• Title/Summary/Keyword: major minerals

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Geochemical evidence for K-metasomatism related to uranium enrichment in Daejeon granitic rocks near the central Ogcheon Metamorphic Belt, Korea

  • Hwang, Jeong;Moon, Sang-Ho
    • Geosciences Journal
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    • v.22 no.6
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    • pp.1001-1013
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    • 2018
  • A new type of uranium occurrence in Korea was identified in pegmatitic and hydrothermally altered granite in the Daejeon area. The U-bearing parts typically include muscovite, pink-feldspar and sericite as alteration minerals. In this study, the geochemical characteristics and alteration age of the granitic rocks were examined to provide evidence for hydrothermally-enriched uranium. The K-Ar ages of muscovite coexisting with U-bearing minerals were determined as 123 and 128 Ma. The U-bearing rocks have relatively low ($CaO+Na_2O$), high $K_2O$ contents, and high alteration index values by major element geochemistry. The trace element geochemistry shows that the uraniferous rocks have significantly low Th/U ratios and strongly differentiated features. The rare earth element patterns indicate that the uraniferous rocks have a low total REE and LREE contents with depletion of Eu. Considering the geochemical variation of the granitic rock major, trace and rare earth elements, it can be concluded that uranium enrichment in pegmatites and altered granite should be genetically related to post-magmatic hydrothermal alteration of K-metasomatism after emplacement of the two-mica granite. This is the first report for geochemical characteristics of Mesozoic granite-related U-occurrences in South Korea. This study will help further research for uranium deposits with similarities in geological setting, mineralogy and age data between South China and Korea, and can also be expected to help solve the source problems related to high uranium concentrations in some groundwater occurring in the granitic terrane.

The Study on the Landslide Occurred in the Nongong Area in Dalseong-gun, Kyeongbuk (경상북도 달성군 논공면 일원에서 발생된 산사태의 원인)

  • 황진연;김종열;김재영
    • The Journal of Engineering Geology
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    • v.5 no.3
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    • pp.249-258
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    • 1995
  • The landslide occurred in the Nongong area of Dalseong - gun, Kyeongbuk, is described and analysed in terms of structural geology and clay mineralogy to understand the causes of the landslide. The result of the analyses shows that the slip direction and the scale of the landslide of the study area were controlled by the attitude of the major discontinuity planes m the area such as joints, faults and dikes. In addition, the surface of the slip planes of the landslide is composed of clay minerals, which are mostly tri - octahedral vermiculite and smectite. From this study it can be concluded that the presence of expandable clay minerals within the bedding joints and fracture zones in bed rock played an important role in causing the landslide of the study area.

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A Study on Mineralization of Anyang Feldspar Ore Deposit (안양장석광상의 광화작용에 관한 연구)

  • Park, Boo Seong;Chi, Jeong Mahn
    • Economic and Environmental Geology
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    • v.27 no.1
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    • pp.11-28
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    • 1994
  • The Anyang Feldspar Mine is located in Seoksu Dong, Anyang City, Kyeonggi Do, Korea and has a long exploitation record that is once produced high grade sodium feldspars, for glaze. Geologically, This area is mainly composed of Mesozoic Jurassic biotite granite (Anyang granite) which intruded Precambrian Kyeonggi Gneiss Complex outcroped near the mining area. The deposit is localized on the southwest hill side of Anyang granite batholith and is confined in hydrothemal alteration zone formed by sodium-rich alkali hydrothermal fluids along the fractures of leucocratic granite showing later differentiation facies in the biotite granite. The hydrothermal alteration is characterized by albitization, sericitization, and desilication. The microscopic observation and EPMA, XRD analysis of the feldspar ores show that major minerals are albite and quartz and accessory minerals are orthoclase and sericite, and they are rarely associated with perthite, fluorite, zircon, kaolinite, molybdenite, microcline and iron-oxide. In the REE pattern, the strong negative Eu anomalies of the feldspar ores indicate the influence of feldspar fractionation and show similiar pattern of the host leucocratic granite. The filling temperature of quartz crystals in ore zone ranges from $276^{\circ}C$ to $342^{\circ}C$, and it is inferred that the alteration occurred by the hypothermal solution.

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Dyeing of Cotton Knitted Fabrics with Volcanic Ash(I) -The Compositions of Volcanic ash Deposited on the Cotton Knitted Fabrics- (화산재를 이용한 면 편성물의 염색(I) - 면 편성물에 부착된 화산재의 성분분석을 중심으로 -)

  • 유복선;신인수
    • Journal of the Korean Home Economics Association
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    • v.41 no.8
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    • pp.55-62
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    • 2003
  • Natural dyes generally fan into two categories; organic dyes coming from animals and plants and inorganic dyes obtained from various minerals such as bengala, loess, ultramarine, prussian blue and etc. The main components of volcanic ash is clay mineral such as kaolinite, illite, quartz. Clay minerals Composing volcanic ash are kaolinite[$Al_4Si_4O_{10}{(OH)_{8}}$], illite[$K_{X}Al_2(Si,\;Al)_4O_{10}{(OH)}_2$], quartz[$SiO_2$], homblende[$Na_{0-1}\;Ca_2{(Mg,\;Fe,\;Al)}_5{(Si,\;Al)}_{8}O_{22}{(OH)}_2$]and etc. And the redish color mainly comes from iron oxide. In this paper, two different classes of dyeing process were tested; dyeing with volcanic ash only and cationic agent pre-treatment followed by dyeing with volcanic ash. The compositions of the volcanic ash powder and the volcanic ash deposited on the cotton knitted fabrics identified by energy dispersive spectrometer and XRD analysis. The major chemical components of volcanic ash deposited on the cotton knitted fabrics were confirmed to be the saicon oxide, iron oxide, and aluminum oxide and etc. According to the analysis by XRD and EDS-SEM, kaolinite, illite and quartz were also identified.

Synthesis of $\beta$다-Sialon with Various Compositions from Kaolin (카올린으로부터 조성이 다른$\beta$다-Sialon의 합성)

  • 최상욱;서규식;이종진
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.17-24
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    • 1986
  • β'-Sialon with different compositions was synthesized by the carbothermal reduction-nitridation of compacts containing kaolin graphite and silicon or aluminum at temperature of 1300-1450℃ under flowing gas of 90% N2-10% H2 or 20hrs. Quantitative analysis of minerals which were formed in the specimens was carried out by using the calibration curve which has been prepared from X-ray diffraction patterns. The obtained results were as follows : 1. In the formation of β'-Sialon by carbothermal reduction-nutridation of Si-Al-O-C system mixtures at 1400℃ for 20hrs. (2) β'-Sialon as a major mineral and α-Al2O3 as a minor mineral were identified in the specimen which was prepared of kaolin and graphite. (3)α-Al2O3 and 15R as a minor minerals were measured in the specimen which was prepared of kaolin aluminum and graphite. (4) AlN instead of α-Al2O3 and 15R was formed in the compacts that excess graphite(=35 wt%) was added to the mixture of kaolin and aluminium. 2. As the reaction time and temperature were increased the formation of β'-Sialon was increased whereas the phases of mllite SiC and Si2ON2 were decreased gradually.

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Hydrothermal Solution-Rhyolite Reaction and Origin of Sericitite in the Yukwang Mine (유문암-열수 반응과 유광 견운모 광상의 성인)

  • Park, Maeng-Eon;Choi, In-Sik;Kim, Jin-Sup
    • Economic and Environmental Geology
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    • v.25 no.3
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    • pp.225-232
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    • 1992
  • The hydrothermal alteration is evaluated using multicomponent equilibrium calculations with the program CHILLER for the reactions between hydrothermal water and rhyolite at the temperature of $300^{\circ}C$ and pressure of 500 bars. The chemical-reaction model on the depositional processes of the sericitite confirms that the hydrothermal water-rock interaction(hydrothermal alteration) is the main mechanism of the sericitite formation. The principal change in the aqueous phase during the reaction is the pH increase. Overall trends for the major species are the increase in total molalities of K, Ca, $SiO_2$, Al, Mg, Fe, Na, and sulfide in solid phase with hydrothermal water-rhyolite reaction and the decrease of them in aqeous solution by precipitation of hydrothermal products. Quartz and sericite are the first minerals to form. The sequence of minerals to precipitate following them is chlorite, epidote, pyrite and microcline as water/rock ratio decreases. Although calculated results cannot duplicate the complexities of natural hydrothermal alteration, the calculation provides thermodynamic constraints on the natural process. The calculation results resemble those of experimental studies. Sericitite forms where pH decreases and water/rock ratio increases.

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MÖssbauer Spectrum of Lava in Jeju Island (제주도 용암의 MÖssbauer 스펙트럼 연구)

  • Hong, Sung-Rak;Ko, Jeong-Dae;Choi, Won-Jun
    • Journal of the Korean Magnetics Society
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    • v.13 no.6
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    • pp.226-230
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    • 2003
  • In this study, we analyzed the volcanic rock and scoria samples taken from special sites of Jeju island in two ways at the room temperature. One is the analysis of the chemical composition using X-ray fluorescence spectrometer, the other is the analysis of minerals in the samples, oxidized iron's genus, valence state and magnetic properties using X-ray diffractometry and Mossbauer spectroscopy. We believe that the volcanic rock and scoria samples are chiefly made of silicate minerals, like SiO$_2$, and they also have olivine, pyroxene, ilmenite, hematite and magnetite. The major Fe fractions of the volcanic rock samples are 2+ charge state and those of the scoria samples are 3+ charge state.

Food Scientific Characteristic of Fond de Boeuf brun (Brown soup stock) (Fond de Boeuf Brun (Brown soup stock)의 조리과학적 성질)

  • 권혁련;안명수
    • Korean journal of food and cookery science
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    • v.7 no.3
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    • pp.29-36
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    • 1991
  • Analysis of major nutritional components and Sensory evaluation in two kinds of beef bone stocks (White & Brown) have been Carried out in this study, these stocks were prepared with four different parts of beef bone (Knee bone, Rumpbone, Legbone, Backbone). White bone stocks were made of each beef bone boiling in water & hours, while brown bone stocks were prepared with roasted beef bone in the oven at $230^{\circ}C$ for half an hour and boiled 8 hours with water. Fatty acids were determined by GLC (Gas Lipids Chromatogram), the minerals were analysed by Automic spectrometer. The results of these analysis were obtained as followes; 1. Neutral lipids was gradually becreased, and glycolipids phospholipids were increased in quantity in Brown stocks for 8 hours. Unsaturated fatty accid of Brown stocks was highly decreased due to roasting of bores in the oven at 23$0^{\circ}C$ for half an hour. But they appeared in large quantity in white stocks. 2. The minerals also contained of high percentage in almost Brown stock except backbone Stock 3. Four materials (Kneebone, Rumpbone, Legbone, and backbone) were used for this study and the paired comparison of flavor test presented the recognition of different flavor at 5% level of Least Significant Difference (LSD) on brown stocks (Kneebone, and Legbone). Ranking preference test showed that white Kneebone stock and brown legbone stock had good taste.

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Gold-Silver Mineralizations in the Imgye District (임계지역(臨溪地域)의 금(金)-은(銀) 광화작용(鑛化作用))

  • Park, Hee-In;Hwang, Jeong;Huh, Soon-Do
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.379-395
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    • 1992
  • The gold ore deposits of Nakcheon, Gongyeong and Dongmyeong mine in the Imgye district are E-W trending fissure filling veins emplaced in Precambrian Jungbongsan granite and sedimentary rocks of Cambrian Yangdeog group. The K-Ar age for vein alteration sericite and vein laced muscovite are 73 and 93 Ma, respectively. Vein structure and mineralogy indicate the three distinct depositional stages: I) basemetal sulfides and tin minerals, II) gold-basemeatl sulfides, III) gold-silver-basemetal sulfides. Major gold and silver ore minerals are electrum, native silver, pyrargyrite and argentite. Fluid inclusion data indicate that filling temperatures were from $350^{\circ}C$ to $190^{\circ}C$ through stage I, II and III. Salinities were in the range of 0.0~9.5 NaCl eq.wt.% and do not reveal any systematic trend. Intermittent boiling of ore fluid during stage I is indicated by fluid inclusions in quartz. Fluid pressure during stage I which is estimated from fluid inclusions showing boiling evidence range from 50 to 100 bars. Gold ore deposits of the Imgye district were formed under higher temperatures and lower sulfur fugacities compared with the Eunchi silver ore deposits about 8 Km apart from the Imgye district.

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The recycle of titanium scrap by electron beam melting and plasma arc melting process (전자빔용해 및 플라즈마아크용해에 의한 티타늄 스크랩의 재활용)

  • Choi, Good-Sun;Park, Jong-Bum;Oh, Jung-Min;Moon, Young-Hee;Um, Tae-Kyung;Kim, Young-Suk;Kim, Young-Rog
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.05a
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    • pp.56-60
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    • 2006
  • In 2005, the imports of titanium metals was about 22.8 million US$(7,700 tons) in Korea. New scrap produced was estimated to be 359 tons and the exports were about 352 tons. Generally scrap is recylced into titanium ingot either with or without virgin metal using traditional vacuum-arc-melting and cold hearth melting. In Korea, there is no titanium ingot producers(recyclers). In this paper, the brief summary of major titanium melting technology, such as vacuum arc remelting(VAR), electron beam melting(EBM), plasma arc melting(PAM) is given and discussed. In view of titanium market situation of Korea, the technological development of ingot production from scrap is big problem to be solved in order to realize extensive cost reduction for titanium products.

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