• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.87-101
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• 2018

The Manjang deposit developed in the Hwajeonri formation of the Okcheon metamorphic belt consists of the Central and Main orebodies of Cu-bearing hydrothermal vein type and the Western orebody of Fe-skarn type. This study focuses on the Cu mineralization of the Central and Main orebodies to compare with the genetic environments of the Western orebody previously studied. The Central orebody produced pyrrhotite and chalcopyrite as major ore minerals with vein texture, while the Main orebody contains pyrite, arsenopyrite, and chalcopyrite as major ore minerals with vein, massive, and brecciated texture. Sphalerite, galena, magnetite, ilmenite, rutile, cassiterite, wolframite, and stannite are also accompanied. Local occurrence of skarn is dominated by grossular and hedenbergite, reflecting the reduced condition of the skarnization. Geothermometries of sphalerite-stannite in the Central orebody and arsenopyrite-pyrite in the Main orebody indicate the formation temperature of $204-263^{\circ}C$ and $383-415^{\circ}C$, respectively. Sulfur fugacity of $10^{-6}-10^{-7}atm$. in the Main orebody decreased toward the Central orebody. Sulfur isotope compositions of sulfide minerals from the Central and Main orebodies are 4.6-7.9‰ and 4.3-7.0‰, respectively, reflecting magmatic origin with slight influence by host rock. Considering ore mineralogy, texture as well as physicochemical conditions, the Main and Central orebodies of hydrothermal Cu mineralization reflect the characteristics of proximal and distal type ore mineralization, respectively, related to hidden igneous rocks, and they were generated under different hydrothermal systems from the Fe-skarn Western orebody.

• Economic and Environmental Geology
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• v.36 no.5
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• pp.365-374
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• 2003

Various deleterious chemicals can be introduced to existing concrete structures from various external sources. The deterioration of concrete by seawater attack is involved in complex processes due to various elements contained in seawater. In the present study, attention was paid to the formation of secondary minerals and characteristics of mineralogical and micro-structural changes involved in concrete deterioration caused by the influence of major seawater composition. The characteristics of deterioration occurred in existing concrete structures was carefully observed and samples were collected at many locations of coastal areas in Busan-Kyungnam. The petrographic, XRD, SEM/EDAX analyses were conducted to determine chemical, mineralogical and micro-structural changes in the aggregate and cement paste of samples. The experimental concrete deteriorations were performed using various chloride solutions (NaCl, CaCl, $MgCl_2$ and $Na_2SO_4$ solution. The experimental results were compared with the observation results in order to determine the effect of major elements in seawater on the deterioration. The alkalies in seawater appear to accelerate alkali-silica reaction (ASR). The gel formed by ASR is alkali-calcium-silica gel which known to cause severe expansion and cracking in concrete. Carbonation causes the formation of abundant less-cementitious calcite and weaken the cement paste. Progressive carbonation significantly affects on the composition and stability of some secondary minerals. Abundant gypsum generally occurs in concretes subjected to significant carbonation, but thaumasite ({$Ca_6/[Si(OH)_6]_2{\cdot}24H_2O$}${\cdot}[(SO_4)_2]{\cdot}[(CO_3))2]$) occurs as ettringite-thaumasite solid solution in concretes subjected to less significant carbonation. Experimentally, ettringite can be transformed to trichloroaluminate or decomposed by chloride ingress under controlled pH conditions. Mg ions in seawater cause cement paste deterioration by forming non-cementitious brucite and magnesium silicate hydrate (MSH).

• Korean Journal of Food Science and Technology
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• v.17 no.4
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• pp.283-288
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• 1985

Fermented big eyed herring. Harengula zunasi, and slimy, Leiognathus nuchalis, were widely used and contributed in diet of people in southern coast of Korea. In this paper, in order to elucidate the taste compounds of fermented big eyed herring and slimy, the nucleotides and their related compounds, free amino acids, TMAO, betaine, total creatinine, and minerals were analyzed. In fermented big eyed herring, lysine, alanine, leucine, isoleucine and valine were dominant holding 88.6% of the total free amino acids while alanine, leucine, isoleucine and lysine in fermented slimy were dominant holding 84.4% of total free amino acids. In the nulceotide and their related compounds, hypoxanthine was the major component in both samples. The contents of betaine, TMA and total creatinine were 99.7mg%, 24.2mg% and 432.8mg% in fermented big eyed herring, 107.6mg%, 19.5mg% and 258.8mg% in fermented slimy, while the contents of TMAO appeared trace in both samples. In the minerals of both samples Na and Ca were dominant holding 37,471-45,100.8ppm, 14,117.1-19,948.1ppm, respectively. From the omission test and chemical analysis, it is concluded that the major taste compounds of fermented big eyed herring and slimy were amino acids such as alanine, lysine, leucine and isoleucine. Minerals, nucleotides and their related compounds, betaine and total creatinine acted as an auxiliary role in taste of both fermented samples.

• Economic and Environmental Geology
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• v.11 no.3
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• pp.89-98
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• 1978

Mineralogy, beneficiation, and processes of titanium ores are reviewed from petrographic viewpoints. The most important titanium minerals are ilmenite ($FeTiO_3$) and rutile ($TiO_2$). Ilmenite will play major role :for raw material, because rutile are rapidly diminishing. Thus, there is a need to develope a successful process for producing high grade Ti02 from ilmenite. Commercial, as well as R and D processes to treat more abundant ilmenite ores fall in three general classess: 1. Iron in ilmenite is partially or completely reduced and separated either physically or chemically. 2. Iron is reduced to ferrous state and chemically leached away from the titanium. 3. Ore is treated to make chlorides either selectively or with subsequent separation and purification of $TiC_4$. Routes and efficiencies of these process technologies are primarily influenced by the particular ore deposit to be mined and secondly by environmental considerations. One deposit parameters which influence ilmenite process technologies are: 1. Complexity of microtextures of ilmenite intergrown with Fe-oxide minerals. 2. Composition of concentrates; ilmenites contain minor amounts of substituted Mg, Mn, and V. These elements plus iron and gangue minerals can cause difficulties to complete reactions, substantial acid consumption, difficulties of removing waste solids, and waste disposal problems. Major contributions to be made by petrologists for process optimization are: characterization and interpretation of compositional and physical changes of raw materials and solids derived from process streams. These informations can play significant role in selecting and improving process steps for titania production.

• Journal of Environmental Health Sciences
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• v.45 no.3
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• pp.238-246
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• 2019

Objective: The purpose of this study was to investigate the distribution of mineral components, health and taste index for water supply plants, spring water located in northern Gyeonggi area and bottled waters in market to analyze Ca, K, Mg Na, Si, $F^-$ and $SO_4{^{2-}}$. Method: The samples were source and tap water in 15 water supply plants over 9 river basin, 172 spring water and 20 bottled water. The Ca, K, Mg Na and Si were analyzed by ICP-OES. The $F^-$ and $SO_4{^{2-}}$ were determined by Ion Chromatograph. Then, taste and health index were calculated using Hashimoto equation. Results: The average concentration of major minerals showed in same order of Ca > Na > Mg > K for all kinds of drinking water from water supply plants, spring waters and bottled waters. Total concentration of major minerals (Ca, K, Mg, Na) was calculated that showed 26.79 mg/L of tap water, 21.81 mg/L of spring water, 32.94 mg/L of bottled water on average. So, the spring waters indicated the lowest minerals sum. The tap water from water supply plants was categorized to Group I, II for 33.3, 44.4% according to K-index and O-index. Otherwise, spring water was classified as Group I, II for 44.0, 46.3%. Conclusion: According to the results of K and O-index, water from water supply plant showed higher K-index which means good for the health. Otherwise, spring water indicated higher O-index that people can feel more delicious than tap water. Futhermore, the mineral distribution of source water from water supply plants and spring water had indicated high correlation with geological effect.

• Journal of the Korean Society of Food Science and Nutrition
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• v.36 no.3
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• pp.327-331
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• 2007

This study was carried out to analyze major chemical components of dried Pimpinella brachycarpa leaves. Proximate compositions of the dried Pimpinella brachycarpa were 8.96% moisture content, 28.73% crude protein, 2.66% lipids, 19.14% ash, and 40.50% carbohydrates. Major components of the free sugars and disaccharides were glucose and maltose. A total of 15 kinds of amino acids were isolated from Pimpinella brachycarpa. Essential amino acids accounted for 49.13% of the total amino acids and non-essential amino acids accounted for 50.87%. A major fatty acid was linolenic acid. A ratio of polyunsaturated fatty acids to saturated fatty acids (P/S ratio) was 2.18. Oxalic acid was a major organic acid. The contents of the vitamins A and E were 9.23 mg% and 0.26 mg%, respectively. Among the minerals in the dried Pimpinella brachycarpa, the content of calcium was the highest (765.13 mg%) and those of magnesium and sodium were also comparatively high (303.00 mg%, 96.21 mg%).

• Preventive Nutrition and Food Science
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• v.10 no.1
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• pp.103-110
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• 2005

Opuntia ficus-indica, commonly known as prickly pear cactus, is commercially grown as a food and medicinal plant in Jeju Island, Korea. The crushed pads and fruits of Opuntia ficus-indica were dried in a freeze-dryer and ground into flour to be used for food materials. The major components of proximate compositions were part of a nitrogen free extract. The major minerals were Ca (4391.2-2086.9㎎%), K (1932.1-2608.7㎎%), and Mg (800.6-1984.8㎎%). The major amino acid was glutamic acid, comprising 16.3% of total amino acids in fruit and 25.2% in pad. Dihydroflavonols were identified as (+)-trans-dihydrokaempferol and (+)-trans-dihydroquercetin. Citric acid methyl esters extracted from fruits showed inhibitory activities against monoamine oxidase-B. The presence of trimethyl citrate has been reported in other plants, but 1,3-dimethyl citrate and 1-monomethyl citrate have not been previously reported. The results of pharmacological efficacy tests, including serum biochemical and hematological parameters, autonomic nervous system, anti-inflammatory, analgestic activity, anti-diabetic activity, antithrombotic, anticoagulant, dopamine beta-hydroxylase, monoamine oxidase activity, hyperlipidemia, the respiratory system, antigastic, and anti-ulcerative actions indicate that the fruit and pad of the Opuntia ficus-indica are rich sources of food and medicinal materials.

• Ocean and Polar Research
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• v.23 no.1
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• pp.51-62
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• 2001

The Arctic consists of numerous sedimentary basins containing voluminous natural resources and two of the world's major oil and gas producing areas. The western Siberia Basin in the Arctic region has the largest petroliferous province with an area of 800 ${\times}$ 1,200 km and produces more than 60% of total Russian oil production. The North Slope of Alaska produces about 20% of the U.S. output, i.e., 11% of the total U.S. consumption. Being small compared to those regions, the Canadian Northwest Territories and the Pechora Basin in Russia produce only fair amount of oil and natural gas. There are also many promising areas in the northern continental shelf of Russia. In addition to Russia, Svalbard and Greenland have been investigated for oil and gas. Gas hydrates are widespread in both permafrost regions and arctic continental shelf areas. The reserves of gas hydrates in the Arctic Ocean are about 20${\sim}$32% of total estimated amounts of gas hydrates in the world ocean. Mineral mining is well developed, especially in Russia. The major centers are located around the Kuznetsk Basin and Noril'sk. They are major suppliers of gold, tin, nickel, copper, platinum, cobalt, iron ore, coal as well as apatite. There are also some minings of lead-zinc in Alaska and Arctic Canada.

• The Korean Journal of Food And Nutrition
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• v.32 no.5
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• pp.454-461
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• 2019

This study was carried out to investigate the chemical properties of safflower seeds cultivated at some areas in Korea. Safflower was used as one of the functional foods and medicinal plants for many centuries. Porximate compositions of safflower seeds were moisture, 4.8~8.1%, crude protein 16.5~19.5%, crude ash 2.7~3.3%, curde fiber 38.5~43.4%, and crude fat 16.6~24.4%, respectively. Glutamic acid, aspartic acid and arginine were the major amino acids and their contents were 2,587.4~3,143.5 mg%, 1,315.8~1,654.8 mg%, and 1,171.9~1,484.2 mg%. K, P, Ca, and Mg were major minerals and their contents were 611.6~886.3 mg%, 501.5~596.7 mg%, 208.5~641.2 mg%, and 530.6~639.5 mg%, respectively. The free sugars that were identified include raffinose, sucrose, glucose, fructose. ${\alpha}$-tocopherol content was 0.14~3.82 mg%. Contents of vitamin C was 0.43~3.39 mg%. The safflower seeds fatty acids were palmitic acid, stearic acid, oleic acid, linoleic acid and linoleic acid. The major fatty acid was linoleic acid it's content was 74.8~82.9%.

• Journal of the Mineralogical Society of Korea
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• v.5 no.2
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• pp.79-92
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• 1992

The Sarisan clay deposits of hydrothermal origin are found in the intensely weathered wto-mica granite in Yeoju area. The major clay minerals of the Sarisan mine are illite and montmorillonite with minor disordered kaolinite, vermiculite, and some interstratified mineral. Clay minerals were studied using various methods including X-ray diffraction, infrared absorption spectroscopy, electron microscopy, and thermal and chemical analyses. Illites occur as discrete illite or highly illitic interstratified mineral. They are of 1M and $2M_1$ polytypes and characterized by a low lattice charge (1.768-0.926 per unit formula), low $K^+$ content (0.741-0.902 per unit formula), and high Si/Al ratio (1.154-1.293) as compared with muscovite. Montmorillonites are highly negative charged and occasionally random-interstratified as I/S with 80-98% smectite. Hydrothermal alteration is more important than later weathering alteration for the formation of illite and montmorillonite clay minerals. The hydrothermal alteration took place through two stages; the formation of illite in the early stage and the formation of montmorillonite in the late stage. Disordered kaolinite and vermiculite are the weathering products of plagioclase and biotite, respectively.