• Journal of Adhesion and Interface
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• v.10 no.2
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• pp.106-112
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• 2009

In the present work, novel biocomposites made with biodegradable Lyocell woven fabrics and poly (butylene succinate) were successfully fabricated for the first time. Lyocell/poly(butylene succinate) biocomposites with different fiber loadings of 0, 30, 40, 50 and 60 wt% were prepared by compression molding with a sheet interleaving manner. The effect of Lyocell fabric loading on the interlaminar shear strength, tensile and flexural properties, heat deflection temperature, thermal expansion behavior, and thermal stability of the biocomposites was investigated. The properties strongly depended on the fabric loading and the results were consistent with each other. It was demonstrated that the Lyocell fabrics played a remarkable role in improving the properties of poly(butylene succinate) resin by incorporating the fabrics into the resin. The greatest inter-laminar, tensile, flexural and thermal properties of the biocomposites were obtained with Lyocell fabrics of 50% by weight.

• Proceedings of the Korean Fiber Society Conference
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• 2000.04a
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• pp.295-298
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• 2000

• Fiber Technology and Industry
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• v.6 no.1_2
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• pp.1-16
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• 2002

• Journal of the Korean Society of Safety
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• v.31 no.1
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• pp.66-73
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• 2016

Lyocell fibers were used as a precursor in order to improve yield and strength of cellulose-based precursor while manufacturing activated carbon fiber(ACF). Lyocell fibers as a precursor for the preparation of ACF were surface-modified by reaction with 3-aminopropyltriethoxysilane(APTES) and pre-treated with KOH and H3PO4. Using aforementioned precursor, ACFs were prepared by a series of stabilization, carbonization and activation process at high temperatures. On each process, FT-IR, TGA, UTM and SEM were used to observe fibers' physical properties including structure and porous surfaces. FT-IR results proved that surface modification was achieved during stabilization, carbonization and activation process. TGA results during carbonization process found that surface modified fibers with APTES 0.02 mol(A2) showed higher thermostability, and extended pre-treatment increased yield. Especially, yield was found to have an increase of 10~20 wt% with surface modification during activation process. UTM results showed that tensile strength has the same order of concentration of APTES after surface modification, however, was found to show lower tensile strength than lyocell fibers after stabilization process. SEM results revealed that more homogeneous porosity control could be proceed after modifying the surface for the effective removal of hazardous substances.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.211-214
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• 2002

셀룰로오즈/아민 옥사이드(NMMO) 수화물 계로부터 제조되는 Lyocell 섬유는 기존의 재생 셀룰로오즈 섬유에 비해 우수한 인장특성과 촉감을 가지고 있다. 특히 이것은 용매의 무독성, 재활용 및 부산물 억제와 같은 환경 친화적인 제조공정으로 인하여 새로운 섬유 소재로 부각되고 있다[1]. 그러나 높은 배향도와 피브릴간의 약한 결합력으로 인하여 섬유 표면의 과도한 피브릴이 형성되고 이는 염색가공시 많은 문제를 일으키는 것으로 알려져 있다. (중략)

• Proceedings of the Korean Fiber Society Conference
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• 2003.10a
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• pp.17-18
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• 2003

Swelling behaviors of Lyocell and Polynosic fibers are investigated by measuring fiber sizes in ferric sodium tartrate complex (FeTNa) and NaOH solution. They showed an anisotropic swelling behavior, i.e., a large expansion in a radius and small shrinking in a longitudinal direction. Birefringent structure was maintained in Lyocell fibers in the swollen state but not in Polynosic fibers for both solvent systems.

• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.3_4 s.141
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• pp.470-477
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• 2005

This study was carried out to evaluate the biodegradability of viscose rayon and lyocell fibers, employing soil burial test, activated sludge test and enzymatic hydrolysis. Using X-ray analysis, crystallinity and morphology change was investigated. External changes after degradation were also observed by SEM and digital photographs. Vscose rayon fibers exhibited higher biodegadation than lyocell fibers, indicating that lower crystallinity favored the biodegradation. Among the biodegradability of lyocell fibers there was a tendency that fibers with lower crystallinity and higher moisture regain had higher values. When external changes after degradation being observed, it was shown that there were microorganisms growing on the surfaces of samples accompanying lading and weakening. From these results it was concluded that biodegradability of the specimens was most closely correlated to the moisture regain and crystallinity of fibers which reflects hydrophilicity and internal structure.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.101-101
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• 2011

재생 셀룰로스 섬유의 원료로 사용되는 셀룰로스는 면, 마, 목재 등 고등식물의 주성분으로 매년 수십억톤이 광합성에 의하여 생산되어지고 있다. 따라서 석유류와 같은 화석연료의 가격 변동에 영향을 받지 않고 안정적으로 수입되고 있다. 또한, 셀룰로스에는 면이나 마류 등과 같이 간단한 정제 처리에 의해 의류용 섬유로서 사용될 수 있는 것과 목재 섬유와 같이 펄프화하여 종이, 인견섬유, 필름 등으로 사용되어지는 것이 있으며, 셀룰로스 유도체도 제조할 수 있다. 현재까지 개발된 섬유들 중 대표적인 셀룰로스계 재생섬유인 비스코스 레이온(Viscose rayon)은 그 제조 방법이 환경적으로 치명적인 문제를 안고 있으나 고유의 우수한 드레이프성, 흡습성, 독특한 광택, 시원한 촉감 등을 가지고 있어 그 소비는 꾸준한 상황이다. 이러한 Viscose rayon을 대체하기 위하여 친환경적인 공법을 이용하여 개발된 Lyocell 제품이 각광을 받고 있다. 면 셀룰로스 재생섬유는 기존의 Lyocell섬유에 비해 신도는 높고 모듈러스가 낮아 Modal과 같은 촉감을 가지고, 피브릴 발생이 없어 방사공정에서 가교반응이 필요치 않는 것으로 기대된다. 친환경 공법인 Lyocell 공법으로 개발된 면 린터 원료를 이용하여 면 린터 셀룰로스 재생섬유 제조기술을 개발하고자 한다. 따라서 본 연구에서는 면 린터 셀룰로스 재생섬유의 기술적인 신뢰성을 검증하기 위해 면 린터 셀룰로스 재생섬유소재 피브릴화 정도의 표준화 시험법을 연구하고자 한다. 사용원단으로 Tencel A-100, Tencel standard, Modal, Lyocell LF, 면 린터 섬유를 사용하였으며, 세탁, 염색, 알칼리조건 처리에 따른 물성 변화를 알아보았다. 물성 변화는 전자현미경으로 측정하였다.

• Journal of the Korean Applied Science and Technology
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• v.27 no.2
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• pp.168-174
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• 2010

In this research, an effective method for reducing the fibrillation of lyocell fibers, which are spun from a solution of cellulose in N-methyl morpholine-N-oxide(NMMO), through consecutive chemical treatments. Undried solution-spun cellulosic fiber was firstly treated with 10 to 30 wt% of multifunctional crosslinking agents, such as ethylene glycol poly(3-chloro-2-hydroxypropyl) ether, and then dipped into alkaline solution to introduce epoxy functions. Finally steam condition was applied to occur a chemical crosslinking in order to reduce the fibrillation on the surface of fibers. Fibrillation was also reduced significantly by adding extra $Na_2SO_4$ in NaOH solution. In addition, Antifibrilllated lyocell fibers show the slightly higher dyeability(4 %) to Cibacron Blue without serious reduction of mechanical properties.

• Journal of the Korean Society of Propulsion Engineers
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• v.25 no.4
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• pp.36-42
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• 2021

In this study, the impregnation of Lyocell fabrics was performed using phosphoric acid, ammonium phosphate, diammonium hydrogen, triammonium phosphate as phosphorus flame retardant, to fabricate continuous graphite fabrics using lyocell fiber. The physical and chemical structure changes were investigated by thermogravimetric, Fourier-transform infrared spectroscopy, C-nuclear magnetic resonance, X-ray diffraction, and weight analyses, By analyzing the thermal behavior of phosphorus flame retardant, conditions for the temperature, gas, and residual time of the pyrolysis process were set. Graphite fabrics with a tensile strength of 1,007.19±11.47 N/5 cm and yield of 25.3% were fabricated using continuous pyrolysis, carbonization and graphitization process.