• Title/Summary/Keyword: magnetic polymer particle

Search Result 25, Processing Time 0.051 seconds

RHEOLOGICAL PROPERTIES OF MAGNETIC PARTICLE SUSPENSIONS

  • Kwon, T.M.;Choi, H.J.;Jhon, M.S.
    • Journal of the Korean Magnetics Society
    • /
    • v.5 no.5
    • /
    • pp.667-671
    • /
    • 1995
  • The viscometric technique is used to study the effects of microstructure on the viscosity (viscosity vs. concentration or shear rate) of magnetic particle suspensions. In this characterization, measurement of suspension viscosity is used to obtain the dependence of viscous energy dissipation on microstructural state of dispersions. Microstructural shape effects which are related to particle orientation are then indirectly obtained. Empirical formulas from mean field theory and the Mooney equation, which are applicable at high concentration of magnetic particles, are used to relate viscosity to particle concentration. The validity and physical meaning of these equations are discussed.

  • PDF

Effect of Surface Treated Magneto-responsible Particle on the Property of Magneto-rheological Elastomer Based on Silicone Rubber

  • Choi, Soyeon;Chung, Kyungho;Kwon, Seunghyuk;Choi, Hyoungjin
    • Elastomers and Composites
    • /
    • v.51 no.2
    • /
    • pp.113-121
    • /
    • 2016
  • Magneto-rheological elastomer (MRE) is a material which shows reversible and various modulus under magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, silicone rubber was used as a matrix of MREs. Carbonyl iron particle (CIP) was used to give magnetic field reactive modulus of MRE. The surface of the CIP was modified with chemical reactants such as silane coupling agent and poly(glycidyl methacrylate), to improve interfacial adhesion between matrix and CIP. The mechanical properties of MREs were measured without the application of magnetic field. The results showed that the tensile strength was decreased while the hardness was increased with the addition of CIP. Also, surface modification of CIP resulted in the improvement of physical properties of MRE, but the degree of orientation of CIP became decreased. The analysis of MR effect was carried out using electromagnetic equipment with various magnetic flux. As the addition of CIP and magnetic flux increased, increment of MR effect was observed. Even though the surface modification of CIP gave positive effect on the mechanical properties of MRE, MR effect was decreased with the surface modification of CIP due to decrease of CIP orientation. Throughout this study, it was found that the loading amounts of CIP affected the mechanical properties of MRE, and surface property of CIP was an important factor on MR effect of MRE.

Ring Oxpening Polymerization of D,L-Lactide on Magnetite Nanoparticles

  • Tian Jing;Feng Ya-Kai;Xu Yong-Shen
    • Macromolecular Research
    • /
    • v.14 no.2
    • /
    • pp.209-213
    • /
    • 2006
  • The ring-opening polymerization of D,L-lactide initiated by tin(II) 2-ethylhexanoate $(Sn(Oct)_2)$ on the surface-initiated magnetite $(Fe_{3}O_4)$ nanoparticles was performed at $130^{\circ}C$. The effects of the polymer molar mass and concentration on the amount of surface polymer were investigated. The number average molecular weights, $M_n$, obtained by both NMR and GPC methods fit well within the accuracy of the applied methods and ranged from 1,100 to $4,040g\;mol^{-1}$. A surface functionalization density of up to 625 initiation sites per particle was obtained. The composition of various core-shell particles was determined by TGA, with results indicating magnetite $(Fe_{3}O_4)$ contents, ${\mu}m$, between 17 and 59 wt%. Under the influence of a magnetic field, the heating generated by superparamagnetic core-shell particles suspended in toluene presented guidelines for an optimization of magnetic particle systems with respect to an application for hyperthermia.

Synthesis of Monodispersed Magnetic Polymer Particle (균일한 자성 고분자 입자의 합성)

  • Ahn, Byung Hyun
    • Applied Chemistry for Engineering
    • /
    • v.19 no.3
    • /
    • pp.316-321
    • /
    • 2008
  • Monodispersed particles of poly(styrene-co-4-vinylpyridine), poly(st-co-4vp) were prepared by soapless emulsion polymerization. Iron oxide was formed on the surface and inside of the poly(st-co-4vp) particles by thermal decompostion of iron pentacarbonyl. The obtained magnetic poly(st-co-4vp) particles was mondispersed and the average size was 250 nm. The magnetic poly(st-co-4vp) particles had 14% of iron oxide, which was identified as $Fe_3O_4$ by XRD. The magnetic poly(st-co-4vp) particles had superparamagnetism according to superconducting susceptometer (SQUID).

Effect of Particles Size on Magnetic Performance of Dielectromagnetics

  • Gaworska, Dominika;Hodgson, Simon N.B.;Koniarek, Jaroslaw;Weglinski, Bogumil
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09b
    • /
    • pp.792-793
    • /
    • 2006
  • In the paper, the influence of different particle size $D:D>125{\mu}m$, $D<50{\mu}m$ and between on magnetic properties of a standardized dielectromagnetic is presented. The tests were taken at frequencies of between 50Hz, and 500Hz. Presented in the paper results provide important materials property data to allow the selection of the most appropriate dielectromagnetic particle size for different applications.

  • PDF

The Filtrational Characteristics of Magnetic Fibrous Polymeric Filter as an Oil Filter for Automotive (자동차용 자성폴리머 오일필터의 여과특성 연구)

  • 안병길;최웅수;권오관;문탁진
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.4 no.5
    • /
    • pp.179-186
    • /
    • 1996
  • The magnetic fibrous polymeric oil filter for automotive was obtained by pneumoextrusion processing prepared from thermoplastic polymer(polyamide) containing magnetic particulate filer (Ba ferrite), and treated subsequently in a magnetic fields. Using an oil filter tester and particle quantifier, the dependence of filtrational characteristics of the magnetic oil filter on the parameters of mean pore sizes and magnetic properties were analyzed. Also experimental engine-bed test of oil filters was investigated. The magnetic fibrous polymeric filter was shown to possess a highly filtration efficiency in filtering the fine metal particles with increasing the magnetic force of filter element. In this study, we knew that efficiency of magnetic fibrous polymeric filter was dependent on the magnetic strength of the filter elements.

  • PDF

A Study on The Filtration Characteristics of Magnetic Fibrous Polymeric Filter with Packing Density Profile as a New Oil Filter (윤활시스템용 오일필터로서 충전밀도 변화에 따른 자성폴리머 필터의 여과특성 연구)

  • 최기영;안병길;최웅수;권숙인;권오관
    • Tribology and Lubricants
    • /
    • v.11 no.2
    • /
    • pp.8-14
    • /
    • 1995
  • The filtration of the magnetic fibrous polymeric filter with packing density profile made of a self-bonded, nonwoven structure comprising a thermoplastic polymer and a magnetic substance was investigated using an oil filter tester, a particle quantifier and an image analyzer system. The magnetic fibrous polymeric filter showed excellent filtration efficiency compared with conventional paper filter. From the experimental results, It is deduced that the filtration mechanism of conventional paper filter is only the function of physical porosity by surface filteration. On the other hand, the newly magnetic fibrous polymeric filter is designed with a new concept in filtration mechanism. That is, it has a dual function of depth and magnetic filters by physical porosity and magnetic attraction. The newly magnetic fibrous polymeric filter has been shown to be a highly effective oil filter for lubrication systems.

Methotrexate-Incorporated Polymeric Micelles Composed of Methoxy Poly(ethylene glycol)-Grafted Chitosan

  • Jeong, Young-Il;Seo, Dong-Hyuk;Kim, Don-Gon;Choi, Chang-Yong;Jang, Mi-Kyeong;Nah, Jae-Woon;Park, Yoon-Kyung
    • Macromolecular Research
    • /
    • v.17 no.7
    • /
    • pp.538-543
    • /
    • 2009
  • In this study, methotrexate (MTX)-encapsulated polymeric micelles using methoxy poly(ethylene glycol) (MPEG)-grafted chitosan (ChitoPEG) copolymer were prepared. The MIX-incorporated polymeric micelles of ChitoPEG copolymer has a particle size of around 50-100 nm. In 1H nuclear magnetic resonance (NMR) study, the specific peaks of MTX disappeared in heavy water ($D_2O$) and only the specific peak of MPEG was observed, while all of the peaks were confirmed in dimethyl sulfoxide (DMSO). These results indicated that MTX was complexed with chitosan and then formed an ion complex inner-core of the polymeric micelle in an aqueous environment. The drug contents of the polymeric micelle were around $4{\sim}12%$ and the loading efficiency of MTX in the polymeric micelles was higher than 60% (w/w) for all of the formulations. The cytotoxicity of MIX and MTX-incorporated polymeric micelle against CT26 tumor cells was not significantly changed.