• 제목/요약/키워드: marine sediment

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적니와 굴패각을 이용한 해양오염퇴적물 내 중금속(Pb, Zn and Cu) 안정화 처리 (Application of Red Mud and Oyster Shell for the Stabilization of Heavy Metals (Pb, Zn and Cu) in Marine Contaminated Sediment)

  • 신우석;강구;박성직;엄병환;김영기
    • 대한환경공학회지
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    • 제34권11호
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    • pp.751-756
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    • 2012
  • 본 연구에서는 인천북항 인근 Pb, Zn 및 Cu로 오염된 해양퇴적물에 대하여 산업부산물인 적니와 굴패각을 안정화제로 선정하여 안정화 처리를 수해하였다. 안정화제는 적니와 굴패각으로 오염토 함량대비 각각 5%, 10%, 15%를 사용하여 15일간 습윤양생 하였다. 연속추출 실험결과를 통해 미처리오염퇴적물에서 큰 비중을 차지하고 있었던 산화물 형태와 유기물 형태 중금속이 안정화제에 의해 유기물 형태 및 잔류물 형태로 안정화되고 있음을 알 수 있었다. 또한, 안정화효율 평가를 위해 TCLP를 수행한 결과, 대조군과 비교해서 안정화 처리 퇴적물인 경우 중금속의 용출량이 확연하게 감소한 것을 확인할 수 있었다. 이러한 결과로부터, 산업부산물을 이용한 안정화제가 오염퇴적물처리에 활용 가능함을 나타내고 있다.

Rare earth element geochemistry of shelf sediments in the western part of Jeju Island, korea

  • Youn, Jeung-Su;Kim, Tae-Joung
    • 한국지구과학회:학술대회논문집
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    • 한국지구과학회 2010년도 춘계학술발표회 논문집
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    • pp.58-58
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    • 2010
  • The sediment geochemistry, including REE of surface and core samples in the western part off Jeju Island have been carried out in order to understand the provenance and hydrolic sorting. The sediment in the study area were primarily composed of coarse silt with a mean grain size of $2.8{\sim}82.8{\mu}m$. The ratios of TOC over total nitrogen (TN) showed that the study area sediments contained more organic matters of marine origin than those of terrigenous origin. The total A1203, Fe203, K20, MgO, and MnO contents and REE concentration of the fine sediments are higher than those of the coarse sediments. The higher Zr/Th and Zr/Yb ratios in coarse sediments relative to fine-grained detritus indicates sedimentary sorting. Grain size influence the REE concentrations of the study area sediment significantly. The < $63{\mu}m$ fraction of the sediment has higher REE concentration and different REE patterns when compared with those in bulk samples, due to the presence of REE-enrich heavy minerals. The REE distribution patterns of the western part of Jeju Island sediments are relatively enriched in most LREEs than the Yellow River sediment and depleted in the Changjiang River, but the LaN/YbN ratios are similar to the Changjiang sediment. The Eu/Eu* ratios ranged from 0.594~0.665(0.631) is much similar to the Yellow River sediment, possibly mixture of the sediments from these two rivers.

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연안준설 및 준설토 해양투기 해양환경평가 개선방안 (Improvement of the Marine Environmental Assessment for Dredging and Ocean Disposal of Coastal Sediment in Korea)

  • 이대인;박달수;엄기혁;김귀영;조현서;김종규;서영교;백근욱
    • 환경영향평가
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    • 제18권3호
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    • pp.131-141
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    • 2009
  • We studied improvement in marine environmental impact assessment and related management systems of coastal sediments that are dredged inshore but disposed offshore. After reviewing and diagnosing the existing assessment procedures and problems, we recommend to design the core assessment items and improve the reliability of assessment byenhancing the quality assurance/quality control (QA/QC) and verification processes. We proposed eco-friendly disposal plan for dredging sediment such as reuse system in land development was explored. A marine environmental database system was established to support the assessment processes. Guidelines for marine research and modelling were proposed for improving assessment of dredging and disposal of coastal sediment. Also, applying of screening and scoping for marine environmental assessment was reviewed.

패류양식해역인 고성만 주변 표층 퇴적물의 유기물과 중금속 분포 및 오염현황 (Distribution and Pollution Status of Organic Matter and Heavy Metals in Surface Sediment Around Goseong Bay, a Shellfish Farming Area, Korea)

  • 이가람;황동운;황현진;박정현;김형철;권정노
    • 해양환경안전학회지
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    • 제23권6호
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    • pp.699-709
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    • 2017
  • 우리나라 남해안의 대표적인 패류양식해역 중에 하나인 고성만 주변 표층 퇴적물 중 유기물과 중금속의 분포 및 오염현황을 이해하기 위해 입도와 총유기탄소(TOC), 총질소(TN), 중금속 9종(As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Zn)에 대해 조사하였다. 고성만 주변 퇴적물은 세립질의 점토(clay)와 니(mud)로 이루어져 있었다. 유기물과 중금속은 만의 입구쪽에서 안쪽으로 갈수록 상대적으로 높은 농도를 보였다. 특히, 퇴적물중 유기물 및 중금속의 분포와 C/N 비(5-10)를 고려하였을 때, 고성만 퇴적물 중 유기물은 해역 자체 내 생물체에 의해 생성된 해양기원성 유기물의 영향을 크게 받고, 중금속은 만 주변 혹은 만내 산재해 있는 인위적인 오염원의 영향을 크게 받고 있는 것으로 파악되었다. 4 가지 퇴적물 오염평가 방법을 이용하여 고성만의 중금속 오염현황을 살펴본 결과, 고성만 퇴적물은 전 해역에 걸쳐 중금속에 대하여 약간 오염된 상태였으며, 만의 북쪽과 북동쪽의 일부 해역은 퇴적물의 중금속 오염도가 높아 퇴적물에 서식하는 저서생물에 큰 위해를 줄 수 있는 상태인 것으로 나타났다. 따라서, 고성만 주변 퇴적환경 개선을 위한 체계적인 관리계획의 수립과 함께 지속적인 양식활동 및 양식생물의 안전성 확보를 위한 오염물질에 대한 집중적인 모니터링 연구가 병행되어져야 한다.

High-Frequency Bistatic Scattering from a Corrugated Sediment Surface

  • Cho, Hong-Sang;La, Hyoung-Sul;Yoon, Kwan-Seob;Na, Jung-Yul;Kim, Bong-Chae
    • The Journal of the Acoustical Society of Korea
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    • 제25권2E호
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    • pp.60-68
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    • 2006
  • High-frequency bistatic scattering measurements from a corrugated surface were made in an acoustic water tank. First the azimuthal scattering pattern was measured from an artificially corrugated surface which has varying impedance. The corrugated surface was installed both transverse to the direction of incident wave and longitudinal to the direction of incident wave. The angle between the corrugated surface and the direction of the incident wave was about $45^{\circ}$. Second, the scattering strengths were measured from the flat sediment and the corrugated sediment. A critical angle of about $37^{\circ}$ was calculated in the acoustic water tank. The measurements were made at three fixed grazing angles: $33^{\circ}$ (lower than critical angle), $37^{\circ}$ (critical angle), and $41^{\circ}$ (higher than critical angle). The scattering angle and the grazing angle are equal in each measurement. Frequencies were from 50 kHz to 100 kHz with an increment of 1 kHz. The corrugated sediment was made transverse to the direction of the incident wave. The first measurement indicates that the scattering patterns depend on the relations between the corrugated surface and the direction of the incident wave. In the second measurement, the data measured from the flat sediment were compared to the APL-UW model and to the NRL model. The NRL model's output shows more favorable comparisons than the APL-UW model. In case of the corrugated sediment, the model and the measured data are different because the models used an isotropic wave spectrum of sediment roughness in the scattering calculations. The isotropic wave spectrum consists of $w_2$ and ${\gamma}_2$. These constants derived from sediment names or bulk size. The model which used the constants didn't consider the effect of a corrugated surface. In order to consider a corrugated surface, the constants were varied in the APL-UW model.

캡이 설치된 퇴적층의 압밀 침하 (I) : 원심모형시험기를 이용한 모델링 방법 (Consolidation Settlement of Capped Sediment (I): Centrifuge Simulation by Modeling of Models Technique)

  • Kim, Tae-Hyung;Hong, Won-Pyo;Moo-Young, Horace-K
    • 한국지반공학회논문집
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    • 제19권3호
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    • pp.33-38
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    • 2003
  • 모래를 이용한 해안퇴적층 캡핑은 오염원의 이동을 줄일 수 있는 하나의 방법이다. 캡핑 설계시 자중에 의한 캡 자체의 압밀과 새로 추가된 캡층에 의한 퇴적층의 압밀을 반드시 고려해야만 한다. 이를 위해 원심모형시험기를 이용한 모형실험이 실시되었다. 이 연구에서는 실험의 정확성을 알아보기 위해 모델을 다시 모델링 하는 방법이 이용되었다. 즉, 똑 같은 경계 조건에서 서로 다른 중력가속도를 가지고 실험이 실시 되었다. 두 실험의 결과가 잘 일치함을 알 수 있었다. 이것은 캡이 설치된 해안퇴적층의 압밀침하 거동을 원심모형실험을 이용하여 예측이 가능함을 알 수 있다.

Changes in Phosphorus and Sediment Oxygen Demand in Coastal Sediments Promoted by Functionalized Oyster Shell Powder as an Oxygen Release Compound

  • Kim, Beom-geun;Khirul, Md Akhte;Cho, Dae-chul;Kwon, Sung-Hyun
    • 한국환경과학회지
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    • 제28권10호
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    • pp.851-861
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    • 2019
  • In this study, we performed a sediment elution experiment to evaluate water quality in terms of phosphorus, as influenced by the dissolved oxygen consumed by sediments. Three separate model column treatments, namely, raw, calcined, and sonicated oyster shell powders, were used in this experiment. Essential phosphorus fractions were examined to verify their roles in nutrient release from sediment based on correlation analyses. When treated with calcined or sonicated oyster shell powder, the sediment-water interface became "less anaerobic," thereby producing conditions conducive to partial oxidation and activities of aerobic bacteria. Sediment Oxygen Demand (SOD) was found to be closely correlated with the growth of algae, which confirmed an intermittent input of organic biomass at the sediment surface. SOD was positively correlated with exchangeable and loosely adsorbed phosphorus and organic phosphorus, owing to the accumulation of unbound algal biomass-derived phosphates in sediment, whereas it was negatively correlated with ferric iron-bound phosphorus or calcium fluorapatite-bound phosphorus, which were present in the form of "insoluble" complexes, thereby facilitating the free migration of sulfate-reducing bacteria or limiting the release from complexes, depending on applied local conditions. PCR-denaturing gradient gel electrophoresis revealed that iron-reducing bacteria were the dominant species in control and non-calcined oyster shell columns, whereas certain sulfur-oxidizing bacteria were identified in the column treated with calcined oyster powder.

북동 태평양 C-C 해역에 서식하는 중형저서동물 군집 (Meiobenthic Communities in the Deep-sea Sediment of the Clarion-Clipperton Fracture Zone in the Northeast Pacific)

  • 김동성;민원기;이경용;김기현
    • Ocean and Polar Research
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    • 제26권2호
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    • pp.265-272
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    • 2004
  • This study was conducted to investigate the community structure and distributional pattern of meiobenthos in the deep-sea bottom of the Clarion-Clipperton Fracture Zone of northeastern Pacific during July 2001. Examination of sediment samples collected on the eight survey station showed that there were 10 different types of meiobenthos. The most abundant meiobenthic animals were nematodes in all stations. Sarcomastigophorans, benthic harpacticoids were next abundant meiobenthos. Vertical distribution of meiobenthic animals showed the highest individual numbers in the surface sediment layers of 0-1 cm depth and showed more steep decreasing trend as sediment gets deeper on the stations of high latitude located in $16-17^{\circ}N$. Horizontal distribution of meiobenthic animal in the study area within CCFZ showed high densities of meiobenthos at the stations had few manganese nodules on their sediment surface in the site of low latitude. For size distribution analyses showed that animals which fit into the sieve mesh size of 0.063 mm were abundant.

고리원자력발전소 인근 조간대에 서식하는 퇴적물과 진주담치에 포함된 다환방향족 탄화수소(PAHs) (Polycyclic Aromatic Hydrocarbons(PAHs) in Sediment and Mussels(Mytilus edulis) from the Intertidal Zone of Kori Nuclear Power Plant, Korea)

  • Il, Noh;Ki-Seok, Lee
    • 해양환경안전학회지
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    • 제5권1호
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    • pp.47-58
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    • 1999
  • Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous contaminants in coastal marine environment. PAHs enter estuarine and nearshore marine environment via several routes such as combustion of fossil fuels, domestic and industrial effluents and oil spills. In August of 1997, sediment and mussels (Mytilus edulis) were collected at 6 sites near Kori nuclear power plant in order to analyze the PAH content by HPLC with uv/vis detection. The concentrations of 15 PAH in sediment ranged from < 1 to 5,900 ppb ( mean 173.5$\pm$99.7 ppb), and in mussels, from < 0.5 to 4,125 ppb (mean 105$\pm$60.5 ppb). Compared with other studies world over, the concentrations of carcinogenic PAHs were relatively low in both sediment and mussels from the intertidal zone of Kori. This study presents preliminary data for the PAH levels in sediment and mussels from the intertidal zone of Kori, and the data will hopefully be utilized for the assessment of oil pollution in the Southeast East Sea, Korea (especially for the PAHs).

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해양퇴적물에서 중금속 용출 차단 및 퇴적물 산소 요구량 감소를 위한 석회석, 제올라이트 및 폐콘크리트의 피복 소재로서 적용 (Application of Limestone, Zeolite, and Crushed Concrete as Capping Material for Interrupting Heavy Metal Release from Marine Sediments and Reducing Sediment Oxygen Demand)

  • 강구;박성직
    • 한국농공학회논문집
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    • 제57권4호
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    • pp.31-38
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    • 2015
  • This study aims to assess the effectiveness of limestone, zeolite, and crushed concrete as capping material to block the release of heavy metals (As, Cu, Cr, Ni, and Pb) and reduce the sediment oxygen demand. The efficiency of limestone, zeolite, and crushed concrete was evaluated in a reactor in which a 1-cm thick layer of capping materials was placed on the sediments collected from Inchon north harbor. Dissolved oxygen concentration and heavy metal concentration in seawater above the uncapped sediments and capping material were monitored for 17 days. The sediment oxygen demand was in the following increasing order: crushed concrete ($288.37mg/m^2{\cdot}d$) < zeolite ($428.96mg/m^2{\cdot}d$) < limestone ($904.53mg/m^2{\cdot}d$) < uncapped ($981.34mg/m^2{\cdot}d$). The capping materials could reduce the sediment oxygen demand by blocking the release of biochemical matters consuming dissolved oxygen in seawater. It was also shown that zeolite and crushed concrete could effectively block the release of Cu, Ni, and Pb but those were not effective for the interruption of As and Cr release from marine contaminated sediments.