• Bulletin of the Korean Chemical Society
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• 제25권11호
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• pp.1661-1666
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• 2004

The reaction of titanium tetraisopropoxide with 2 equiv of N,N-diethyl acetoacetamide affords Ti($O^iPr)_2(CH_3COCHCONEt_2)_2$ (1) as colorless crystals in 80% yield. Compound 1 is characterized by spectroscopic (Mass and $^1H/^{13}C$ NMR) and microanalytical data. Molecular structure of 1 has been determined by a single crystal X-ray diffraction study, which reveals that it is a monomeric, cis-diisopropoxide and contains a six coordinate Ti(IV) atom with a cis($CONEt_2$), trans($COCH_3$) configuration (1a) in a distorted octahedral environment. Variable-temperature $^1H$ NMR spectra of 1 indicate that it exists as an equilibrium mixture of cis, trans (1a) and cis, cis (1b) isomers in a 0.57 : 0.43 ratio at -20$^{\circ}C$ in toluene-$d_8$ solution. Thermal properties of 1 as a MOCVD precursor for titanium dioxide films have been evaluated by thermal gravimetric analysis and vapor pressure measurement. Thin films of pure anatase titanium dioxide (after annealing above 500$^{\circ}C$ under oxygen) have been grown on Si(100) with precursor 1 in the substrate temperature range of 350- 500$^{\circ}$ using a bubbler-based MOCVD method.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제34회 춘계학술대회논문집
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• pp.210-213
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• 2010

최근의 실험 결과를 통해 하이브리드 로켓 연료의 표면에 연소가 진행되지 않은 채 남아있는 고립된 부분들이 존재함을 확인하였다. 이러한 불규칙적인 spot은 연료의 기화로 인한 분출유동(wall blowing)과 산화제의 유동 사이에서 발생하는 경계층 교란에 의한 현상인 것으로 여겨진다. 본 연구에서는 23,000의 높은 Reynolds수와 벽면분출 현상을 효과적으로 처리할 수 있도록 LES 기법을 이용하여, 연료 표면 근처의 난류 유동 특성을 해석하였다. 원형 단면을 갖는 하이브리드 로켓 모터의 그레인 형상을 사실적으로 모사하기 위하여 곡률효과를 포함한 3차원 실린더 형태의 지오메트리를 고려하였다. 연료 표면에서 발생하는 불규칙한 spot의 발생은 경계층과 분출되는 유동이 상호 간섭함으로써 난류구조들의 기구학적 특성을 변경시키기 때문인 것으로 추측되는 결과들을 얻을 수 있었다.

• Wind and Structures
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• 제10권5호
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• pp.463-479
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• 2007

A series of wind tunnel sectional model dynamic tests of a twin-deck bridge were conducted at the CLP Power Wind/Wave Tunnel Facility (WWTF) of The Hong Kong University of Science and Technology (HKUST) to investigate the effects of gap-width on the self-excited vibrations and the dynamic and aerodynamic characteristics of the bridge. Five 2.9 m long models with different gap-widths were fabricated and suspended in the wind tunnel to simulate a two-degrees-of-freedom (2DOF) bridge dynamic system, free to vibrate in both vertical and torsional directions. The mass, vertical frequency, and the torsional-to-vertical frequency ratio of the 2DOF systems were fixed to emphasize the effects of gap-width. A free-vibration test methodology was employed and the Eigensystem Realization Algorithm (ERA) was utilized to extract the eight flutter derivatives and the modal parameters from the coupled free-decay responses. The results of the zero gap-width configuration were in reasonable agreement with the theoretical values for an ideal thin flat plate in smooth flow and the published results of models with similar cross-sections, thus validating the experimental and analytical techniques utilized in this study. The methodology was further verified by the comparison between the measured and predicted free-decay responses. A comparison of results for different gap-widths revealed that variations of the gap-width mainly affect the torsional damping property, and that the configurations with greater gap-widths show a higher torsional damping ratio and hence stronger aerodynamic stability of the bridge.

• Journal of Microbiology and Biotechnology
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• 제18권7호
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• pp.1257-1265
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• 2008

To lower the cost of ethanol distillation of fermentation broths, a high initial glucose concentration is desired. However, an increase in the substrate concentration typically reduces the ethanol yield because of insufficient mass and heat transfer. In addition, different operating temperatures are required to optimize the enzymatic hydrolysis (50$^{\circ}C$) and fermentation (30$^{\circ}C$). Thus, to overcome these incompatible temperatures, saccharification followed by fermentation (SFF) was employed with relatively high solid concentrations (10% to 20%) using a portion loading method. In this study, glucose and ethanol were produced from Solka Floc, which was first digested by enzymes at 50$^{\circ}C$ for 48 h, followed by fermentation. In this process, commercial enzymes were used in combination with a recombinant strain of Zymomonas mobilis (39679:pZB4L). The effects of the substrate concentration (10% to 20%, w/v) and reactor configuration were also investigated. In the first step, the enzyme reaction was achieved using 20 FPU/g cellulose at 50$^{\circ}C$ for 96 h. The fermentation was then performed at 30$^{\circ}C$ for 96 h. The enzymatic digestibility was 50.7%, 38.4%, and 29.4% after 96 h with a baffled Rushton impeller and initial solid concentration of 10%, 15%, and 20% (w/v), respectively, which was significantly higher than that obtained with a baffled marine impeller. The highest ethanol yield of 83.6%, 73.4%, and 21.8%, based on the theoretical amount of glucose, was obtained with a substrate concentration of 10%, 15%, and 20%, respectively, which also corresponded to 80.5%, 68.6%, and 19.1%, based on the theoretical amount of the cell biomass and soluble glucose present after 48 h of SFF.

• 한국항공우주학회지
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• 제32권5호
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• pp.91-96
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• 2004

액체로켓 엔진에 사용되는 가스발생기를 최적설계 하였다. 추진제는 RP-1/LOx 이고, open cycle터보펌프 시스템을 사용하였으며, 가스발생기는 농후 (fuel-rich) 연소를 적용하였다. 최적설계의 목적함수는 주연소설의 비추력의 최대화이고 설계 제한조건은 가스발생기 연소 실온도와 터빈-펌프의 출력일치이다. 가스 발생기의 설계에 사용된 설계변수는 가스발생기 유량, O/F비, 터빈 노즐 입구 각, 부분분사비, 그리고 터빈 원주속도이며 이들을 이용하여 가스발생기의 열역학적 성능을 계산하였다. 그리고 설계 제한조건을 만족하면서 목적함수를 최대화 할 수 있는 가스발생기의 크기와 성능조건을 확인하였다. 설계된 가스발생기 기본형상은 연소시험에 적용된 후 최종적으로 결정된다.

• 한국정보통신학회:학술대회논문집
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• 한국해양정보통신학회 2010년도 춘계학술대회
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• pp.347-350
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• 2010

뉴 미디어 시대의 도래로 우리는 움직이는 영상 이미지의 세계에 살고 있다고 해도 과언이 아니다. 매체의 발달과 함께 일상에서는 이미지와 함께 순간을 지나며 느끼며 그것을 일부처럼 공존하며 소통하고 있다. 이러한 시대에 논리적이고 현실적인 사고보다 감각적이고 형상적인 이미지가 더 많은 것을 전달하고 설명하기도 한다. 움직이는 이미지를 보는 행위는 언어적이고 개념적인 의미의 전달 이전에 색채와 화면을 구성하고 있는 조형적인 요소와 그것들이 만들어내는 변화가 먼저 인식된다. 특히 서사의 구조를 가지는 영화영상 애니메이션에서는 그 영역이 더욱 크게 작용하며 이러한 장면의 이미지를 연결시키는 트랜지션의 기법 역시 본연의 단순한 기능에서 의미소통의 기능으로 확대되고 있다. 이러한 트랜지션 효과는 단순한 장면전환의 전통적 기법에서 시각적 유희성을 제공하고 서사의 흐름에 도움을 주는 내러티브 기능으로 수행되는 관점에서 시각적 표현의 연구는 지속되어야 한다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2003년도 학술회의 논문집 정보 및 제어부문 B
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• pp.414-416
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• 2003

메모리 제품의 사용 환경은 점차적으로 High Speed/High Density화됨에 따라 현 Comp. Test 환경으로 Field 환경을 모두 수용하기가 어려워지고 있다. 따라서, Component Level에서 다양한 실장 System을 이용한 Screen 방법이 요구 되고 있다. 다양한 환경에서 Test를 실시하기 위해서 필수 불가결한 조건은 온도(Temperature)를 자동으로 제어(Control)할 수 있는 기능이 필요하게 되었다. 이에, 현재 사용하고 있는 방법은 Chamber나 히터를 이용하고 있으나 온도 제어가 보다 용이하고 정밀한 기능이 요구됨에 따라 열전반도체(Thermoelectric semiconductor)원리를 이용한 온도 제어 장치 도입을 위한 연구가 진행되었다. 본 논문에서는 그 개발 현황 및 평가 결과를 근거로 신규 Component실장 Tester에 효율적으로 도입 적용 가능함을 제시 하고자 한다. 또한, 향후 기타 Tester 및 산업용 설비 등에 까지 확대적용 가능함으로써 전자부품(메모리)의 품질 향상 및 설비투자 Cost절감 효과가 기대 된다.

• Nuclear Engineering and Technology
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• 제48권2호
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• pp.457-469
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• 2016

During the late phase of severe accidents of light water reactors, a porous debris bed is expected to develop on the bottom of the flooded reactor cavity after breakup of the melt in water. The geometrical configuration, i.e., internal and external characteristics, of the debris bed is significant for the adequate assessment of the coolability of the relocated corium. The internal structure of a debris bed was investigated experimentally using the DAVINCI (Debris bed research Apparatus for Validation of the bubble-Induced Natural Convection effect Issue) test facility. Particle sedimentation under the influence of a two-phase natural convection flow due to the decay heat in the debris bed was simulated by dropping various sizes of particles into a water vessel with air bubble injection from the bottom. Settled particles were collected and sieved to obtain the particle mass, size distribution in the radial and axial positions, and the bed porosity and permeability. The experimental results showed that the center part of the particle bed tended to have larger particles than the peripheral area. For the axial distribution, the lower layer had a higher fraction of larger particles. As the sedimentation progressed, the size distribution in the upper layers can shift to larger sizes because of the higher vapor generation rate and stronger flow intensity.

• Molecules and Cells
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• 제21권1호
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• pp.129-134
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• 2006

Lon, also known as protease La, belongs to a class of ATP-dependent serine protease. It plays an essential role in degradation of abnormal proteins and of certain short-lived regulatory proteins, and is thought to possess a Ser-Lys catalytic dyad. To examine the structural organization of Lon, we performed an electron microscope analysis. The averaged images of Lon with end-on orientation revealed a six-membered, ring-shaped structure with a central cavity. The side-on view showed a two-layered structure with an equal distribution of mass across the equatorial plane of the complex. Since a Lon subunit possesses two large regions containing nucleotide binding and proteolytic domains, each layer of the Lon hexamer appears to consist of the side projections of one of the major domains arranged in a ring. Lon showed a strong tendency to form hexamers in the presence of $Mg^{2+}$, but dissociated into monomers and/or dimers in its absence. Moreover, $Mg^{2+}$-dependent hexamer formation was independent of ATP. These results indicate that Lon has a hexameric ring-shaped structure with a central cavity, and that the establishment of this configuration requires $Mg^{2+}$, but not ATP.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.293-300
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• 2008

Efficient designing of SRM Grains in the field of Rocketry is still the main test for most of the nations of world for scientific studies, commercial and military applications. There is a strong need to enhance thrust, improve the effectiveness of SRM and reduce mass of motor and burning time so as to allow the general design to increase the weight of payload/on board electronics. Moreover burning time can be increased while keeping the weight of the propellant and thrust in desired range, so as to give the time to control / general design group in active phase for incorporating delayed cut off if required. A mathematical design, optimization & analysis technique for Slotted Tube Grain has been discussed in this paper. In order to avoid the uncertainties that whether the Slotted Tube grain configuration being designed is best suited for achieving the set design goals and optimal of all the available designs or not, an efficient technique for designing SRM Grain and then getting optimal solution is must. The research work proposed herein addresses and emphasizes a design methodology to design and optimize Slotted Tube Grain considering particular test cases for which the design objectives and constraints have been given. In depth study of the optimized solution have been conducted thereby affects of all the independent parametric design variables on optimal solution & design objectives have been examined and analyzed in detail. In doing so, the design objectives and constraints have been set, geometric parameters of slotted tube grain have been identified, performance prediction parameters have been calculated, thereafter preliminary designs completed and finally optimal design reached. A Software has been developed in MATLAB for designing and optimization of Slotted Tube grains.