• 제목/요약/키워드: magnetic absorption

검색결과 340건 처리시간 0.027초

Dichlororhodium(Ⅲ) Complexes of N,N$^\prime$-Dimethylethylenediamine-N,N$^\prime$-diacetic Acid

  • Kim, Chang-Hwan;Jun, Moo-Jin;Jun, Jin-Seung
    • Bulletin of the Korean Chemical Society
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    • 제7권2호
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    • pp.145-147
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    • 1986
  • Dichlororhodium(Ⅲ) complexes of a flexible quadridentate ligand, N,N'-dimethylethylenediamine-N,N'-diacetic acid (dmedda), have been prepared. Both cis-${\alpha}$ and cis-${\beta}$ isomers have been yielded in the $K[Rh(dmedda)Cl_2]$ complexes, which were characterized with elemental analyses, electronic absorption and proton nuclear magnetic resonance spectroscopic data.

Spectroscopic Studies of Conjugated Uracil $Derivatives^+$

  • Chang Kiu Lee;Young Hie Kim
    • Bulletin of the Korean Chemical Society
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    • 제12권2호
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    • pp.207-210
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    • 1991
  • Ultraviolet spectra of 5-and 6-uracilyl compounds which contain conjugated double bonds were obtained and their characteristic phenomena were examined. 5-Formyluracil and 6-methyl-5-formyluracil showed bathochromic shifts which should be expected from a conjugated carbonyl compound. 6-Formyluracil did not show any shift in absorbing wavelength. 5-and 6-uracilylacrylic acid derivatives, on the other hand, showed absorption at similar wavelengths, indicating the presence of a hexatriene chromophore. The ratio of ${\Delta}ν/J$ in nuclear magnetic resonance spectra of those compounds decreased drastically as the acrylic acids or esters were converted into amides.

Preparation and Characterization of the L-prolino Co(III) Complexes with the Tetradentate $N_2O_2$-type Ligands

  • Jin-Seung Jung;Cheal Kim;Moo-Jin Jun
    • Bulletin of the Korean Chemical Society
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    • 제11권3호
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    • pp.235-238
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    • 1990
  • Complexes of the type[Co(T)(L-pro)], where T is the quadridentate $N_2O_2$-type ligand, N,N'-dimethylethylenediamine-N,N'-diacetate or N,N'-dimethylethylenediamine-N,N'-di-$\alpha$-butyrate, have been prepared. The complexes were separated into the two stereoisomers, $\Delta$-s-cis-[Co(T)(L-pro)] and $\Lambda$-s-cis-[Co(T)(L-pro)]. They were characterized by their proton magnetic resonance, absorption and circular dichroism spectra, elemental analyses.

Experimental investigation of organic fouling mitigation in membrane filtration and removal by magnetic iron oxide particles

  • Jung, Jaehyun;Sibag, Mark;Shind, Bora;Cho, Jinwoo
    • Membrane and Water Treatment
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    • 제11권3호
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    • pp.223-229
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    • 2020
  • Here magnetic iron oxide particles (MIOPs) were synthesized under atmospheric air and which size was controlled by regulating the flow rate of alkali addition and used for efficient removal of bovine serum albumin (BSA) from water. The MIOPs were characterized using field-emission scanning electron microscopy (FE-SEM), Fourier transformation-Infrared spectroscopy (FT-IR) and vibrating sample magnetometer (VSM). The results revealed a successful preparation of the MIOPs. The removal efficiency for BSA using MIOPs was found to be about 100% at lower concentrations (≥ 10 mg/L). The maximum adsorption of 64.7 mg/g for BSA was achieved as per the Langmuir adsorption model. In addition, microfiltration membrane for removal of BSA as model protein organic foulant is also studied. The effect of various MIOPs adsorbent sizes of 210, 680 and 1130 nm on the absorption capacity of BSA was investigated. Water permeability of the BSA integrated with the smallest size MIOPs membrane was increased by approximately 22% compared by the neat BSA membrane during dead-end filtration. Furthermore, the presence of small size MIOPs were also effective in increasing the permeate flux.

FeSiCr에 Fe50Ni가 첨가된 폴리머 복합 시트의 전자파 흡수 특성 (Electromagnetic Wave Absorbing Properties of FeSiCr and Fe50Ni Flaky Powder-Polymer Composite Sheet)

  • 이석문;김상문
    • 한국전기전자재료학회논문지
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    • 제27권7호
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    • pp.462-467
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    • 2014
  • In this paper, we studied the magnetic composite sheets for electromagnetic wave noise absorber of quasi-microwave band by using soft magnetic FeSiCr and Fe50Ni flakes with the thickness of about $1{\mu}m$ and polymer. The magnetic hysteresis curve including saturation magnetization and residual magnetization and the complex permeability characteristics of the composite sheets were investigated to clarify the mixing effect on electromagnetic wave absorption properties. The saturation magnetization was decreased about 10% while the residual magnetization was increased about 15% and the real parts of complex permeability at below 500 MHz were increased 0.6~4 while those values at above 500 MHz were decreased 0.4~2.5 according to the change of contents of FeSiCr and Fe50Ni powders. As a result, the reflection loss can be moved to the lower frequency from 2~3 GHz to 1~1.5 GHz as the contents of Fe50Ni flaky powder into FeSiCr flaky powder was increased up to 50%.

Extraordinary Optical Transmission and Enhanced Magneto-optical Faraday Effect in the Cascaded Double-fishnet Structure with Periodic Rectangular Apertures

  • Lei, Chengxin;Man, Zhongsheng;Tang, Shaolong
    • Current Optics and Photonics
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    • 제4권2호
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    • pp.134-140
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    • 2020
  • A significant enhancement of the magneto-optical Faraday rotation and extraordinary optical transmission (EOT) in the cascaded double-fishnet (CDF) structure with periodic rectangular apertures is theoretically predicted by using the extended finite difference time domain (FDTD) method. The results demonstrate that the transmittance spectrum of the CDF structure has two EOT resonant peaks in a broad spectrum spanning visible to near-infrared wavebands, one of them coinciding with the enhanced Faraday rotation and large figure of merit (FOM) at the same wavelength. It is most important that the resonant position and intensity of the transmittance, Faraday rotation and FOM can be simply tailored by adjusting the incident wavelength, the thickness of the magnetic layer, and the offset between two metallic rectangular apertures, etc. Furthermore, the intrinsic physical mechanism of the resonance characteristics of the transmittance and Faraday rotation is thoroughly studied by investigating the electromagnetic field distributions at the location of resonance. It is shown that the transmittance resonance is mainly determined by different hybrid modes of surface plasmons (SPs) and plasmonic electromagnetically induced transparency (EIT) behavior, and the enhancement of Faraday rotation is mostly governed by the plasmonic electromagnetically induced absorption (EIA) behavior and the conversion of the transverse magnetic (TM) mode and transverse electric (TE) mode in the magnetic dielectric layer.

Statistical Studies on the Physical Parameters and Oscillations of Sunspots and Flares

  • Cho, Il-Hyun;Cho, Kyung-Suk;Kim, Yeon-Han
    • 천문학회보
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    • 제41권2호
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    • pp.41.2-41.2
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    • 2016
  • We perform three statistical studies on the physical properties and oscillations in the confined plasma such as a photospheric sunspot and confined coronal loop. From the statistical studies on the sunspot umbra and its oscillation, we find that (1) the total magnetic flux inside the umbra for the three groups increases proportionally with the powers of the umbral area and the power indices in the three groups significantly differ from each other; (2) the three groups have different characteristics in their umbral area, intensity, magnetic field strength, and Doppler velocity as well as their relationships; (3) the mean frequency of the umbral oscillations increases with the umbral mean magnetic field strength and height; (4) the time delay of the core intensity of Fe I absorption line relative to the continuum which are de-convolved with the frequency range higher than 3.5 mHz is mostly positive, implying that the photospheric umbral oscillations are likely upwardly propagating; (5) the umbral mean plasma beta ranges approximately 0.6-1.1 and does not vary significantly from pores to mature sunspots. From the comparative study on the quasi-periodic pulsations (QPPs) in the solar and stellar flares, (6) we find that the power index of the periods scaling the damping times observed in the stellar QPPs is consistent with that observed in the solar QPPs, suggesting that physical mechanisms responsible for the stellar QPPs are likely the magneto-hydrodynamic oscillation of solar coronal loops.

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Detection of electromagnetic interference shielding effect of Hanji mixed with carbon nanotubes using nuclear magnetic resonance techniques

  • Byun, Young Seok;Chae, Shin Ae;Park, Geun Yeong;Lee, Haeseong;Han, Oc Hee
    • Carbon letters
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    • 제27권
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    • pp.90-97
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    • 2018
  • Electromagnetic interference (EMI) shielding is an important issue in modern daily life due to the increasing prevalence of electronic devices and their compact design. This study estimated EMI-shielding effect (EMI-SE) of small ($8-14{\times}17mm$) Hanji (Korean traditional paper) doped with carbon nanotubes (CNTs) and compared to Hanji without CNT using $^2H$ (92.1 MHz) and $^{23}Na$ (158.7 MHz) nuclear magnetic resonance (NMR) peak area data obtained from 1 M NaCl in $D_2O$ samples in capillary tubes that were wrapped in the Hanji samples. The simpler method of using the variation of reflected power and tuning frequency by inserting the sample into an NMR coil was also tested at 242.9, 158.7, and 92.1 MHz. Overall, EMI shielding was relatively more effective at the higher frequencies. Our results validated that NMR methods to be useful to evaluate EMI-SE, particularly for small, flexible shielding materials, and demonstrated that EMI shielding by absorption is dominant in Hanji mixed with CNT.