• Title/Summary/Keyword: magnesia cement

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Fundamental Properties of Magnesia-Prosphate Composite Considering Mix Conditions and Curing Temperature (배합조건 및 양생온도에 따른 마그네시아 인산염 복합체의 기초물성 평가)

  • Cho, Hyun Woo;Kang, Su Tae;Shin, Hyun Seop;Lee, Jang Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.163-170
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    • 2012
  • With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

An Experimental Study on Quality Properties of Living Concrete Using Loess-Magnesia Composites (황토-마그네시아 복합체 활용 Living Concrete의 품질특성에 관한 실험적 연구)

  • Yun-Wang, Choi;Young-Woo, Na;Yong-Woo, Kwon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.498-505
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    • 2022
  • In this study, as a result of eva lua ting the quality properties of Living Concrete, the flow of the table showed a tendency to decrease as the mixing ratio of ocher increased. Compressive strength was found to decrease with increasing loess mixing ratio. Density properties were evaluated for weight reduction, As a result of comparison with the panel using cement as a comparison group, the density was measured to be a bout 20 % lower than that of the cement panel, and it is judged that it is less affected by the load and can be installed in the structure. As a result of evaluating the panel temperature reduction, there was a difference in the temperature reduction with time. It is judged that the panel planted with moss has a lower temperature than the panel without moss, so it is judged that it can be used in a vertical greening system.

Effect of Phosphate-to-binder and Water-to-binder Ratio on Magnesia-potassium Phosphate Cement (마그네시아-인산칼륨 시멘트에 대한 인산염 비 및 물-결합재비의 영향)

  • Lee, Kyung-Ho;Yoon, Hyun-Sub;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.29 no.3
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    • pp.275-281
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    • 2017
  • This study examined the effect of water-to-binder ratio (W/B) and phosphate-to-binder ratio (P/B) on the flow, setting time, compressive strength development, and pH variation of magnesium-potassium phosphate composites, MKPC mortars. Ten mortars mixtures were prepared with the W/B varying from 20% to 40% at each P/B of 0.3 or 0.5. The hydration products and microstructural pore distribution of the MKPC pastes were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP). The initial flow and setting time of MKPC mortars tended to decrease with an increase of P/B, indicating that the final setting time was shortened by approximately 24% when P/B increased from 0.3 to 0.5. The slope of the early-strength development measured in the MKPC mortars was considerably higher than that of cement concrete specified in code provisions. For obtaining a relatively good 28-day strength (above 30 MPa) and a near neutral pH (below 9.0) in MKPC mortars, the P/B and W/B need to be selected as 0.5 and 30%, respectively. The strubite-K crystal increased with the increases of P/B and W/B, which leads to the decrease of the macro-capillary pores.

Proper Mixing Ratio for Securing Quality of Free-form Panel (비정형 패널의 형상 품질확보를 위한 적정 배합비 도출)

  • Kim, Min-Sik;Park, Chae-Wool;Kim, Ki-Hyuk;Do, Sung-Lok;Lee, Dong-Hoon
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.5
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    • pp.449-456
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    • 2019
  • Recent developments in architectural technologies and programs have enabled architects to think creatively and design free-form architecture. however, there are many problems in the production technology of FCP(Free-Form Concrete Panel). In particular, reduced accuracy due to lack of free-form panel production technology can lead to redesign of buildings as a result, problems such as an increase in construction cost and period. Therefore, this experiment aimed to compensate the decrease of the accuracy according to the displacement difference and to derive the proper mixing ratio for maintaining the shape during the free-form panel curing. In this study, molds were made using paraffin that is a recyclable phase change material. Concrete Panel is usually produced from Portland cement, dead burn magnesia, phosphate, borax and fine aggregate. In this study, four mixing ratios of FCP were selected after each material was blended to determine the proper blending ratio of the fluidity phase, the water absorption rate and the water content of the test piece. FCP was fabricated on the basis of the selected four compounding ratios and thickness and error rate were measured. Based on the error rate of the measured FCP, the quality standard was satisfied among the four compounding ratios.

A Effect of Chemical Composition and Replacement Ratio of Limestone Admixture on Initial Cement Characteristics (석회석 혼합재의 화학성분과 치환량이 시멘트 초기 물성에 미치는 영향)

  • Dong-Kyun Suh;Gyu-Yong Kim;Jae-Won Choi;Kyung-Suk Kim;Ji-Wan Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.440-448
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    • 2023
  • Utilizing admixture, which is one of the raw material replacement method in the cement industry, is expected to be easily and quickly put to practical use as it is relatively more accessible than other methods. Among cement admixtures, limestone powder is reported to be able to improve cement performance through nucleation effects, chemical effects, and filler effects, so it is a material expected to be suitable as a cement admixture. Meanwhile, as high-quality limestone is depleted around the world, the use of limestone with clay or high magnesia (MgO) content is becoming increasingly inevitable. Therefore, in this study, we attempted to evaluate the suitability of limestone cement as a admixture by measuring the basic properties of limestone cement mixed with limestone of different qualities commonly used in Korea. As a result, the effect of alite reaction promotion was confirmed regardless of the chemical composition of the limestone binder. However, the dilution effect depending on the substitution amount was greater than the chemical composition. It is believed that normal-grade limestone can be used as a mixture as long as the limestone content in cement is within 15 % in this scope of study. In the future, we plan to evaluate the impact of the chemical composition of the limestone mixture through additional experiments depending on the chemical composition of cement.

Eco-Friendly and Thermal Conductivity Properties of Magnesium oxide Matrix Utilizing Bentonite (벤토나이트를 활용한 산화마그네슘 경화체의 친환경성 및 열저항 특성)

  • Gwon, Oh-Han;Lim, Hyun-Ung;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.64-65
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    • 2016
  • This study that prevent cancer using absorbent to inflow Radon gas in the room existing soil and rock is making board to absorb the Radon gas as a fundamental study. So, we use bentonite as a absorbent. So, we use bentonite as a absorbent. Bentonite is a 'clay mineral' composed to montmorillonite of main component that volcanic ash denatured to a clay mineral. Bentonite has fine microparticle of nano level, abundant mineral 66 of kinds, adsorbability, swelling, a positive ion(heavy metal adsorption reaction) as a bentonite's property. Using magnesia cement for oxide of magnesiuma and magnesium chloride as a main binder, we measure Radon gas absorbent efficiency and thermal conductivity.

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Physical Properties of Artificial Interior stone Using Waste Resources (폐자원을 활용한 내장용 인조석재의 물리적 특성)

  • Yoo, Yong-Jin;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.237-243
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    • 2014
  • The environmental problem is serious due to global warming In a concrete industry, the effort to reduce the problem of the destruction of environment arising from the indiscriminate use of limestone that is the raw material of cement and aggregate and the exhaustion of resources are continually emphasized In this research, the waste porcelain and waste glass that are the natural aggregate substitute materials were mixed and were applied. In addition, the magnesia phosphate composite and fly ash are mixed with a cement substitute material and the properties of the artificial stone was examined. Density, water absorption, rate of aggregate on the surface, compressive strength, and flexural strength were performed. As a result of the test, it is that waste glass with 60% and waste porcelain with 70% are the most excellent mix to produce the artificial stone.

The Patent Analysis of the Treatment Technology of Asbestos Wastes (석면 폐기물 처리 특허기술 분석)

  • Kim, Jong-Heon;Cho, Jin-Dong;Lee, Sang-Kwon;Cha, Seong-Ki
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.451-462
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    • 2011
  • Asbestos or its applications have been used for long times and for various purposes in our life because of their merits, namely fire resistance, electric insulation and chemical resistance capacity etc. Despite of theses many merits, one of the problems of asbestos is shown toxicity according to its fiber type. So we need data to solve about this problem. In this paper, we study on the technical method of asbestos waste treatment and on the trends of asbestos researches and developments by the analysis of its patents and DWPI database materials. As a result, the asbestos-waste treatment data in the its related patents is used 267 cases to analyze. These data are divided into 86(32.5%) cases of solid waste disposal(B09B). 41(16.6%) cases of separation(B01D) and 27(10.2%) of lime, magnesia, slag, cement and their composites(C04B).