• Title/Summary/Keyword: magnetic absorption

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Studies on the Paramagnetic Impurity $Y_2BaCuO_5$ in Superconducting $YBa_2Cu_3O_{7-\delta}$ Phase

  • Choy Jin-Ho;Chun Sung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.10 no.1
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    • pp.5-8
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    • 1989
  • Conventional ceramic method has been used to prepare the green phase, $Y_2BaCuO_5$, commonly observed in 90-K superconductor $YBa_2Cu_3O_P{7-{\delta}}$as an impurity phase. The powder X-ray diffraction analysis indicates that $Y_2BaCuO_5$ has an orthorhombic symmetry with lattice parameter of a = 12.2 $\AA$, b = 5.61 $\AA$, and c = 7.14 $\AA.$ The average g-value 2.13 observed in ESR spectrum is attributable to Cu2+ stabilized in $C_{4v}$ field. From the magnetic susceptibility ($\mu$eff = 2.29 BM) and the ESR measurements, it is confirmed that Cu(II) $3d^9$ electrons in $Y_2BaCuO_5$ are localized and can be characterized by Curie-Weiss behavior. Optical reflectance spectrum shows a broad absorption peak around 680 nm due to dxy ${\rightarrow}$ $dx^2-y^2$ eletronic transition.

A Study on Manufacturing Method of High Performance Smart EMW Absorber with Heat Radiating Function and Its Prospects (방열 기능형 고성능 스마트 전파흡수체 제조 방법 개발 및 전망)

  • Kim, Dong Il;Jeon, Yong Bok
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.10
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    • pp.841-850
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    • 2015
  • With the rapid progress of electronics and radio communication technology, human enjoys greater freedom in information communication. However, EMW(Electro-Magnetic Wave) environments have become more complicate and difficult to control. Thus, international organizations, such as the American National Standard Institution(ANSI), Federal Communications Commission(FCC), the Comite Internationale Special des Perturbations Radio Electrique(CISPR), etc, have provided standard for controlling the EM wave environments and for the countermeasure of the electromagnetic compatibility(EMC). In this paper, fabrication of the smart EMW absorber which has heat radiating function and high performance absorption abilities were suggested. Furthermore, we prospected future smart EMW absorbers. The designed smart EMW absorber is fabricated following process. Firstly, we applied high temperature heat treated to a mixture of Iron-oxide($Fe_2O_3$) and ceramics. Secondly, we applied low temperature heat treated to the mixture of heat treated material and a carbon material. Lastly, we made apertures on the absorber. The designed smart EM wave absorber has the absorption ability of more than 20 dB from 2 GHz to 2.45 GHz band, respectively. Thus, it is respected that these results can be applied as various EMC devices in electronic, communication, and controlling systems.

Studies on Crystallographic and Mossbauer Spectra of the LiFe0.9Mn0.1PO4 (LiFe0.9Mn0.1PO4 물질의 결정구조 및 뫼스바우어 분광 연구)

  • Kwon, Woo-Jun;Lee, In-Kyu;Rhee, Chan-Hyuk;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.15-18
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    • 2012
  • The olivine structured $LiFe_{0.9}Mn_{0.1}PO_4$ material was prepared by solid state method, and was analyzed by x-ray diffractometer (XRD), superconducting quantum interference devices (SQUID) and Mossbauer spectroscopy. The crystal structure of $LiFe_{0.9}Mn_{0.1}PO_4$ was determined to be orthorhombic (space group: Pnma) by Rietveld refinement method. The value of N$\acute{e}$el temperature ($T_N$) for $LiFe_{0.9}Mn_{0.1}PO_4$ was determined 50 K. The temperature dependence of the magnetization curves showed magnetic phase transition from paramagnetic to antiferromagnetic at $T_N$ by SQUID measurement. M$\ddot{o}$ssbauer spectra of $LiFe_{0.9}Mn_{0.1}PO_4$ showed 2 absorption lines at temperatures above $T_N$ and showed asymmetric 8 absorption lines at temperatures below $T_N$. These spectra occurred due to the magnetic dipole and electric quardrupole interaction caused by strong crystalline field at asymmetric $FeO_6$ octahedral sites.

Comparison and Optimization of Parallel-Transmission RF Coil Elements for 3.0 T Body MRI (3.0 T MRI를 위한 병렬전송 고주파 코일 구조 비교와 최적화)

  • Oh, Chang-Hyun;Lee, Heung-K.;Ryu, Yeun-Chul;Hyun, Jung-Ho;Choi, Hyuk-Jin
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.44 no.4 s.316
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    • pp.55-60
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    • 2007
  • In high field (> 3 T) MR imaging, the magnetic field inhomogeneity in the target object increases due to the nonuniform electro-magnetic characteristics of the relatively high RF frequency. Especially in the body imaging, the effect causes more serious problems resulting in locally high SAR(Specific Absorption Ratio). In this paper, we propose an optimized parallel-transmission RF coil and show the utility of the coil by FDTD simulations to overcome the unwanted effects. Three types of TX coil elements are tested to maximize the efficiency and their driving patterns(amplitude and phase) optimized to have adequate field homogeneity, proper SAR level, and sufficient field strength. For the proposed coil element of $25cm{\times}8cm$ loop structure with 12 channels for a 3.0 T body coil, the field non-uniformity of more than 70% without optimization was reduced to about 26 % after the optimization of driving patterns. The experimental as well as simulation results show that the proposed parallel driving scheme is clinically useful for (ultra) high field MRI.

Embodiment of High Impedance Surface of Meta-Material Characteristic Using Symmetrical AMC Structure and Its SAR Analysis (대칭형 인공자기도체 구조를 이용한 메타물질 특성의 고임피던스 표면 구현 및 SAR 특성 분석)

  • Lee, Seungwoo;Lee, Moung-Hee;Rhee, Seung-Yeop;Kim, Nam
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38B no.9
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    • pp.744-750
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    • 2013
  • In this paper, we proposed new type of an artificial magnetic conductor(AMC) structure, which has a high impedance surface for realizing the meta-material characteristics. The designed AMC structure set a goal of 3.2GHz, and the reflector, which consists of periodically arrayed AMCs is fabricated and measured. The high impedance improves the reflection coefficient, decreases the system size and interference, and increases the antenna performance. The structure has embodied the high impedance by the thickness and relative permitivity of the dielectric substrate and the design configuration without the metallic via hole which connects the AMC to the GND. The bandwidth is 150% broader than the similar AMC structures. Also, the distance between the antenna and the AMC reflector is decreased by ${\lambda}/10$ as working as the metal(PEC) reflectors. The antenna radiation characteristics are 3dB increased at 10mm away from reflector by measurement. The proposed reflector could be inserted in the portable mobile devices, and the antenna's performance has improved by the reflector. The specific absorption rate is dramatically decreased over 94% because the back radiation of the antenna is shielded.

Measurement of Optical Properties of Nano-Cement Using THz Electromagnetic Waves (THz 전자기파를 이용한 나노시멘트 광학물성 측정)

  • Kim, Heonyoung;Kang, Donghoon;Oh, Seung Jae;Joo, Chulmin
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.5
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    • pp.363-369
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    • 2016
  • Enhancing mechanical strength of concrete has been fascinated using carbon-based nanomaterials such as CNT and graphene. The key to improving strength is a dispersion of nanomaterials. A novel method is required to investigate the dispersion inner concrete nondestructively. In this study, the optical optical properties such as refractive index and absorption coefficient are measured in nano-cement mortar specimens containing MWCNT and GO using THz electro-magnetic waves. From the results, the properties of nano-cement mortar are confirmed to be 1.0% to 2.5% higher in refractive index, and -14% to 28% higher in absorption coefficient than those of cement mortar at the average values. Using these characteristics, visualizing the dispersion of nano-concrete structures seems possible in future.

A Study on Development of Electro Magnetic Wave Absorbers for Mobile Phones (휴대전화 단말기용 전파 흡수체의 개발에 관한 연구)

  • Choi Yun-Seok;Jung Jae-Hyun;Kim Dong-Il
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.5 s.108
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    • pp.423-429
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    • 2006
  • This paper deals with research for development of electromagnetic wave absorbers in sheet type for mobile phones. By controlling the sendust ratio, the $Al(OH)_3$ coating, the thickness, the kind of binders, and the milling time, electromagnetic wave absorbers were prepared and examined. Central frequency shills toward lower 2.2 GHz, 1.29 GHz, 842 MHz with increasing thickness 1 mm, 2 mm, 3 mm of the absorber, and absorption ability controlled each 2.2 GHz to 1.91 GHz, 1.29 GHz to 801 MHz, 842 MH2 to 801 MHz adjust sendust amount from 80 wt% to 85 wt%. The absorption band of the electromagnetic wave absorber coated with $Al(OH)_3$ becomes larger than that of non-coated one. Sendust composite microwave absorbers mixed with CPE were prepared at $70^{\circ}C$ in temperature. The fabricated electromagnetic wave absorbers show a reflection coefficient 5.76 dB at 1.8 GHz in thickness of 0.85 mm.

Development and prospect of Smart EMW Absorber for Protection of Electronic Circuits and Devices with Heat Radiating Function (전자회로 및 부품 보호용 방열기능형 스마트 전파 흡수체의 개발과 전망)

  • Kim, Dong Il;Park, Soo Hoon;Joo, Yang Ick
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.5
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    • pp.1040-1046
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    • 2015
  • With the rapid progress of electronics and radio communication technology, human enjoys greater freedom in information communication. However, EMW (Electro-Magnetic Wave) environments have become more complicate and difficult to control. Thus, international organizations, such as the American National Standard Institution (ANSI), Federal Communications Commission (FCC), the Comite Internationale Special des Perturbations Radio Electrique (CISPR), etc, have provided standard for controlling the EM wave environments and for the countermeasure of the electromagnetic compatibility (EMC). In this paper, the status of EMW absorbers and the goal of smart EMW absorber in the future were described. Furthermore, design method of the smart EM wave absorber with heat radiating function was suggested. The designed smart EM wave absorber has the absorption ability of more than 20 dB from 2 GHz to 2.45 GHz band, the optimum aperture (hole) size, the adjacent hole space, and the thickness of which were 6 mm, 9 mm, and 6.5 mm, respectively. Thus, it is respected that these results can be applied as various EMC devices in electronic, communication, and controlling systems.

Introduction to the Technology, Applications, Products, Markets, R&D, and Perspectives of Nanofoods in the Food Industry

  • Kim, Dong-Myong;Lee, Gee-Dong
    • Preventive Nutrition and Food Science
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    • v.11 no.4
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    • pp.348-357
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    • 2006
  • Nano is a unit that designates a billionth; accordingly nanotechnology could be described as the study and applications of the unique characteristics and phenomena of nanometer size materials. Applications of nanotechnology fall into two categories (one is top-down and the other is bottom-up). Currently, most products are the results of the top-down approach. Nanofoods have distinct functional characteristics stemming from the size, mass, chemical combinations, electrolytic features, magnetic properties of food sources at the nano level and which can be applied for safe absorption and delivery into the body. The greatest advantage of nanofood is that it permits the efficient use of small quantities of nutritional elements by increasing digestive absorption ability and by delivering natural elements without any change in their original characteristics. On the other hand, there are still unsolved problems, such as questions about safety and introduction of harmful material. The demand for new commercial food products is increasing, and commercial food producers are gradually combining nanotechnology and traditional food preparation methods. Nanofoods will improve our eating habits remarkably in the future. Tomorrow we will design nanofoods by shaping molecules and atoms. It will have a big impact on the food and food-processing industries. The future belongs to new products and new processes with the goals of customizing and personalizing consumer products. Nanotechnology is expected to be applied to not only foods themselves, but also to food packaging, production, safety, processing and storage. Also, it is believed that nanotechnology will be applied tracking finished products back to production facilities and even to specific processing equipment in those facilities. The aim of this study is the introduction of technology, applications, products, markets, R&D, and perspectives of nanofoods in the food industry.

Pharmaceutical Study on Pranoprofen Argininate and Pranoprofen Lysinate (Pranoprofen Argininate 및 Pranoprofen Lysinate의 약제학적 연구)

  • Jee, Ung-Kil
    • Journal of Pharmaceutical Investigation
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    • v.17 no.4
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    • pp.197-204
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    • 1987
  • Novel pranoprofen algininate and lysinate salts were manufactured and their salt formation was confirmed by melting point, infrared spectroscopy, nuclear magnetic resornance spectroscopy, differential scanning calorimetry and powder X-ray diffractometry. The physical properties of pranoprofen lysinate and argininate salts were compared with those of pranoprofen through in vitro and in vivo tests. Solubility, $pK_a$ and lipid-water partition coefficient were measured through in vitro experiments, while antiinflammatory efficacy, analgesic effect, acute toxicity and in situ absorption were tested through in vivo experiments. The results obtained were as follows: 1) The solubilities of pranoprofen argininate and lysinate salts were increased markedly in pH 6.8 and pH 7.5 phosphate buffer solutions, comparing with that of pranoprofen itself. 2) $pK_a$ values of pranoprofen, pranoprofen argininate and lysinate salts were 6.34, 7.99 and 7.56 in carbon tetrachloride, and 5.86, 6.69 and 7.92 in chloroform, respectively by liquid-liquid partition method. 3) The lipid-water partition coefficients of pranoprofen argininate and lysinate salts were increased more than that of pranoprofen in carbon tetrachloride, chloroform, or benzene-pH 6.8 buffer system, but were nearly identical using pH 1.2 buffer as water phase. 4) Antiinflammatory effects of pranoprofen argininate and lysinate salts were remarkably increased and analgesic effects of the salts were as same as that of pranoprofen. 5) Pranoprofen argininate and lysinate salts were safer than pranoprofen itself in acute toxicity, and the in situ absorption rates of pranoprofen, pranoprofen argininate and lysinate salts were 0.392, 0.960 and $0.762\;hr^{-1}$, respectively according to the rat intestine recirculation experiment.

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