• 제목/요약/키워드: low temperature reduction

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도시근린공원 미세먼지(PM)저감과 공간차폐율과의 관계 - 대구광역시 수성구 근린공원을 중심으로 - (The Relationship between Particular Matter Reduction and Space Shielding Rate in Urban Neighborhood Park)

  • 구민아
    • 한국조경학회지
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    • 제47권6호
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    • pp.67-77
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    • 2019
  • 본 연구는 미세먼지 문제가 심각한 도심에서 도시근린공원의 중심이 입구에 비해 어느 정도 저감된 공간인지 분석해 보는데 목적이 있다. 또한 공원중앙의 공간 차폐율과 미세먼지 저감율과의 상관관계를 실험을 통해 도출해 내고자 하였다. 대구시 수성구 평지형 도시근린공원 7개를 대상으로 3일동안 같은 장소에서 측정하였다. 연구결과, 첫째, 도시근린공원 중심은 입구보다 온도는 평균 1.05℃ 낮고, 습도는 평균 2.57% 높았다. 둘째, 미세먼지 감소율은 PM1 17.09%, PM2.5 17.65%, PM10 14.99%의 저감율로 초미세먼지가 더 높은 것으로 분석되었으며, 공원의 규모가 작을수록 저감효과가 더 높았다. 또한 기상청발표 미세먼지 농도가 높은날일수록 공원중앙에서의 저감율은 낮았으며, 공원입구의 농도가 높을수록 저감율은 높았다. 셋째, 공원중심에서 공간차폐율이 높을수록 미세먼지 저감효과가 높은 것으로 파악되었다. 도시근린공원의 미세먼지 저감정도와 공간차폐율과의 상관관계를 파악할 수 있었으며, 더 확대된 실험데이터들의 기초가 되기를 기대한다.

대표적인 열분해가스화 용융시설의 공정별 다이옥신 배출거동에 관한 연구 (A study on the Dioxin behavior in the process of representative pyrolysis/gasfication/melting plant)

  • 신찬기;신대윤
    • 환경위생공학
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    • 제22권1호
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    • pp.1-16
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    • 2007
  • The incineration process has commonly used for wastes amount reduction and thermal treatments of pollutants as the technologies accumulated. However, the process is getting negative public images owing to matter of hazardous pollutants emission. Specially dioxins became a main issue and is mostly emitted from municipal solid wastes incineration. In this reason, pyrolysis/gasfication/melting process is presented as a alternative of incineration process. The pyrolysis/gasfication/melting process, a novel technology, is middle of verification of commercial plant and development of technologies in Korea. But the survey about the pollutant emission from the process, and background data in these facilities is necessary. So in this survey, it Is investigated that the behavior of dioxins in three pyrolysis/gasfication/melting plant (S, T, P) of pilot scale. In case of S plant, concentration of dioxins shows high at latter part of cogenerated boiler and stack which are operate on low temperature conditions than a latter parts of pyrolysis and melting furnace which are operate on high temperature condition. Concentration of gas phage dioxins had increased after combusted gas passed cogenerated boiler and this is attributed to react of precursor materials such as chlorobenzene and chlorophenol. Concentration of dioxins in T plant showed lower levels at latter part of cooling equipment which are operate with water spray type on low temperature conditions than a latter parts of gasfied melting furnace which are operate on high temperature condition. Removal efficiency of dioxins at gas treatment equipment was 78.8 %. Concentration of dioxins in P plant was low at latter part of SDA/BF which is operate at low temperature conditions than a latter parts of pyrolysis gasfied chamber which are operate at high temperature condition. Removal efficiency of dioxins of SDA/BF was 85.9 % and therefore, it showed high efficiency at those of stoker type incineration facility. However, concentration of dioxins which emitted at high temperature condition were low in three facilities and satisfied present standard emission level of dioxins. To consider the distribution ratio of dioxins, Particulate phase dioxins at S and P plants showed similar ratio with which shows in current stoker type for middle scale domestic waste incineration facility. It is necessary to continuos monitoring the ratio of distribution of dioxins in T plant in because ratio of gas phage dioxins showed high.

유전체장벽방전을 이용한 촉매공정의 질소산화물 저감성능 향상 (Improvement in Catalytic NOx Reduction by Using Dielectric Barrier Discharge)

  • 목영선;남창모
    • 한국산업융합학회 논문집
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    • 제9권1호
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    • pp.13-19
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    • 2006
  • The ozone produced by a dielectric barrier discharge device was injected into the exhaust gas to oxidize a part of NO to $NO_2$, and then the exhaust gas containing the mixture of NO and $NO_2$ was further treated in a catalytic reactor where both NO and $NO_2$ were reduced to $N_2$ in the presence of ammonia as the reducing agent. The $NO_2$ content in the mixture of NO and $NO_2$ was changed by the amount of ozone added to the exhaust gas. The experiments were primarily concerned with the effect of reaction temperature on the catalytic $NO_x$ reduction at various $NO_2$ contents. The increase in the $NO_2$ content by the ozone injection remarkably improved the performance of the catalytic $NO_x$ reduction, especially at low temperatures.

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High-Performing Adhesive Bonding Fastening Technique For Automotive Body Structures

  • Symietz, Detlef;Lutz, Andreas
    • 접착 및 계면
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    • 제7권4호
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    • pp.60-64
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    • 2006
  • In modern vehicle construction the search for means of weight reduction, improving durability, increasing comfort and raising body stiffness are issues of priority to the design engineer. The intelligent usage of many materials such as high strength steel, light-alloys and plastics enables a significant vehicle weight reduction to be achieved. The classical joining techniques used in the automobile industry need to be newly-evaluated since they often do not present workable solutions for such mixed-material connections, for example aluminium/steel. Calculation/simulation methods have made progress as a key factor for broader and more cost-effective implementation of structural bonding. This will lead to reduction of spotwelds and accelerate the car development. A special focus of the paper is the use of high strength steel grades. It will be shown that adhesive bonding is a key tool for yielding the potential of advanced high strength steel for low gauging without compromising the stiffness. The latest status of adhesive development has been described. Improvements with physical strength and glass temperature as well as of process relevant properties are shown. Also the situation regarding occupational hygiene is treated, showing that by further spotweld point reduction the emission around the working area can be even lowered against the current praxis. High performing lightweight design cannot longer do without high performing crash durable adhesives.

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황산염환원균을 이용한 폐광폐수의 중금속 제거 (Removal of Heavy Metals from Acid Mine Drainage Using Sulfate Reducing Bacteria)

  • 백병천;김광복
    • 상하수도학회지
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    • 제13권2호
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    • pp.47-54
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    • 1999
  • SRB(Sulfate Reducing Bacteria) converts sulfate into sulfide using an organic carbon source as the electron donor. The sulfide formed precipitates the various metals present in the AMD (Acid Mine Drainage). This study is the fundamental research on heavy metal removal from AMD using SRB. Two completely mixed anaerobic reactors were operated for cultivation of SRB at the temperature of $30^{\circ}C$ and anaerobic batch reactors were used to evaluate the effects of carbon source, COD/sulfate($SO_4^=$) ratio and alkalinity on sulfate reduction rate and heavy metal removal efficiency. AMD used in this study was characterized by low pH 3.0 and 1000mg/l of sulfate and dissolved high concentration of heavy metals such as iron, cadmium, copper, zinc and lead. It was found that glucose was an organic carbon source better than acetate as the electron donor of SRB for sulfate reduction in AMD. Amount of sulfate reduction maximized at the COD(glucose)/sulfate ratio of 0.5 in the influent and then removal efficiencies of heavy metals were 97.5% of Cu, 100% of Pb, 100% of Cr, 49% of Mn, 98% of Zn, 100% Cd and 92.4% of Fe. Although sulfate reduction results in an increase in the alkalinity of the reactor, alkalinity of 1000mg/1 (as $CaCo_3$) should be should be added continuously to the anaerobic reactor in order to remove heavy metals from AMD.

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돈분과 톱밥혼합물의 연속 및 간헐 통기 퇴비화에서 암모니아 휘산 (Ammonia Emissions from Composting Hog Manure Amended with Sawdust under Continuous and Intermittent Aeration)

  • 홍지형
    • 한국농공학회지
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    • 제43권4호
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    • pp.113-119
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    • 2001
  • Ammonia emissions during composting of hog manure mixed with sawdust were studied in four runs comprising a total of 22 pilot-scale reactor vessels. These four runs extended previous work and both verified and extended the previous conclusions. The pilot-scale vessels were 205 L insulated stainless steel drums that were aerated either continuously (high/low thermostatically controlled fans) or intermittently (5 min high fan 55 min off). Temperature ammonia emissions air flow rates carbon dioxide production and oxygen utilization moisture and dry matter reduction initial and final chemical compositions were measured. Ammonia emissions from the intermittently aerated vessels were only about 50% as great as those from the continuously aerated ones but this was found to be a result more related to total air flow than to aeration technique. All of the data for total result more related to total air flow were fitted with a linear regression line y=0.139x+29.835 where y is ammonia expressed as g of N and x is air flow in kg with $R^2$=0.6808. this general trend indicates that about 50% reduction in ammonia emissions can be achieved with 75% reduction in air flow. For the aeration techniques used the minimum oxygen level in te exhaust gas from the vessels was 5% and this is probably a resonable lower limit constraining air flow reduction. However within this constraint lower air flow now appears to be a technique that can reduce odorous ammonia emissions.

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Improvement in Characteristics of Thin Film Transistors by High Pressure Steam Annealing

  • Nagasawa, Y.;Yamamoto, N.;Chishina, H.;Ogawa, H.;Kawasaki, Y.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.333-336
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    • 2006
  • High Pressure Annealing System was developed to improve the characteristics of low-temperature poly-silicon thin film transistors.. (TFTs). The high-pressure steam annealing was applied to the poly-silicon film made by rapid thermal annealing method. The carrier lifetime was investigated by Microwave detection of the Photo-Conductive Decay and the increase of carrier lifetime which indicates the reduction of the defect was observed by high-pressure steam annealing of 1MPa 600C 1hour.

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DMSO-Oxalyl Chloride에 의한 당의 산화 (DMSO-Oxalyl Chloride for the Oxidation of Carbohydrates)

  • 천문우
    • 약학회지
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    • 제27권2호
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    • pp.181-184
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    • 1983
  • DMSO-oxalyl chloride at low temperature in methylene chloride reacted with isolated secondary hydroxyl groups in some monosaccharides to give alkoxysulfonium salts, convertible to carbonyls in high yields upon addition of triethylamine. And 1, 2:5, 6-di-O-isopropylidene-.alpha.- D-allofuranose which is the key intermediate in the synthesis of 3-O-acetyl-5-O-benzoyl- 2-deoxy-2- fluoro-D-arabinofuranosyl bromide, was also obtained by oxidizing 1, 2:5, 6-di-O-isopropylidene-.alpha.- D-glucofuranose with the oxidizing reagent, followed by reduction with sodium borohydride.

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Release of Ammonia Odor from AAFA (Ammonia Adsorbed Fly Ash) by Installation of NOx Reduction System

  • Kim, Jae-kwan;Park, Seok-un;Lee, Hyun-dong;Chi, Jun-wha
    • KEPCO Journal on Electric Power and Energy
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    • 제2권3호
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    • pp.437-445
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    • 2016
  • This paper discussed the effect of ammonia concentration adsorbed on fly ash for the ammonia emission as AAFA (Ammonia Adsorbed Fly Ash) produced from coal fired plants due to operation of NOx reduction technologies was landfilled with distilled or sea water at closed and open systems, respectively. Ammonia bisulfate and sulfates adsorbed on fly ash is highly water soluble. The pH of ammonium bisulfate and sulfate solution had significant effect on ammonia odor emission. The effect of temperature on ammonia odor emission from mixture was less than pH, the rate of ammonia emission increased with increased temperature when the pH conditions were kept at constant. Since AAFA increases the pH of solution substantially, $NH_3$ in the ash can release the ammonia order unless it is present at low concentration. $NH_4{^+}$ ion is unstable in fly ash and water mixtures of high pH at open system, which is changed to nitrite or nitrate and then released as ammonia gas. The proper conditions for < 20 ppm of ammonia concentration released from the AAFAs landfilled in ash pond were explored using an open system with sea water. It was therefore proposed that optimal operation to collect AAFA of less than 168 ppm ammonia at the electrostatic precipitator were controlled to ammonia slip with less than 5 ppm at SCR/SNCR installations, and, ammonia odor released from mixture of fly ash of 168 ppm ammonia with sea water under open system has about 20 ppm.

백금산화촉매를 통한 이산화질소(NO2)의 저감 특성에 관한 실험적 연구 (Experimental Investigation on the Reduction Characteristics of Nitric Dioxide(NO2) over Platinum-based Oxidation Catalyst)

  • 김영득;조자윤;이정길;김우승
    • 한국자동차공학회논문집
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    • 제20권4호
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    • pp.142-149
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    • 2012
  • The reduction characteristics of $NO_2$ to NO are experimentally studied over a platinum-based catalyst, especially at lower temperatures below about $200^{\circ}C$. In the present work, two types of steady-state experiments, engine bench and synthetic gas bench tests, are carried out in sequence. Steady-state engine bench tests with the DOC mounted on a light duty 4-cylinder 2.0 liter turbocharged diesel engine are performed and prove that CO plays a major role in $NO_2$ abatement at temperatures below the light-off temperature of CO oxidation, about $200^{\circ}C$. Synthetic gas bench tests are then performed using synthetic gas mixtures with CO, $C_3H_6$, NO, $NO_2$, $O_2$, $H_2O$ and $N_2$ in the $140{\sim}450^{\circ}C$ T-range and show that both CO and $C_3H_6$ are capable of reducing $NO_2$. It is noted that the reaction rate of $NO_2$ with $C_3H_6$ is much higher than that with CO. At temperatures below about $200^{\circ}C$, the reduction of $NO_2$ to NO is promoted with increasing CO concentration and $NO_2$/$NO_X$ ratio and with decreasing $O_2$ concentration, as well as with the presence of $H_2O$.