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Recycling of Waste Bittern from Salt Farm (I) : Recovery of Magnesium (염전 폐간수의 재활용(I) : 마그네슘 회수)

  • Na, Choon-Ki;Park, Hyunju
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.427-432
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    • 2016
  • The purpose of the research was to examine the utilization of waste bittern from salt farm as a source for producing magnesium (Mg). In this work, a precipitation process for recovering Mg, where Mg is precipitated as $Mg(OH)_2$ by the addition of NaOH solution, was investigated. At the NaOH/Mg molar ratios of 2.70 : 1 to 2.75 : 1 and pH 9.5-10, > 99% of Mg could be precipitated from the bittern. The molar concentration of NaOH solution added as an alkaline reagent had no significant influence on the recovery efficiency of Mg precipitate. The particle size of Mg precipitate was strongly affected by the flow rate of caustic addition. The faster the flow rate of caustic addition, the smaller particles were formed. The Mg precipitate recovered was 100-120 g per 1 L of bittern and contained 94% $Mg(OH)_2$ after washing with water. Our results showed that the bittern can be used as a potential resource for Mg production.

Coal particle distribution inside fuel droplets of high loading CWM (고부하도 CWM 연료방울안에 존재하는 미분탄 분포)

  • 김성준;유영길
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.2
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    • pp.618-629
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    • 1991
  • The purpose of this experiment is to understand the distribution of coal particles inside CWM droplet which is believed to be a very important factor controlling the flame stability. CWM slurry is atomized by an air assisted twin fluid nozzle. An experimental rig is designed and fabricated. The mean size of coal particle distribution in CWM slurry, atomizing air pressure, coal particle loading in slurry and sampling position inside spray are main experimental variables. The atomized CWM droplets are sampled on the thin white layer of magnesium oxide by the emergency sampling shutter. The sampled coal particles on magnesium oxide layers are collected into test tubes and dispersed completely by Ultra-Sonicator. The size distribution of coal particles inside droplets are measured by Coulter Counter. The presence of coal particle inside the impressions of droplets on magnesium oxide layer are investigated by photo technique. There are quite many droplets which do not have any coal particles. Those are just water droplets, not CWM droplets. The population ratio of droplets without coal particles to toal number of droplets is strongly affected by the mean size of coal particle distribution in slurry and this ration becomes bigger number as the mean size of coal particles be larger. The size distribution of coal particles inside CWM droplets is not even and depends on the size of droplet. Experimental results show that the larger CWM droplets has droplets has bigger mean value of particle size distribution. This trend becomes more evident as the atomizing air pressure is raised and the mean size of coal particles in CWM slurry is bigger. That is, the distribution of coal particles inside CWM dropolets is very much affected by the atomizing air pressure and the mean size of pulverized coal particles in CWM slurry.

Effects of Ethanol on Zinc, Calcium, Copper and Magnesium Conoentrations of Tissues in Rats (Ethanol 투여가 체내의 Zn, Ca 및 Mg의 함량에 미치는 영향)

  • Lee, Hyun Beom;Lee, Keun Woo;Hong, Kyung Tae
    • Current Research on Agriculture and Life Sciences
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    • v.7
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    • pp.221-230
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    • 1989
  • Present experiment was designed to investigate the effect of long-term ethanol drinking on the mineral contents on hair, liver, kidney and muscle tissues. Forty-five rats were divided into 2 experimental groups and a control group. The control group received tap water and the other 2 groups 4% and 25% ethanol respectively as drinking source for 28 days. All rats were dissected on the 29th day. Hair, liver, kidney and muscle samples were taken and analyzed for zinc, calcium, copper and magnesium contents by atomic absorption spectrophotometeric method. The results obtained are summrized as follows : 1) The zinc content of muscle in 25% ethanol group showed significant (P<0.01) decrease whereas that of hair in 4% ethanol group showed significant (p<0.1) increase. 2) The calcium content of hair in 4% ethanol group showed significant (p<0.1) increase whereas; that of hair, kidney and muscle in both group showed no significant difference. 3) The copper and magnesium contents of muscle showed significant (p<0.1, p<0.05) decrease in both groups. From these results it may be concluded that the long-term drinking of ethanol affects the mineral content of body tissue.

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Reaction of Organic Halogen Compounds with metals (Part III) Metal Distribution in the Reaction Products and System of a Reaction between Organo Chloro Acid or Ester and Metals under Various Solvents (有機할로겐化合物과 金屬과의 反應 (第 3 報) 有機클로로酸 및 에스터와 各種金屬과의 反應生成物 및 反應系中의 金屬分布에 關하여)

  • Kim, You-Sun
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.61-65
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    • 1965
  • Metal distribution in the reaction products and system of reactions between organo chloro acid or ester and zinc, silicon, magnesium, and tin under acetonitrile, dioxane, and toluene solvent were determined by means of radioactive tracer prepared by means of a (n, ${\gamma}$) reaction. It was found that the solubility of the organo halogen metal complex was markedly increased in a hydrophilic solvent and was decreased in a nonpolar solvent which resulted in an increased metal distribution in the recovered metal or water washing of the recovered metal mixture. This was also true in the case of the reaction conducted in the presence of a carbonyl compound. The relative increase of the solubility of the metal complex in a hydrophilic solvent was in order of zinc, silicon, tin and magnesium, and in a nonpolar solvent, it was in order of silicon, tin, magnesium, and zinc. There was no formation of organo metallics throughout the reaction sequence. The result was discussed and the observed solvent influence on the present reaction path was criticized.

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Solidification/stabilization of simulated cadmium-contaminated wastes with magnesium potassium phosphate cement

  • Su, Ying;Yang, Jianming;Liu, Debin;Zhen, Shucong;Lin, Naixi;Zhou, Yongxin
    • Environmental Engineering Research
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    • v.21 no.1
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    • pp.15-21
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    • 2016
  • Magnesium potassium phosphate cement (MKPC) is an effective agent for solidification/stabilization (S/S) technology. To further explore the mechanism of the S/S by MKPC, two kinds of Cd including $Cd(NO_3)_2$ solution (L-Cd) and municipal solid waste incineration fly ash (MSWI FA) adsorbed Cd (S-Cd), were used to compare the effects of the form of heavy metal on S/S. The results showed that all the MKPC pastes had a high unconfined compressive strength (UCS) above 11 MPa. For L-Cd pastes, Cd leaching concentration increased with the increase of Cd content, and decreased with the increase of curing time. With the percentage of MSWI FA below 20%, S-Cd pastes exhibited similar Cd leaching concentrations as those of L-Cd pastes, while when the content of MSWI FA come up to 30%, the Cd leaching concentration increased significantly. To meet the standard GB5085.3-2007, the highest addition of S-Cd was 30% MSWI FA (6% Cd contained), with the Cd leaching concentration of 0.817 mg/L. The S/S of L-Cd is mainly due to chemical fixation, and the hydration compound of Cd was $NaCdPO_4$, while the S/S of S-Cd is due to physical encapsulation, which is dependent on the pore/crack size and porosity of the MKPC pastes.

A Study on the Formation of Fouling in a Heat Exchanging System for River Water (하천수를 이용하는 열교환 시스템 내 파울링 형성에 관한 연구)

  • Sung, Sun-Kyung;Suh, Sang-Ho;Roh, Hyung-Woon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.646-651
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    • 2004
  • When the water flowing inside of the heat transfer equipments such as heat exchangers, condensers, and boilers is heated, calcium, magnesium sulfate, and other minerals in the water are deposited and built up for scales on the heat transfer surfaces. When those scales accumulate on the heat transfer surfaces, their performance of the heat transfer become progressively reduced due to the increase of the heat transfer resistance. The mechanism of this reduced heat transfer is called fouling. This study investigated the formation of the fouling in a heat exchanger with river and tap water flowed inside of it as a coolant. In order to visualize the formation of the fouling and to measure the fouling coefficients, a lab-scale heat exchanging system was used. Based on the experimental results, it was found that the formation of fouling for river water was quite different with the formation for tap water.

Trace (Minor) Elemental and Isotopic Compositions of Calcitic Skeletons in the Eastern Coast and Cheju Island, Korea (한반도 동해안과 제주도 연안에서 발견되는 방해석질 각질의 미량원소, 부원소 및 탄소와 산소 동위원소 함량의 변화)

  • Ji, Ok-Mi;Woo, Kyung-Sik
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.3 no.3
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    • pp.124-141
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    • 1998
  • The objectives of this study are to investigate the trace (minor) elemental and isotopic compositions of calcitic skeletons, such as barnacle, echinoid, branching and encrusting calcareous algae and oyster, from the eastern coast of Korean peninsula and Cheju Island, and to compare their variations with latitude, that is, the temperature of ambient seawater at which the skeletons grew. Articulated and encrusting red algae are composed of high-Mg calcite (7-21 mol% $MgCO_3$). Echinoids are also composed of high-Mg calcite (7-15 mol% $MgCO_3$). Whereas barnacles are composed of low-Mg calcite (1-5 mol% $MgCO_3$). The Mg compositions of articulated red algae, barnacle and oyster tend to increase with increasing water temperature, whereas those of encrusting red algae and echinoid do not show any trend. Sr compositions of articulated red algae, echinoid and barnacle tend to decrease with increasing water temperature, whereas those of encrusting red algae and oyster do not show any trend. Mn compositions of articulated red algae and encrusting red algae decrease with an increase of water temperature, whereas those of echinoid and barnacle do not show any trend. Fe compositions of articulated red algae tend to decrease with increasing water temperature, whereas those of encrusting red algae and oyster increase. Fe compositions of echinoid and barnacle do not show any trend with water temperature variations. Ba compositions of echinoid and low-magnesium calcitic skeletons do not show any trend with water temperature variations. Ba compositions of articulated red algae tend to decrease with increasing water temperature, whereas those of encrusting red algae increase. Cd and Pb compositions of all the skeletons tend to increase with increasing water temperature. Cu compositions of encrusting red algae increase with increasing water temperature, whereas articulated red algae, echinoid, barnacle and oyster do not show any trend. Zn compositions of high-magnesium calcitic skeletons and low-magnesium calcitic skeletons do not show any trend. Estimated water temperatures from oxygen isotopic data of all the skeletons except for the barnacle arc higher than the range of temperature of the shallow seawater of the East Sea and around Cheju Island. The oxygen isotopic compositions of oyster and echinoid are well clustered, and they do not show any trend with increasing water temperature. Therefore, this could reflect that the organisms have not secreted their shells in oxygen isotopic equilibrium with ambient seawater due to vital effect. Thus, the oxygen isotopic composition of barnacle can potentially be utilized for paleotemperature estimate whereas those of other organisms in this study may not be useful.

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Science and Technology on MgO Protecting Materials for ac Plasma Displays

  • Uchiike, Heiju;Hirakawa, Takayoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.705-709
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    • 2005
  • In order to clarify the heat annealing process for Magnesium Oxide (MgO), cathodoluminescent (CL) analysis was performed. Our results in the present work prove that the heat annealing has effects on not only removing water from the surface of MgO, but also increasing density of O and Mg defect pairs. It is the first work that the influence of annealing process on physical properties of the vacuum evaporated MgO thin films by using CL spectra.

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In vitro and in vivo evaluation of meloxicam capsule

  • Park, Sei-Yeon;Park, Young-Joon;Kang, Dae-Sik;Lee, Ho-Chan;Kang, Heui-Il
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.232.1-232.1
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    • 2003
  • Purpose. To develop a hard gelatine capsule containing meloxicam (Yuhan Meloxam capsule$\^$TM/), in vitro dissolution characteristics and bioavailability in beagle dog were compared with commercial product (Mobic capsule$\^$TM/). Methods. Meloxicam capsule$\^$TM/ was prepared by powder filling method using meloxicam, lactose, magnesium stearate, and others. The release of Meloxicam capsule$\^$TM/ and Mobic capsule$\^$Tm/ were monitored by USP dissolution method under various dissolution donditions - dissolution medium (pH 1.2, 4.0, 6.8 and water). (omitted)

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Comparison of Application Effects among Three Products of Granular Fused Magnesium Phosphate on Soybean Cultivation (대두(大豆)에 대한 입상(粒狀), 용성인비(熔成燐肥) 제품간(製品間)의 비효(肥效) 비교(比較))

  • Lim, Dong-Kyu;Kim, Seok-Cheol;Song, In-Kwan;Moon, Jae-Hyon;Choi, Du-Hoi;Kang, Hang-Won;Jung, Yeun-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.29 no.3
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    • pp.255-263
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    • 1996
  • This study was conducted to evaluate the application effects of three different granular fused magnesium phosphate products on soybean in a volcanic ash upland soil(Namweon series) of Cheju island. They were two domestic products(Kyunggi Chemical Industrial Co., LTD, Pungnong Biryo Industrial Co., LTD) and an imported Chinese product that were manufactured from different added materials. A powder fused magnesium phosphate. a single superphosphate(water soluble phosphatic fertilizer) and a fused superphosphate(mixed water soluble phosphate and 2% citric acid soluble phosphate) were presented as check fertilizers. Yield of soybean was the highest in the Pungnong product of granular fused magnesium phosphate. the next was the Chinese product imported and the Kyunggi product was the lowest but there was no statistical significance among the three granular products of fused magnesium phosphate. There was no clear tendency between yield and yield components of soybean plant however, the effects on the number of mainstem nodes, number of branches nodes and number of pods per plant were observed in the increased yield treaments. Phosphate concentration in stems and pods of soybean plant at harvesting stage was higher than those in stems of soybean plant during growing period. Uptake amounts and recovery rates of phosphate in stems and pods of soybean plant at harvesting stage were similar with the yield increasing tendency on soybean. In the changes of soil pH at different periods, the application of phosphatic fertilizers was increased soil pH. Soil pH in Chinese product was higher than domestic products, but it was similar to single superphosphate. The available silicate concentrations of soil were higher in the plot of Pungnong product than Chinese product.

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