• Title/Summary/Keyword: low porosity

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Fabrication of Porous Yttria-Stabilized Zirconias Controlled by Additives

  • Paek, Yeong-Kyeun;Oh, Kyung-Sik;Lee, Hyuk-Jae
    • Journal of the Korean Ceramic Society
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    • v.44 no.2 s.297
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    • pp.79-83
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    • 2007
  • To fabricate a thick, porous yttria-stabilized zirconia without cracking and warping, a method for the simultaneous control of the porosity and shrinkage was designed. As a pore former, a potato starch was used. For the control of shrinkage the oxidation of Al metal particles was used. For the sintering of the above powder mixtures, a partial sintering technique was used at $1300^{\circ}C$ for 10 min in air. Upon adding the additives, high open porosity above 53% and a low shrinkage level were obtained. As a result cracking and warping of the sintered body were deterred. This outcome most likely resulted from the compensation of sintering shrinkage due to the volume expansion caused by oxidation of the Al metal particles during heat-treatment.

A Study on the Electrochemical Properties of the Cathode upon Different Kinds of Activated carbon in Zinc/Air Battery (활성탄 종류에 따른 아연공기전지용 Cathode의 전기화학적 특성 연구)

  • 김지훈;엄승욱;문성인;윤문수;김주용;박정식;박정후
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.415-421
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    • 2004
  • The voltage profile of Zinc/Air battery during discharge has very flat pattern in a given voltage range, But, if not enough the porosity in cathode, as a result of that capacity, energy and discharge voltage of batteries become low. Therefore, we focused the pore effects in activated carbon for cathode. We examined discharge voltage, specific capacity, specific energy, resistance and characteristics during the GSM pulse discharge upon different kinds of activated carbon in Zinc/Air battery, Also we measured porosity of the air cathode according to the ASTM. So we achieved improvement of specific capacity, specific energy and discharge voltage according to increase meso pores of activated carbon. We found the optimized activated carbon material for Zinc/Air battery.

Porometric Study on the Gas Diffusion Layer in PEMFCs Using Method of Standard Porosimetry (MSP 기법을 적용한 고분자 전해질 연료전지 가스확산층의 포로시메트리 연구)

  • Lee, Yongtaek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.2
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    • pp.64-69
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    • 2013
  • The structure of pore network of gas diffusion layers (GDLs) in PEMFCs plays a critical role in determining the transport phenomena of reaction gas as well as generated water. In addition, the interactive characteristics between water and surface of pore are no less important than the structural characteristics of pore network. In this study, porometric investigation is conducted for two kinds of GDL using method of standard porosimetry which enable to distinguish hydrophobic pores from hydrophilic pores of GDLs. The porosity of TGPH-120 decreases by 6% by adding 30 wt.% of PTFE, but the porosity of hydrophilic pores decreases by 12%. The relation of $p_c-S_{nw}$ varies with the addition of PTFE, especially at low $p_c$.

Physicochemical Properties of Root Zone Soil Based on Sand Blending with Coconut Coir and Peat Moss (코코넛 코이어와 피트모스 혼합 모래 토양의 물리·화학적 특성)

  • Kim, Young-Sun;Bae, Eun-Ji;Choi, Mun-Jin;Kim, Tae-Wooung;Lee, Geung-Joo
    • Korean Journal of Environmental Agriculture
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    • v.41 no.2
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    • pp.101-107
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    • 2022
  • BACKGROUND: Soil amendment was necessary applied for the sand that had been used to root zone of green ground in golf course because of its low water retention power and cation exchangeable capacity. This study was conducted to evaluate the effect of the mixed ratio of peat moss and coconut coir as soil amendment materials on the soil physicochemical properties applied to rootzone based on sand. METHODS AND RESULTS: The soil amendments were blended at 0, 3, 5, 7 and 10% by soil volume. The pH in the peat moss treatment was lower than that of control (0% soil amendment), and pH and electrical conductivity (EC) in the coconut coir were higher. The blending ratio of peat moss was negatively correlated with pH of rootzone soil (p<0.01), and that of coconut coir positively with EC (p<0.01). As compared with control, capillary porosity, the physical factors such as air-filled porosity, total porosity, and hydraulic conductivity of rootzone soil were increased by applying peat moss and coconut coir. For correlation coefficients between percentage of soil amendments and soil physical factors, peat moss and coconut coir were positively correlated with porosity and hydraulic conductivity (p<0.01). CONCLUSION(S): These results indicated that the application of peat moss and coconut coir affected on the change of physicochemical properties of rootzone soil, and improved soil porosity and hydraulic conductivity.

Estimation of Concrete Porosity Using Image Segmentation Method (영상 분할기법을 활용한 콘크리트의 공극률 평가 )

  • Hyun-Joon Jeong;Hoseong Jeong;Jae Hyun Kim;Kang-Su Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.1
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    • pp.30-36
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    • 2023
  • In this study, an image segmentation model that can evaluate surface porosity based on concrete surface images was derived. Three types of concrete specimens with different water-cement ratios (w/c = 54, 35, and 30%) were prepared, and 2,729 surface images were obtained using an optical microscope. Benchmarking tests, parameter optimization, and final model derivation were performed using the surface images, and an image segmentation model with 97% verification accuracy was obtained. The model was verified by comparing the porosity obtained from the model and X-Ray Microscope (XRM). The model provided similar porosity to that of XRM for the specimens with a high water-cement ratio, but tended to give lower porosity for specimens with a low water-cement ratio.

Fabrication and Characteristics of Anode-Supported Tubular Solid Oxide Fuel Cell (연료극 지지체식 원통형 고체산화물 연료전지의 제조 및 특성연구)

  • Kim, Eung-Yong;Song, Rak-Hyun;Shin, Dong-Ryul;Lim, Y.E.
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1547-1549
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    • 1999
  • As a preliminary experiment for the development of anode-supported tubular cell with proper porosity, we have investigated the anode substrate and the electrolyte-coated anode tube. The anode substrate was manufactured as a function of carbon content in the range of 20 to 50 vol.%. As the caron content increased, the porosity of the anode substrate increased slightly and the carbon content with proper porosity was obtained at 30 vol.%. The anode tube was fabricated by extrusion process and the electrolyte layer was coated on the anode tube by slurry dipping process. The anode-supported tube was cofired successfully. Their sintered property and microstructure were examined and the porosity of the anode tube was 35%. From the gas permeation test, the anode tube was found to be porous enough for gas supply. On the other hand, the anode-supported tube with electrolyte layer indicated a very low gas permeation rate. This means that the coated electrolyte was dense. Based upon these experimental results. we will fabricate and test the anode-supported tubular cell.

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Effects of Physicochemical/Mineralogical Characteristics of Limestones and Porosity after Calcination on Desulfurization Reactivities

  • Baek, Chul-Seoung;Seo, Jun-Hyung;Cho, Jin-Sang;Cho, Kye-Hong;Han, Choon
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.34-42
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    • 2016
  • Characteristics of wet flue gas desulfurization and in-furnace desulfurization of domestic and overseas limestone with different crystallinity and crystalline size are studied in this article. Properties of desulfurization were evaluated in relation to physicochemical/ mineralogical characteristics, degree of pore formation for different calcination temperatures and TNC(total neutralizing capability). TNC of domestic high crystalline limestone was lower than that of overseas one. On the other hand, the porosity after calcination was shown to be relatively high for domestic limestone, which had high initial rates of desulfurization reactions in-furnace. Based on low pore formation and porosity with high TNC of crystalline high-Ca limestones compared to macrocrystalline ones, the former are preferred for wet desulfurization processes.

Studies on the Soil Management in Ginseng Preplanting Soil (II) Relationship between the Soil Characteristics of 2-Year-Old Ginseng Field Soil and the Ratio of Missing Plant (인삼식부 예정지의 토양관리에 관한 연구 제2보. 2연근포지의 토양 특성변화 및 결주율과의 관계)

  • 이일호;박찬수
    • Journal of Ginseng Research
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    • v.9 no.1
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    • pp.36-41
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    • 1985
  • The study was conducted to investigate the changes of soil physico-chemical properties between soils of preplanting fields and 2 years old ginseng fields, and compare the missing plant rate among the 2 years 016 ginseng fields. 1, The missing plant rate of 2 years old ginseng was high in sand loam while low in clay loam soil texture, soil porosity and NO3-N were remarkably increased in 2 years old ginseng field than preplanting soil, as the clay content was increased, soil porosity seemed to be increased but exchangeable nitrogen decreased. 2. The preplanting soil management methods did not significantly influenced on the missing plant rate and soil porosity in 2 years old ginseng fields, However NO3-N content and Fusarium density seemed to be decreased as the plow frequency was increased, exchangeable nitrogen content, whereas, seemed to be increased with more organic matter. 3. Differences of clay content (below 15% and above 20% of clay content) was significantly influenced on soil porosity, bulk density, total nitrogen, organic matter and P2O5 content. 4, Missing rate showed negative correlation with clay, soil moisture, and organic matter content but positive corelation with NO3-N in 2 years old ginseng fields.

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The development of prevention technique for crack and porosity occured during hardening overlay auto MIG welding for press die of gray cast iron (회주철 프레스 금형에 대한 경화육성 자동 MIG 용접시 균열 및 기공방지 기법의 개발)

  • Yu, Gwang-Seon;Hwang, Jae-Ryeon;Kim, Deok-Hwan;Kim, Byeong-Hun;Hwang, Ji-Seon;Jo, Sang-Myeong
    • Proceedings of the KWS Conference
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    • 2005.11a
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    • pp.114-116
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    • 2005
  • There are some problems when weld gray cast iron which is used well in automobile industry with auto MIG welding. the problems are followed like this 1) Occurrence of porosity and hardening organization. 2) Occurrence of crack due to lower elongation of gray cast iron when restraint stress works on. 3) Occurrence of porosity and unstable bead shape due to unstable arc under low current MIG welding.. especially there is a restraint on chemical composition of weld metal because the weldment demands more than 570Hv hardness. so it is hard to use Fe-Ni wire to prevent cracks occured on weldment and new welding method is needed to resolve that problems. This study shows how to prevent porosity and cracks occurring when weld gray cast iron trimming die and shows a new welding method for press die of gray cast iron

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Thermo-mechanical vibration analysis of temperature-dependent porous FG beams based on Timoshenko beam theory

  • Ebrahimi, Farzad;Jafari, Ali
    • Structural Engineering and Mechanics
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    • v.59 no.2
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    • pp.343-371
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    • 2016
  • In this paper thermo-mechanical vibration analysis of a porous functionally graded (FG) Timoshenko beam in thermal environment with various boundary conditions are performed by employing a semi analytical differential transform method (DTM) and presenting a Navier type solution method for the first time. The temperature-dependent material properties of FG beam are supposed to vary through thickness direction of the constituents according to the power-law distribution which is modified to approximate the material properties with the porosity phases. Also the porous material properties vary through the thickness of the beam with even and uneven distribution. Two types of thermal loadings, namely, uniform and linear temperature rises through thickness direction are considered. Derivation of equations is based on the Timoshenko beam theory in order to consider the effect of both shear deformation and rotary inertia. Hamilton's principle is applied to obtain the governing differential equation of motion and boundary conditions. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of several parameters such as porosity distributions, porosity volume fraction, thermal effect, boundary conditions and power-low exponent on the natural frequencies of the FG beams in detail. It is explicitly shown that the vibration behavior of porous FG beams is significantly influenced by these effects. Numerical results are presented to serve benchmarks for future analyses of FG beams with porosity phases.