• Title/Summary/Keyword: low porosity

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WC-Co coating by cold spray deposition (Cold spray를 이용한 WC-Co 코팅)

  • 김형준;황순영;권영각
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.311-313
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    • 2004
  • WC-12-17%Co powders with nano- and micro-structures were deposited by cold spray process using nitrogen and helium gases. The results show that there is no detrimental phase transformation and/or decarburization of WC by cold spray deposition as expected. It is also observed that nano-sized WC in the feedstock powder is maintained in the cold spray deposition. It is demonstrated that it is possible to fabricate the nano-structured WC-Co coating with low porosity and very high hardness (-2050 HV) by cold spray deposition with reasonable powder preheating.

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Formation and humidity-sensing properties of porous silicon oxide films by the electrochemical treatment (전기화학적 처리에 의한 다공질 실리콘 산화막의 형성과 감습 특성)

  • 최복길;민남기;류지호;성영권
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.1
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    • pp.93-99
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    • 1996
  • The formation properties and oxidation mechanism of electrochemically oxidized porous silicon(OPS) films have been studied. To examine the humidity-sensitive properties of OPS films, surface-type and bulk-type humidity sensors were fabricated. The oxidized thickness of porous silicon layer(PSL) increases with the charge supplied during electrochemical humidity sensor shows high sensitivity at high relative humidity in low temperature. The sensitivity and linearity can be improved by optimizing a porosity of PSL. (author). refs., figs.

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Spray Forming of $Mg_2Si$ Rich Aluminum Alloys

  • Ellendt, N.;Uhlenwinkel, V.;Stelling, O.;Irretier, A.;Kessler, O.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.231-232
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    • 2006
  • Aluminum Alloys with a content of 22 wt.-% $Mg_2Si$ were spray formed. This alloy features by a low density and is therefore a superior material for leightweight applications. The main problem in spray forming of this type of alloy was the occurance of high porosities. First process optimizations have been performed to decrease porosity under a certain level, so that it can be closed by an extrusion process

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STUDY PROCESSES OF INTUMESCENCE IN FIRE-PROTECTING COATINGS

  • Efremov, V.L.;Paltseva, N.G.;Leiman, Z.A.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.657-658
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    • 2005
  • Flame retard of polymers was studied for prevention from burning by various additives stimulated the char formation during heating and thermal degradation of polymer materials. Forming char have high porosity, low thermal conductivity and act as thermal shield for heat transmission from the flame to the polymer and. oxygen towards the polymer. The results showed that various additives may regulate the processes of intumecsence. The efficient fire protective intumescent char was result of processes of melting, gas evolution, cross-linking, carbonization etc.

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Preparation of Gemcitabine-Loaded Methoxy Poly(ethylene glycol)-b-Poly(L-lactide) Microparticles Using W/O/W Double Emulsion (W/O/W 다중유화법을 이용한 젬시타빈 함유 Methoxy Poly(ethylene glycol)-b-Poly(L-lactide) 미립자 제조)

  • Ryu, Jong-Hoon;Jung, In-Il;Lee, Ji-Eun;Lim, Gio-Bin
    • KSBB Journal
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    • v.26 no.4
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    • pp.333-340
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    • 2011
  • In this study, gemcitabine-loaded methoxy poly(ethylene glycol)-b-poly(L-lactide) (MPEG-PLLA) microparticles with different PEG block lengths were prepared by a W/O/W double emulsion technique. The present study focuses on the investigation of the influence of various preparative parameters such as the ratio of internal water phase and oil phase, polymer concentration, solvent composition of organic phase and salt concentration of external water phase on the morphology and encapsulation efficiency of the microparticles. The microparticles fabricated at high volume ratios of internal water phase to oil phase and at high polymer concentrations showed a relatively high encapsulation efficiency and low porosity. When a dichloromethane/ethyl acetate mixture was used as solvent, both the encapsulation efficiency and drug loading of the microparticles decreased as the level of ethyl acetate increased. The addition of a salt (NaCl) to the external water phase significantly improved the encapsulation efficiency up to 40%, and the microparticles became more spherical with their size and porosity decreased.

Plasticity and Fracture Behaviors of Marine Structural Steel, Part II: Theoretical Backgrounds of Fracture (조선 해양 구조물용 강재의 소성 및 파단 특성 II: 파단의 이론적 배경)

  • Choung, Joon-Mo;Shim, Chun-Sik;Kim, Kyung-Su
    • Journal of Ocean Engineering and Technology
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    • v.25 no.2
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    • pp.92-100
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    • 2011
  • The main goal of this paper is to provide the theoretical background for the fracture phenomena in marine structural steels. In this paper, various fracture criteria are theoretically investigated: shear failure criteria with constant failure strain and stress triaxiality-dependent failure strain (piecewise failure and Johnson-Cook criteria), forming limit curve failure criterion, micromechanical porosity failure criterion, and continuum damage mechanics failure criterion. It is obvious that stress triaxiality is a very important index to determine the failure phenomenon for ductile materials. Assuming a piecewise failure strain curve as a function of stress triaxiality, the numerical results coincide well with the test results for smooth and notched specimens, where low and high stress triaxialities are observed. Therefore, it is proved that a failure criterion with reliable material constants presents a plastic deformation process, as well as fracture initiation and evolution.

Mechanical Strength and Thermal Conductivity of Pure/Opacified Silica Aerogels (순수/불투명화 실리카 에어로겔의 기계적 강도 및 열전도도)

  • 현상훈;이찬호;김동준;성대진
    • Journal of the Korean Ceramic Society
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    • v.34 no.9
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    • pp.969-978
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    • 1997
  • The properties of microstructure, hydrophobicity/hydrophilicity, mechanical strength, and thermal conduction of pure/opacified silica aerogels synthesized by the sol-gel supercritical drying technique were investigated. The hydrophobic surface of opacified silica aerogels doped with carbon (0.13 g/cm3 density, 94% porosity, 580 m2/g specific surface area) transformed to hydrophilic surface after heat-treated above 30$0^{\circ}C$. The values of compressive modulus (1.85 MPa) and strength (0.5 MPa) of opacfied silica aerogels were about 20 times higher than those of pure silica aerogels. The mechanical properties of pure silica aerogels heat-treated at $700^{\circ}C$ were also considerably improved without changing their porosity and density. Particularly, compressive modulus and compressive strength of pure silica aerogels GPSed under 100$0^{\circ}C$ and 80 bar were improved 140 and 37 times, respectively. Thermal conductivities of pure/opacified silica aerogels measured at room temperature and 227$^{\circ}C$ were about 0.013 and 0.019 W/m.K, respectively, and were to be found very low value of 0.004 W/m.K below 10 torr pressure at room temperature.

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A study of the simulation of thermal distribution in an aquifer thermal energy storage utilization model (대수층 축열 에너지 활용 모델의 온도 분포 시뮬레이션 연구)

  • Shim, Byoung-Ohan;Song, Yoon-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.697-700
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    • 2005
  • Aquifer Thermal Energy Storage (ATES) system can be very cost-effective and renewable energy sources, depending on site-specific parameters and load characteristics. In order to develop an ATES system which has certain hydrogeological characteristics, understanding of the thermo hydraulic processes of an aquifer is necessary for a proper design of an aquifer heat storage system under given conditions. The thermo hydraulic transfer for heat storage is simulated using FEFLOW according to two sets of pumping and waste water reinjection scenarios of heat pump operation in a two layered confined aquifer. In the first set of model, the movement of the thermal front and groundwater level are simulated by changing the locations of injection and pumping well in seasonal cycle. However, in the second set of model the simulation is performed in the state of fixing the locations of pumping and injection well. After 365 days simulation period, the temperature distribution is dominated by injected water temperature and the distance from injection well. The small temperature change is appears on the surface compared to other slices of depth because the first layer has very low porosity and the transfer of thermal energy are sensitive at the porosity of each layer. The groundwater levels and temperature changes in injection and pumping wells are monitored to validate the effectiveness of the used heat pump operation method and the thermal interference between wells is analyzed.

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Fabrication and Pore Characteristics of Cu Foam by Slurry Coating Process

  • Park, Dahee;Jung, Eun-Mi;Yang, Sangsun;Yun, Jung-Yeul
    • Journal of Powder Materials
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    • v.22 no.2
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    • pp.87-92
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    • 2015
  • Metallic porous materials have many interesting combinations of physical and geometrical properties with very low specific weight or high gas permeability. In this study, highly porous Cu foam is successfully fabricated by a slurry coating process. The Cu foam is fabricated specifically by changing the coating amount and the type of polyurethane foam used as a template. The processing parameters and pore characteristics are observed to identify the key parameters of the slurry coating process and the optimized morphological properties of the Cu foam. The pore characteristics of Cu foam are investigated by scanning electron micrographs and micro-CT analyzer, and air permeability of the Cu foam is measured by capillary flow porometer. We confirmed that the characteristics of Cu foam can be easily controlled in the slurry coating process by changing the microstructure, porosity, pore size, strut thickness, and the cell size. It can be considered that the fabricated Cu foams show tremendous promise for industrial application.

Influence of solvent on the nano porous silica aerogels prepared by ambient drying process (상압건조 나노다공성 실리카 에어로젤에 대한 용매의 영향)

  • Ryu, Sung-Wuk;Kim, Sang-Sig;Oh, Young-Jei
    • Journal of Sensor Science and Technology
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    • v.15 no.5
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    • pp.371-377
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    • 2006
  • Nano porous, transparent silica aerogels monoliths were prepared under ambient drying (1 atm, $270^{\circ}C$) condition by the combination of sol-gel process and surface modification with subsequent heat treatment. Three kinds of solvent, n-hexane, n-heptane and xylene, were selected in the point view of low surface tension and vapor pressure in order to restrain a formation of cracks during drying. Crack-free silica aerogels with over 93 % of porosity and below $0.14g/cm^3$ of density were obtained by solvent exchange and surface modification under atmosphere condition. Optimum solvent was confirmed n-heptane among these solvents through estimation of FT-IR, TGA, BET and SEM. Modified silica aerogel exhibited a higher porosity and pore size compare to unmodified aerogels. Hydrophobicity was also controled by C-H and H-OH bonding state in the gel structure and heat treatment over $400^{\circ}C$ effects to the hydrophobicity due to oxidation of C-H radicals.