on the spectral collocation method. In order to validate the numerical approach, the numerical results are compared wish the analytical ones given by existing theories, for simple cases where the both approaches are applicable. Good agreement was found between the results. It is found the effects of the Reynolds number, defined by rotating velocity, on the fluid-dynamic forces are important for the case of relatively low oscillatory Reynolds number, defined by oscillatory frequency : j.e., in case of $Re_\omega\gg Re_S$.

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