• Journal of the Mineralogical Society of Korea
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• v.9 no.2
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• pp.55-63
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• 1996

Epidote occurs as veinlets in the propylitic alteration zone of the Bobae clay deposit, Pusan, Korea. Its cell parameters apparently decrease with the contents of Al, Fe, and Ca. Fourier transform infrared (FTIR) spectra show one hydrosyl environment related to AlM2 at 3357-3358 cm-1. In the mid-infrared region, the peaks at 950 and 1030 cm-1 sharper with increasing Al shifting to higher energy region. The peak at 885 cm-1 shifts slightly to a lower energy region with a decreasing intensity as the Fe content increases. In the far-IR region, epidote exhibits absorption bands at 120 and 140 cm-1, which are related to the Ca-O bonds in A-sites.M ssbauer spectra of epidote show that the isomer shifts of Fe3+ range from 0.36-0.37 at the M3 site and from 0.35-0.44 at M1 site. Fe2+ shows the isomer shift ranging from 1.11 to 1.13. Quadrupole splitting is 2.04 for Fe3+M3, 0.52-0.70 for Fe3+M1, and 2.61-2.70 for Fe2+M3. Calculation shows Fe3+M386-90.7%, Fe3+M12.5-3.6%, and Fe2+M35.8-11.4% of total iron, showing preferential distribution of Fe3+ in the M3 site. The Fe3+M3 content is between 0.486 and 0.513 per formula unit. in the Fe-rich epidote, less Fe3+ and more Fe2+ are accommodated in the M1 and M3 sites. Hence, the overall disorder increases as total Fe content increase. The ordering parameter of the Bobae epidote is 0.93-0.95, suggesting a disequilibrium state below 200$^{\circ}C$. The constant temperature over a long period may be essential for the transition from disordered state to equilibrium state, despite the possible variation in flux and composition of the hydrothermal fluid.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.10
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• pp.2595-2606
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• 1995

Buoyancy-assisted melting of an unconstrained ice in an isothermally heated horizontal enclosure was numerically analyzed in a range of wall temperatures encompassing the density inversion point. The problem as posed here involves two physically distinct domains each of which has its own scales and respective heat transfer mode. These two domains join at the junction where the liquid squeezed out of the film region flushes into the lower melt pool. Both of these domains have been treated separately in the literature by a patching technique which invokes several, otherwise unnecessary, assumptions. The present study eliminates successfully such a superfluous procedure by treating the film and lower melt pool regions as a single domain. As a result of this efficient solution procedure, the interaction of the water stream ejected at the junction and the natural convection in the melt pool could be clarified for different wall temperatures. Though limited by two-dimensionality, the present results conformed indirectly the earlier reported transition of the flow pattern, as the wall temperature was increased over the density inversion point. The transient evolution of the melting surface, the time rate of change in melt volume fraction, the local and temporal variation of the heat transfer coefficients are analyzed and presented.

• Journal of Welding and Joining
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• v.20 no.5
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• pp.87-92
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• 2002

Weldability of Friction Stir Welded(FSW) AZ31B-H24 Mg alloy sheet with 4m thick was evaluated by changing welding speed. The sound welding conditions mainly depended on the suffiicient welding heat input during the process. The insufficient heat input resulted in the void like defect in the weld zone. Higher welding speed caused a larger inner void or lack of bonding. The defects were distributed at the stir zone or the transition region between stir zone and thermo-mechanical affected zone (UE). The size of defects slightly increased with increasing welding speed. These defects had a great effect on the joint strength of weld zone. The weld zone was composed of stir zone, TMAZ and heat affected zone. The stir zone was cosisted of fine recrystallized structure with $5-8\mu\textrm{m}$ in the mean grain size. The hardness of weld zone was near the 60HV, which was slightly lower than that of base metal. The maximum joint strength was about 219MPa that was 75% of that of base metal and the yield strength was also lower than that of base metal partly due to the existance of defects.

• Korean Journal of Materials Research
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• v.33 no.6
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• pp.251-256
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• 2023

This study aims to examine the correlation between microstructures and the mechanical properties of two high-strength API X70 linepipe steels with different specimen directions and Moaddition. The microstructure of the Mo-added steel has an irregularly shaped AF, GB matrix with pearlite because of the relatively large deformation in the non-recrystallization temperature region, while that of the Mo-free steel shows a PF matrix with bainitic microstructure. In the Mo-added steel, the M/A (martensite-austenite) in granular bainite (GB) and pearlite act as crack initiation sites with decreased upper shelf energy and an increased ductile to brittle transition temperature (DBTT). Regardless of Mo addition, all of the steels demonstrate higher strength and lower elongation in the T direction than in the L direction because of the short dislocation glide path and ease of pile-up at grain boundaries. In addition, the impact test specimens with T-L direction had a lower impact absorbed energy and higher DBTT than those with the L-T direction because the former exhibit shorter unit crack path compared to the latter.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.1
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• pp.29.2-29.2
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• 2010

The Extreme ultraviolet Imaging Spectrometer (EIS) on board Hinode provide us with excellent imaging spectroscopic data with very good spatial and spectral resolutions, which can be used for detecting Doppler flows in transition region and coronal lines as well as diagnosing plasma properties such as temperature, density, and non-thermal velocity. In this study we have made an EUV-imaging spectroscopic study of the source region of a partial halo coronal mass ejection (CME) that occurred on 2007 July 9 in NOAA 10961. Dopplergrams are obtained before and after the CME eruption using 12 EIS spectral lines (Log T= 4.9~7.2). Major results are summarized as follows. First, it is noted that either red shifts disappeared or blue shifts newly appeared for all spectral lines lower than Log T =6.0. Second, there were significant intensity increases for all wavelengths. Third, there were no significant variations in non-thermal motions for all wavelengths. We found one interesting bright point that newly appeared after the CME eruption. We discuss the implication on the results in terms of the CME eruption.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.61.1-61.1
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• 2014

GSH 006-15+7 is a Milky Way supershell discovered by Moss et al. (2012). This supershell shows large shell-like structures in H I velocity maps. We have analyzed FUV emission for the supershell regions based on the FIMS and GALEX observations. Bright FUV flux at the boundaries of the supershell is mostly originated from dust scattering of FUV photons by dust clouds which was also observed at the boundaries of the supershell. We could find the distance to the supershell can be closer more than 30% compared with the distance of 1500 pc suggested by Moss et al. (2012) from the dust scattering simulation. And we also found the albedo and the phase function asymmetry factor of interstellar grains were 0.30 and 0.40, respectively. The confidence range for the albedo covers the theoretical value of 0.40, but g-factor is rather smaller than the theoretical value of 0.65. The small g-factor might mean the environment of turbulent ISM of the supershell. Meanwhile, the excess of C IV and X-ray emissions in the inside of the supershell can support the existence of hot gas and cooling in the supershell. And the C IV and X-ray emissions are monotonically decrease as away from the center of the SNR. This indicates the size of the hot bubble has considerably shrunk. We applied a simple simulation model to the PDR candidate region of the lower part of the supershell and obtained a H2 column density N(H2) = 1017.0-18.0 cm-2 and total hydrogen density nH ${\geq}$ 10 cm-3. This result shows the PDR candidate region represents a transition region from the warm phase to the cool phase in the PDR.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.16 no.5 s.96
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• pp.488-493
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• 2005

In this study, waveguide-to-CPW transitions were developed for integrating waveguide and MMIC at V-band. The finite element method for numerical analysis and repeated experiments were performed to propose two types of waveguide-to-CPW transition. Using quartz substrate, proposed structures were designed for low loss as well as broadband characteristics. These waveguide-to-CPW transitions showed a good reliability and insensitivity to matching precision, and they could be fabricated with lower cost than that of the conventional connectors. Proposed two types of the structure showed insertion loss less than 1.9 dB and return loss better than 14 dB from 53 GHz to 60 GHz except unwanted resonance region, respectively.

• Journal of the Mineralogical Society of Korea
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• v.16 no.2
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• pp.161-169
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• 2003

A phase transformation study on a synthetic amorphous diopside, $(Ca,Mg)SiO_3$has been carried out up to ∼30 GPa, and ∼$1000^{\circ}C$ using a diamond anvil cell and YAG laser heating system, respectively. A starting amorphous material shows a direct transition to cubic $(Ca,Mg)SiO_3$perovskite at high pressure, which contradicts to the crystalline diopside phase transformation sequence disproportionating into mixtures of the orthorhombic$ MgSiO_3$perovskite and the cubic $CaSiO_3$perovskite phases. This discrepancy might be due to the different starting materials as well as the temperature variations at each specific experiment performed. The present phase transfor mation sequence would modify the mineralogical assemblage in the Earth transition region and the lower mantle depending upon the pressure, temperature and the oxygen partial pressure.

• Polymer(Korea)
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• v.35 no.4
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• pp.356-362
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• 2011

The branched polycarbonates (B-PCs) with two different branching agents were synthesized from melt polymerization. The contents of branching agent were in the range of 0.001~0.005 mol%. The chemical structure of the synthesized PC was determined by FTIR, $^1H$ NMR, and $^{13}C$ NMR, spectroscopy. The molecular weight, glass transition and degradation temperatures were determined by GPC, DSC, and TGA. The molecular weight of the phloro type B-PC had a lower value than the other one, and the glass transition temperature increased with molecular weight. Compared with linear PC, the rheological properties of the B-PC indicated an increase of complex viscosity in the low frequency region and shear thinning tendency. Power law index(n) representing shear thinning was calculated by linear regression and the values were in the range of 0.483~0.996. The rheological properties of the B-PCs were measured by a dynamic rheometer.

• Journal of Astronomy and Space Sciences
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• v.37 no.1
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• pp.69-75
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• 2020

We analyze the observations of temperature and ozone measured by the Microwave Limb Sounder (MLS) during the period of 2005-2016, to investigate the vertical structures of temperature and ozone in the stratosphere and mesosphere during stratospheric sudden warming (SSW). We compute the height profiles of the correlation coefficients between 55 height levels of MLS temperature anomalies and compare them with the results of Whole Atmosphere Community Climate Model simulations for three major SSWs. We also construct the temperature and ozone anomalies for the events to investigate the changes in the temperature and ozone distributions with height. There seems to always be a relatively weak but broad negative correlation between the temperature anomaly at 10 hPa and temperature anomalies over the entire mesosphere during the period before SSW events. However, this pattern gets stronger in the lower mesosphere but becomes a positive correlation in the upper mesosphere and lower thermosphere after the onset of SSW. We also found that the temperatures from the simulations show a similar trend to the observational results but with smaller variations and the transition height from negative to positive correlation in the mesosphere is much lower in the simulation than in the actual observations.