• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.157-163
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• 2011

Combustion of magnesium dust particle were fabricated test devices and combustion experiments were carried out. The ignition delay time were measured in change of magnesium particle mass flow rate in premixed flame. According to increasing magnesium particle mass flow rate, ignition delay time were more shorter. In addition, magnesium dust combustion temperature were measured different particle sizes and o/f ratio by two wavelength pyrometry. Dust combustion flame temperature is almost similarly, through to equivalence ratio, confirm the combustion flame temperature range characteristics.

• Journal of the Korean Society of Industry Convergence
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• v.23 no.6_2
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• pp.927-934
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• 2020

Magnesium powder has been widely used in various industries because it is light weight and extremely high mechanical strength including aeronautics and chemicals. However, magnesium, as a combustible metal, poses serious safety issues such as fires and explosions if it is not managed properly. Especially, magnesium's max adiabatic flame temperature is 3,340℃ and it is impossible to extinguish it by using water, CO2 and Halonagents. The aim of this study is to identify the combustion characteristics of magnesium powder. We carried out a combustion experiment, using 1 kg of magnesium (purity > 99 %, particle < 150 ㎛). The features of the magnesium burning process were scrutinized using infrared thermal image analysis. Also, a field-emission scanning electron microscope (FE-SEM) were used employed to analyze particulate composites and properties. It concludes the significant tendency of magnesium fire and light, combustion carbide's particle characteristics. This study contributes to make better prevention and response manners to magnesium fires, as well as fire investigation measures.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.439-443
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• 2011

It was performed to test the combustive properties of low density polyethylene and ethylene vinyl acetate (LDPE-EVA) mixture by the addition of magnesium hydroxide. Flame retardant of natural magnesium hydroxide was added to the mixture of LDPE-EVA in 40 to 80 wt% concentration. The composite was compounded to prepare specimen for combustive analysis by cone calorimeter (ISO 5660-1). Comparing with virgin LDPE-EVA, the specimens including the magnesium hydroxide had lower combustive properties. It is supposed that the combustion-retardation properties in the composites improved due to the endothermic decomposition of magnesium hydroxide. The specimens with magnesium hydroxide showed both the lower peak heat release rate (PHRR) and lower effective heat of combustion (EHC) than those of virgin polymer. As the magnesium hydroxide content increases, time to ignition increased and the peak heat release rate decreased.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.311-316
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• 2010

The ignition and the burning characteristics of aluminum and magnesium particles ($30-110{\mu}m$ in diameter) isolated due to electrodynamic levitation were experimentally investigated. The burning time, the ignition delay time, the flame temperature, and the flame diameter were measured. The thermal radiation intensity was measured using the photomultiplier tube and the combustion history was monitored by high-speed cinematography. Two-wavelength pyrometry measured the temperature of the burning particles. The burning times of aluminum particles were measured approximately 5 to 8 times longer than those of magnesium particles. Exponents of $D^n$-law, for the burning rate of magnesium and aluminum particles of diameters less than $110{\mu}m$, are found to be 0.6 and 1.5, respectively. The instant of aluminum ignition is clearly distinguished with the ignition delay time little less than 10 ms, however the burning history of magnesium particle exhibits no distinct instant of the ignition. The ignition delay time of magnesium particle (less than $110{\mu}m$) were approximately shown in the range from 50 to 200 ns. The flame temperatures of single metal particles are lower than the boiling point of the oxide. The nondimensional flame diameters for magnesium are decreased with increasing of the diameter. The nondimensional flame diameters for aluminum are not changed significantly.

• Journal of the Korean Society of Industry Convergence
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• v.24 no.6_2
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• pp.795-800
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• 2021

Magnesium fires require early fire extinguishment due to impulsive and rapid-fire expansion that makes difficult fire fighting. For this reason, efficient early fire fighting and appropriate prevention of fire spread are considered mainly as significant fire extinction measures. However, there is a limit to developing tools for metal fire fighting, such as devices, facilities, and fire extinguishing agents, due to a lack of regulatory instruments in South Korea. It often generates challenges to early fire fighting implementation by fire responders. Thus, the aim of this study is to investigate a measure for securing the efficiency of early fire fighting in magnesium. This study identified the applicability of the metal fire extinguisher used in the United States for magnesium fire through a performance test of a fire extinguishing agent for metal fire. Moreover, we implemented a free burning experiment using magnesium powder to compare varying combustion and extinction process that could occur during applying metal fire extinguishers. Finally, this study suggests measures of the use and application of metal fire extinguishers for magnesium.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.6
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• pp.324-327
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• 2009

In the present study, the effect of Ca additions on the ignition and combustion behaviors of Mg alloys has been investigated. Cracks and inclusions were observed at the free surface and interior in as-cast pure magnesium but not in Ca-bearing Mg alloys. There was a tendency that ignition temperature rapidly increased with increasing Ca content in Mg-Ca alloy. Saturated composition for increasing of ignition temperature was related with solid solubility of Ca in Ca-bearing Mg alloys. The protective oxide layers, MgO, could also be found on the combustion surface of Ca-bearing magnesium alloy.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.341-350
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• 2011

A simplified analytical study for micro-sized single metal particle combustion in air was conducted in the present study. The metal particle combustion consists of two distinct reaction regimes, ignition and quasi-steady burning, and the thermo-fluidic phenomena in each stage are formulated by virtue of the conservation and transport equations. When particle temperature reaches to 1200 K, ended an ignition stage and was converted at quasi-steady combustion stage. Effects of Initial particle size, convection, ambient pressure and temperature are examined and addressed with validation.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.1
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• pp.12-19
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• 2022

The propellants used in the gas generator of the ducted rocket are fuel-rich propellants, which contain an excessive amount of metal fuel and a small amount of oxidizing agent compared to general solid rocket propellants. In this paper, boron powder and MgAl(Magnesium-Aluminium alloy) were applied to produce fuel-rich propellants. The optimum formulation was determined by characterizing these metal fuel-rich propellants. Analysis of combustion products in the gas generators confirmed that the fuel-rich propellants containing fine boron powder itself instead of boron-bead could be useful in gas generators.

• Proceedings of the Materials Research Society of Korea Conference
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• 2001.11a
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• pp.25-25
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• 2001

• Journal of the Korea Institute of Military Science and Technology
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• v.17 no.3
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• pp.387-393
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• 2014

The combustion pressure and thrust of aft-igniter were measured to investigate the characteristics of ignition charge. Granule and pellet shape ignition charge of $BKNO_3$ and MTV(Magnesium-Teflon-Viton) were used for igniters. Ignitions with granule charges show abrupt increases of combustion pressure and thrust compared to those of pellet charge. $BKNO_3$ igniter shows higher combustion pressure than MTV igniter due to higher combstion rate. Mg particle size affects the combustion pressure of MTV igniter.