• 제목/요약/키워드: lyotropic

검색결과 34건 처리시간 0.021초

Solvent-Assisted Soft-Lithographic Patterning of Lyotropic Liquid Crystalline Polymer Film by Flow Control through Patterned Channels

  • Park, Chang-Sub;Park, Kyung-Woo;Kang, Shin-Won;Kwak, Gi-Seop;Kim, Hak-Rin
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.641-644
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    • 2009
  • We demonstrated a solvent-assisted soft-lithographic patterning method for producing patterned structure and patterned ordering with lyotropic liquid crystalline polymer (LCP) film. Experimental results showed that the liquid crystalline ordering of lyotropic film could be controlled by shearing effects of the fluidic solvent though the patterned mold channels. In this work, two types of lyotropic LCPs were used to investigate the effects of the alkyl chain length of the lyotropic LCP on producing liquid crystalline ordering through the solvent-assisted fluidic patterning.

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Lyotropic Mesomorphisms of a Lamellar Liquid Crystalline Phase in Non-hydrous Condition: A Phospholipid Hydrated by Different Polar Solvents

  • Lee, Dong-Kyu;Jeong, Kwan-Young
    • Bulletin of the Korean Chemical Society
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    • 제31권5호
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    • pp.1165-1171
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    • 2010
  • The lyotropic mesomorphism of lamellar liquid crystalline phase was examined by observing the swelling behavior of Distearoylphosphatidylcholine(DSPC) in glycerin and panthenol without water. The lyotropic mesomorphism was examined by using DSC, XRDs and Cryo-SEM. Increase of two polar solvents under non-hydrous condition showed distinctive differences in the lyotropic mesomorphism from forming different anisotropic structures with DSPC. Glycerin did not affect to the crystalline region of lamellar phase, whereas typical swelling mesomorphism was shown in the noncrystalline region. In contrast, panthenol showed some effect on the crystalline region, but common swelling mesomorphism was found in the non-crystalline region. In this case, the isopropyl and propyl groups in panthenol were the main factor to affect to the lipophilic domain in the crystalline region of lamellar phase. Also, it was found that the formation of well-arranged lamellar structure only by introducing glycerin and panthenol as a solvent without water, was possible. These results were confirmed by examination of the swelling mesomorphism of liquid crystal membrane triggered by introducing the two polar solvents.

Novel Coatable Polarizer Based on Polymer-Stabilized Lyotropic Chromonic Liquid Crystals

  • Bae, Yun-Ju;Jeong, Kwang-Un;Shin, Seung-Han;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.517-519
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    • 2009
  • We fabricated thin film polarizer by coating lyotropic chromonic liquid crystals (LCLCs) dissolved in anionic monomer solution. Compared to water-based technique, the new method provided many advantages such as excellent coatability, good adhesion to various substrates, and superb surface hardness.

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Lyotropic Chromonic Liquid Crystals: Effects of Additives and Optical Applications

  • Park, H.S.;Tortora, L.;Vasyuta, R.M.;Golovin, A.B.;Augustin, E.;Finotello, D.;Lavrentovich, O.D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.307-310
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    • 2007
  • We describe effects of ionic and neutral additives on phase and structural behavior of the lyotropic chromonic liquid crystals used in preparation of optical elements such as polarizers and compensators.

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O-and E-polarizers and advanced optical films for LCDs based on Lyotropic Dichroic Dyes

  • Belyaev, S.V.;Khan, I.G.;Malimonenko, N.V.;Kleptsyn, V.F.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.361-364
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    • 2004
  • Polarizers with high polarizing efficiency and other advanced optical films based on Lyotropic Dichroic Dyes have been developed for LCD and other applications. The developed optical films reveal both rod-like chromophores structure in a case of positive, or O-films and disc-like one for negative, or E-film.

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Manufacture of Photopatterned Coatable Polarizer Using Lyotropic Chromonic Liquid Crystal Based on Perylene

  • Bae, Yun-Ju;Jeong, Kwang-Un;Shin, Seung-Han;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1447-1449
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    • 2009
  • We report the syntheses bis-(N,N-diethylaminoethyl) perylene-3,4,9,10-tetracarboxylic diimide (PDI) of lyotropic chromonic liquid crystal and it dissolves in photocurable ionic monomer solution. PDI-acrylic acid solution was observed whether liquid crystal phase appeared in each concentration. Thin film polarizer was prepared by simultaneously coating and aligning the solution of PDI-acrylic acid (in the chromonic nematic phase) onto glass substrates using a mechanical shearing force and was cured by irradiation of UV light. Also Photopatterned polarizer is manufactured by same process.

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Lyotropic Chromonic Liquid Crystals in Aligned Films for Applications as Polarizing Coatings

  • Schneider, Tod;Golovin, Andrii;Lee, Jong-Chan;Lavrentovich, Oleg D.
    • Journal of Information Display
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    • 제5권2호
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    • pp.27-38
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    • 2004
  • We describe dried oriented films with anisotropic structural and optical properties prepared from the aqueous solutions of plank-like molecules, the so-called Lyotropic Chromonic Liquid Crystals (LCLCs). The dried LCLC films may be used as optical elements, such as polarizers, compensators, color filters, or retardation plates in the UV, visible, or infrared parts of spectrums. The optical quality of the films is determined by the uniformity of the molecular alignment, which often distorted by periodic variations of the director field. We describe different ways to improve the alignment properties of the films by using additives. We present compositions capable of polarizing effects in visible and UV parts of spectrum.

액정 고분자 HIQ-40의 열처리에 의한 기체전달 특성 변화 (The Effect of Thermal Annaling on the Gas Transport Properties of Liquid Crystalline Polymer HIQ-40)

  • 박진용
    • 한국막학회:학술대회논문집
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    • 한국막학회 1995년도 추계 총회 및 학술발표회
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    • pp.22-28
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    • 1995
  • Since the discovery of liquid crystallinity by Reinitzer [1] in 1988 as he studied the melting behavior of cholesteryl benzoate, anisotropic structural ordering in fluid phases has been of considerable interest to chemists, physicists and other scientists. Polymers which exhibit liquid crystallinity either in solution (lyotropic) or in the neat state upon heating (thermotropic) have both theoretical and practical importance [2]. Du Pont's Kevlar, a high modulus polyamide fiber spun from a lyotropic solution, is a prime example of such an application.

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