• Clean Technology
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• v.13 no.4
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• pp.281-286
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• 2007

VOCs from the heat recovery ventilation system (total heat exchanger) are measured in this study. Two different types of element (L and M type) from heat recovery ventilating system are tested to study the intial release characteristics of VOCs under KS cooling and heating standard conditions. VOCs are measured for the various flow rates and different operating times. Considering errors in the test method and the measuring instrument, the tested heat recovery ventilating systems was found to release 6 major VOCs, such as acetic acid, 2-butanone (MEK), 2-(methylthio )ethylamine, toluene, styrene, and x-acids (Ion 57). The concentrations of released VOCs are not quite much affected by operating conditions. The results show much larger VOCs concentrations in the cooling mode than in the heating mode, due to the high operating temperatures.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.1
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• pp.73-77
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• 1998

In this study, a total of 10 volatile organic compounds (VOCs) including BTEX were determined in the inside and outside of a highway thnnel in order to evaluate the emission profile of automobile exhaust with respect to the concentrations, relative ratio and correlation coefficient of target analytes. In addition to VOCs, CO $CO_2 and NO_2$ were measured simultaneously. The results of this study indicated that the most abundant compound was toluene followed by benzene and m+p-xylenes, and the correlation coefficients between VOCs except styrene were higher than 0.96. The concentration ratio of toluene, ethylbenzene, xylenes with respect to benzene measured in the inside of tunnel was 1.5, 0.13, 0.74, respectively. Such ratios were found to be very similar to those measured in tunnels in the USA.

• Proceedings of the Korea Information Processing Society Conference
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• 2023.05a
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• pp.609-611
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• 2023

4차 산업혁명의 발달로 스마트공장 기술이 발달하면서, 딥 러닝을 활용한 공정 과정에서 나타나는 이상을 탐지하는 기술이 활발히 연구되고 있다. 하지만 공정 과정에서 발생하는 휘발성유기화합물(VOCs) 저감 설비에서 발생하는 이상을 탐지하기 위한 연구는 적극적으로 진행되고 있지 않다. 따라서 본 논문에서는 딥 러닝 기술을 이용하여 VOCs 저감설비에서 발생하는 이상을 탐지하고, 설명가능 인공지능(XAI)을 활용하여 이상에 큰 영향을 미치는 주요 설비를 특정하여 이상 발생 시 관리자가 용이하게 설비들을 관리할 수 있도록 하였다.

• Clean Technology
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• v.19 no.2
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• pp.134-139
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• 2013

VOCs such as formaldehyde and benzene in a control chamber were adsorbed onto gypsum incorporating oyster shell powder, which was solidified and dried. VOC was first exposed in air and then gypsum mortar was placed in the chamber for 180 min for adsorption. The mortar was prepared with 0, 10, 30, and 50% of oyster shell powder. Two initial concentrations of VOCs including formaldehyde were $27.7{\sim}28.5mg/m^3$ or $175{\sim}150{\mu}g/m^3$. We found out that the initial concentrations did not seem to make any difference in adsorption performance but higher oyster content strongly led to higher adsorption. We used a convection-diffusion-adsorption model to compare the experiment. The model which considers diffusion coefficients of adsorbates and affinity of the adsorbents well represented the experimental data with a fair agreement.

• Journal of the Korea Furniture Society
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• v.27 no.4
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• pp.335-342
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• 2016

In previous study, volatile organic compounds (VOCs) emission characteristics were highly affected by coating materials for wood finishing. Natural based coating materials showed that about 15~46% lower TVOC emission than typical products. In this study, long-term changes of VOCs emission characteristics from pine panel with three types of coating treatments were determined. Non-treated pine panel emitted $604.7{\mu}g/m^2{\cdot}h$ of TVOC that contained 66% of NVOC ($399.7{\mu}g/m^2{\cdot}h$) at 0 month. After 10 month, TVOC reduced 88% and 93% reduction on NVOC was observed. Natural oil and waterborne stain treated pine panel showed 61% and 77% lower TVOC, respectively, than non-treated pine panel. However, TVOC from finished pine panels showed higher TVOC emission than non-treated pine panel. All samples satisfied the VOC emission regulation (below $4,000{\mu}g/m^2{\cdot}h$) by Korean Ministry of Environment. Toluene emission regulation (below $80{\mu}g/m^2{\cdot}h$) was passed on all sample without varnish treated pine panel at 0 month. According to HB qualification standard for construction materials by Korea Air Cleaning Association (KACA), wood is not qualified to get the best tag due to high TVOC emission. At the 10 months, only non-treated pine panel could get the best tag of HB from KACA.

• Journal of Environmental Science International
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• v.18 no.5
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• pp.517-525
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• 2009

We measured ambient concentrations of hazardous air pollutants such as volatile organic compounds (VOCs) and aldehydes in residential areas nearby small and medium scale shipbuilding companies. The VOC concentrations were higher during the normal operation periods than vacation at which almost all operations were shutdown. Concentrations of VOCs was higher, as the sampling site was nearer from shipbuilding companies. The major components of VOCs were m,p-xylene, ethylbenzene, o-xylene, toluene, and 1,3,5-trimethylbenzene which had been found as major VOC compounds emitted from painting processes of shipbuilding in the previous studies. The major components of aldehydes analyzed were benzaldehyde, acrolein, formaldehyde, and acetaldehyde. The concentration of aldehydes was highest at the furthest sampling point from shipbuilding companies because the formation of aldehyde compounds could be occurred by the secondary chemical reactions of VOCs. The results of this study shows a proper counterplan need to be established for the reduction of hazardous air pollutants emitted from small and medium scale shipping companies.

• Clean Technology
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• v.24 no.4
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• pp.280-286
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• 2018

In this study, the adsorption performance of vapor phase VOCs under dry conditions was evaluated by using two metal oxides, $TiO_2$ powder and $Al_2O_3$ powder. BET analysis and ammonia in-situ FT-IR analysis were used to analyze specific surface area and surface acid site. As a result, $TiO_2$ powder and $Al_2O_3$ powder had a specific surface area of $317.6m^2\;g^{-1}$ and $64m^2\;g^{-1}$, respectively. In the case of $TiO_2$ powder, many acid sites were observed on the surface. As a result of evaluating the vapor phase VOCs adsorption performance using two metal oxide powders, $TiO_2$ powder having a relatively large specific surface area and a large number of acid sites exhibited relatively good adsorption performance. In particular, it is considered that the specific surface area directly affects the adsorption performance, and further study on the effect of the acid site is required. Based on the $TiO_2$ exhibited excellent adsorption performance, it manufactured into various forms of honeycomb, hollow fiber and disc. As a result, the adsorption performance was lower than that of the powder, but it is advantageous in view of applicability. In addition, it was confirmed that the disc adsorbent having excellent thermal durability due to the characteristics of the manufacturing process stably maintains adsorption performance even at a high temperature desorption process several times.

• Analytical Science and Technology
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• v.20 no.6
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• pp.474-482
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• 2007

Daycare centers are an important indoor environment for pre-school children and exposure area with potential harmful health effects for infants and children who spend most of their daily life. Sampling was undertaken at 29 daycare centers located Seoul in Korea from January, 2006 to December 2006. The target compounds were 7 individual volatile organic compounds (benzene, toluene, ethylbenzene, m,p-xylene, styrene, o-xylene, TVOC). The mean concentrations of TVOC, toluene, m ,p-xylene, ethylbenzene, benzene and styrene in daycare centers were $318.7{\mu}g/m^3$, $51.6{\mu}g/m^3$, $11.7{\mu}g/m^3$, $6.5{\mu}g/m^3$, $4.2{\mu}g/m^3$, $3.6{\mu}g/m^3$, respectively. Toluene occupied 17.6 % of the concentration of individual VOCs. The ratio of indoor and outdoor (I/O) of TVOC and toluene were 2.0 and 1.6, respectively. The results of characteristics according to a season of a year, the concentration of TVOC were measured $433.9{\mu}g/m^3$, and these concentrations during third quarter of the year in summer were higher than the other season. In the other four seasons, TVOC were measured 280.5 in winter, 298.3 in spring and $264.6{\mu}g/m^3$ in fall, respectively.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.2
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• pp.87-96
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• 2017

In this study, 4 gases containing typical chlorinated volatile organic compounds (VOCs) were treated by ultraviolet (UV) irradiation. The typical chlorinated VOCs are dichloromethane (DCM), trichloromethane (TCM), carbon tetrachloride (CTC) and trichloroethylene (TCE). The removal efficiency (RE) and the products of chlorinated VOCs by UV irradiation are investigated. At this time, 2 types of background gas (air and nitrogen) were used to figure out the RE by photooxidation and photolysis. The specification of UV-lamp used in this study was low-pressure mercury lamp emitting wavelength of 185~254 nm. The experimental conditions were set as initial VOC concentration of $180{\pm}10ppm$, empty bed retention time (EBRT) of 53 s, temperature of $23{\pm}2^{\circ}C$ and relative humidity of $65{\pm}5%$. In the photolysis condition with nitrogen ($N_2$) as background gas, the averaged RE of the 4 types of chlorinated VOCs was about 24% higher than that with photooxidation; and the REs of VOCs except CTC were confirmed as >99%. The composition of off-gases after UV photooxidation in air was investigated and several intermediates from DCM, TCM and TCE were detected by GC/MS. Among them, phosgene which is a toxics was detected as an intermediate of TCM. In addition, the concentration of carbon dioxide ($CO_2$) in the off-gases was measured to calculate the mineralization rate (MR). With the photooxidation, TCE showed the highest RE (>99%) while MR was the lowest (17%); and the MR of DCM was the highest (86%). In addition, particulate matters (PM) in the off-gases was also detected and high concentrated $PM_{10}$ ($21,580{\mu}g{\cdot}m^{-3}$) and $PM_{2.5}$ ($6,346{\mu}g{\cdot}m^{-3}$) were detected in TCE off-gas. More than 99% of the chlorinated VOCs could be removed using UV254-185 nm lamp, while it is necessary to conduct further studies on the production and treatment of secondary pollutants.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.27 no.1
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• pp.59-69
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• 2017

Objectives: The objective of this study is to evaluate the exposure of VOCs and effects of the chemicals on the nail technicians whose works in a nail shop. Methods: For four month from May to August in 2016, we measured twenty-two kinds of VOCs in ten nail shops and carried out health examinations on thirty-four workers in there. Results: The TVOC concentration in indoor air of nail shops is $0.487mg/m^3$ at a minimum and $33.236mg/m^3$ at a maximum where it consists of 70.5% of Ketones, 25.4% of Alcohols, 2.6% of Esters, 0.8% of Aldehydes and 0.7% of Aromatics. The VOCs concentration during nail art works shows an increase in average ratio 1.8 compared to the concentration of indoor air quality and also the concentration of Isopropanol rose with 3.2 of the highest ratio. The results of Spearman correlation between TVOC concentration in indoor air and environmental factor was like that has significance level of correlation(${\rho}$<0.05, r=0.682) in case of number of customers per day, but the other factors were not meaningful in correlation. Correlation between VOCs and medical check-up items was like that has positive significance level(${\rho}$<0.01, r=0.638) between isopropanol and GPT, but the others have not meaningful. The exposure level of VOCs was not exceed the criteria exposure level 1 of working environment measuring method which announced by labor ministry in all ten nail shop indoor air quality. Conclusions: In this study although it was not significant correlation between harmful substances and medical check-up items in the nail shop indoor air quality, it is necessary to do more ventilation and to install exhaust facilities because of existing high VOCs concentration in the nail shop indoor air.