• Economic and Environmental Geology
• /
• v.53 no.3
• /
• pp.307-320
• /
• 2020

This study focuses on the raw material characteristics, including firing temperature and the similarity of clay body, and making techniques on the underwater ceramics from offshore of Taean Mado, the Republic of Korea. The ceramic specimens include various types of celadons, Buncheongwares and white porcelains with very similar physical characteristics. All the clay bodies composed of same mineral phases within mullite and quartz, while cristobalite were also found in some white porcelains. Also, the geochemical composition of the clay body shows regular behavior properties for all the elements consisting of the celadons and Buncheongwares. In contrast, the irregular properties of trace and incompatible elements were found in white porcelains. Therefore, it is presumed that the white porcelains were made using the clay body with different source from the celadons and Buncheongwares. Notably, some white porcelains in low Th content are assumed to be made with clay formed in a different environments. Meanwhile, most of the ceramics had gone through the firing of 1,200 to 1,300℃, with some celadons fired from 1,150℃ to 1,200℃. Also, it can be interpreted as some white porcelains were fired on even up to 1,500℃.

• Korean Journal of Heritage: History & Science
• /
• v.37
• /
• pp.349-369
• /
• 2004

Today, in the cultural properties research, there are several methods for knowing the culture of the past through a lot of information that remains and relics contain. Especially, statistical method like presumption of producing center were introduced from computer development at the early 20th century. This study showed the characteristic about firing historic sites presumed as a tile-kiln in the remains of Cheonwang temple sites, Hanam, Gyeonggi province. Also, I used nature scientific methods for correlation between tiles excavated at historic sites and circumference building and obtained there results as follows. First, soft tile parts showed similar water suction ratio(over 10%) like another tiles, except hard tile parts. Second, identification about mineral crystallization in a sample showing low water suction ratio confirmed a result that Mullite, Tridymite, Cristobalite as high temperature crystal form were presented. I know that firing temperature was higher than the other tile parts from this result. Third, statistical analysis from micro-component resulted that tiles excavated at firing historic sites and Cheonwang temple sites were closely connected. As the results, I knew that the tiles got a supply after the establishment of tile-kiln, not at a long distance at the period of Cheonwang temple construction.

• Korean Journal of Materials Research
• /
• v.13 no.2
• /
• pp.120-125
• /
• 2003

A low melting borosilicate glass frit was used as an adhesion promoter, which enables $MnWO_4$to be sintered with in a reasonable sintering temperature range ($800∼1000^{\circ}C$). The glass was evaluated for glass transition temperature ($Τ_{g}$ X) and thermal expansion coefficient($\alpha$). Mechanical property (Vickers hardness), grain growth, the comparison of lattice parameter and pore distribution of sintered $MnWO_4$ with the frit were methodically discussed. As sintering temperature increased, a typical liquid phase sintering showed the rapid grain growth and high densification of X$MnWO_4$grain, improvement of hardness (until $920^{\circ}C$) and different pore size distribution. Resistance of sintered $MnWO_4$varied from 450k$\Omega$ to 8.8M$\Omega$ under the measuring humidify ranging from 30 to 90%. Thus, the results will contribute to the application of glass frit containing sensor materials and their future use.

• Korean Journal of Materials Research
• /
• v.5 no.2
• /
• pp.151-156
• /
• 1995

Low temperature firing $(Ba, Sr)TiO_{3}$ dielectrics were successfully prepared with lead based glass and those electrical properties were investigated. Different amount of PbO content glass materials were added to dielectrics to investigate the sinterability and its dielectric properties. Also, various compositions of ceramic capacitors were prepared to applicate in multilayer ceramic capacitors. A large amount of experiment has been done with various Pb contented glasses and different sintering temperatures. The sintering temperature of $(Ba,Sr)TiO_{3}$can be reduced from $1350^{\circ}C$to as low as $1050^{\circ}C$ with 4wt% addition of $PbO-ZnO-B_{2}O_{2}$ glass materials. Its dielectric constant at room temperature was up to 8100 with low dielectric loss, 0.005. This ceramic capacitor showed fully fired microstructures with its grain size of 1-3$\mu \textrm{m}$. The sintered body which was sintered at $1150^{\circ}C$ for 2hr with 4wt% $PbO-ZnO-B_{2}O_{2}$ glass material addition satisfied the Z5U specification of the EIAS.

• Journal of Technologic Dentistry
• /
• v.31 no.4
• /
• pp.25-30
• /
• 2009

Zirconia($ZrO_2$) has attracted much attention in science and technology because of its high refractive index, high melting temperature, hardness, low thermal conductivity and corrosion barrier properties. And it is widely used as the dental restoration material because of its esthetic appearance. In this research, we analyzed the particle size and composition of the imported dental porcelain for zirconia. And the glass frit was produced. To decrease the glass transition temperature and softening temperature of the glass frit, $Li_2O$ was added into it and the effect of $Li_2O$ on the firing temperature was researched. Then the glass which contains leucite crystal with a high coefficient of thermal expansion(CTE) was manufactured and it was mixed with the glass frit to control the CTE. The phase composition were analyzed using the X-ray diffraction. The morphologies of the samples were observed by the scanning electron microscope. The 4wt% $Li_2O$-added glass frit has the optimal glass transition temperature and softening temperature. And 6 wt% leucite crystal was mixed with the glass frit to control the CTE. From the experimental results of crystallization, the crystal phase was found only leucite crystal.

• Journal of the Korean Ceramic Society
• /
• v.38 no.7
• /
• pp.597-601
• /
• 2001

The effect of CuO, $B_2$ $O_3$, $V_2$ $O_{5}$ and CuO-B $i_2$ $O_3$additives on microwave dielectric properties of (P $b_{0.45}$C $a_{0.55}$) [(F $e_{0.5}$N $b_{0.5}$)$_{0.9}$S $n_{0.1}$] $O_3$(PCFNS) were investigated. The PCFNS ceramics were sintered at 11$65^{\circ}C$. To decrease the sintering temperature for using as a low-temperature co-firing ceramics (LTCC), CuO, $B_2$ $O_3$, $V_2$ $O_{5}$ and CuO-B $i_2$ $O_3$were added to the PCFNS. As the content of CuO increased, the sintered density and dielectric constant increased and the temperature coefficient of resonance frequency ($\tau$$_{f}$) shifted to the positive value. When the CuO-B $i_2$ $O_3$were added, dielectric properties were $\varepsilon$$_{r}$ of 83, Q. $f_{0}$ of 6085 GHz, and $\tau$$_{f}$ of 8ppm/$^{\circ}C$ at a sintering temperature of 100$0^{\circ}C$. The relationship between the microstructure and properties of ceramics was studied by X-ray diffraction and scanning electron microscopy.icroscopy.y.icroscopy.y.

• Korean Journal of Materials Research
• /
• v.22 no.11
• /
• pp.598-603
• /
• 2012

MgO based cement for the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. Furthermore, adding reactive MgO to Portland-pozzolan cement can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as starting materials was carried out. In order to increase the hydration activity, $MgCO_3$ and serpentinite were fired at a temperature higher than $600^{\circ}C$. In the case of $MgCO_3$ as starting material, hydration activity was highest at $700^{\circ}C$ firing temperature; this $MgCO_3$ was completely transformed to MgO after firing. After the hydration reaction with water, MgO was totally transformed to $Mg(OH)_2$ as hydration product. In the case of using only $MgCO_3$, compressive strength was 35 $kgf/cm^2$ after 28 days. The addition of silica fume and $Mg(OH)_2$ led to an enhancements of the compressive strength to 55 $kgf/cm^2$ and 50 $kgf/cm^2$, respectively. Serpentine led to an up to 20% increase in the compressive strength; however, addition of this material beyond 20% led to a decrease of the compressive strength. When we added $MgCl_2$, the compressive strength tends to increase.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.10
• /
• pp.92-98
• /
• 2006

An 1 lbf of NASA standard monopropellant thruster, MRE-1, is used for KOMPSAT (Korea Multi-Purpose Satellite) which is launched in 2006 and provides reliable and cost-effective means for attitude and maneuvering control system. The monopropellant thruster obtains required thrust by thermal decomposition process of propellant through catalyst bed. During firing, the decomposition plays a role of a heat source that may occur an excessive radiation heat transfer to peripheral structures and electronics in relatively low temperature condition.Therefore, the radiation heat shield is needed to prevent the critical radiative heat exchange between thruster and satellite during firing. This paper summarizes an overall development process of radiation heat shield from the design engineering up to the manufacturing.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.22 no.5
• /
• pp.397-404
• /
• 2009

Effects of ceramic filler types and dose on the low temperature sintering and dielectric properties of ceramic/$CaO-Al_2O_3-SiO_2$ (CAS) glass composites were investigated. All of the specimens were sintered at $850{\sim}900^{\circ}C$ for 2 h, which conditions are required by the low-temperature co-firing ceramic (LTCC) technology. Ceramic fillers of $CaCO_3$, $Al_2O_3$, $CaCO_3-Al_2O_3$ mixture, and $CaCO_3-Al_2O_3$ compound ($CaAl_2O_4$), respectively, were used. The addition of $Al_2O_3$ yielded the crystalline phase of alumina, which was associated with the inhibition of sintering, while, $CaCO_3$ resulted in no apparent crystalline phase but the swelling was significant. The additions of $CaCO_3-Al_2O_3$ mixture and $CaAl_2O_4$, respectively, yielded the crystalline phases of alumina and anorthite, and the sintering properties of both composites increased with the increase of filler addition and the sintering temperature. In addition, the $CaAl_2O_4$/CAS glass composite, sintered at $900^{\circ}C$, demonstrated good microwave dielectric properties. In overall, all the investigated fillers of 10 wt% addition, except $CaCO_3$, yielded reasonable sintering (relative density, over 93 %) and low dielectric constant (less than 5.5), demonstrating the feasibility of the investigated composites for the application of the LTCC substrate materials.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.50 no.12
• /
• pp.593-598
• /
• 2001

Transient liquid phase processing was investigated to decrease processing temperatures while maintaining useful piezoelectric properties in the lead zirconate titanate (PZT) system. Niobium oxide$(Nb_2O_5)$ modified crystalline PZT (PZTN) powder was combined with lead silicate $(PS; PbO-SiO_2)$ glass powder and crystalline titania, zirconia, and niobia. Firing above the melting temperature of the lead silicate $(PS; Tm \risingdotseq\; 714^{\circk}C)$ resulted in liquid phase densification of the PZTN followed by dissolution of the titania, zirconia, and niobia into the liquid phase, and crystallization of additional PZTN. The addition of crystalline titania, zirconia, and niobia to react with the lead oxide from the lead silicate phase resulted in an increase in the dielectric and Piezoelectric properties.