• Title/Summary/Keyword: low conductivity

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Tribological Properties of Heat-resistant Cast Steel Discs: Effect of Thermal Conductivity (내열 주강 디스크의 마찰특성: 열전도도 영향)

  • Kim, H.S.;Lee, J.S.;Cho, D.H.;Kang, S.W.;Na, T.Y.;Jang, H.
    • Tribology and Lubricants
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    • v.30 no.1
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    • pp.29-35
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    • 2014
  • The temperature-dependent tribological properties of brake discs for a train were examined in this study. The discs were produced using heat-resistant alloy steel, which showed different thermal conductivity after the heat treatments. A commercial brake friction material was used to evaluate the friction effectiveness, and the friction tests were carried out using a 1/5 scale dynamometer under various initial braking temperature conditions. The results showed that the tribological property of the disc was strongly affected by the heat treatment schedule. At low temperatures (below $250^{\circ}C$), the friction coefficient increased as a function of disc temperature, indicating that frictional heat increased the adhesion between the disc and pad. In addition, fade was observed at high temperatures (above $250^{\circ}C$); it was pronounced in the case of the disc with low thermal conductivity. The different fade resistances observed in the discs with different heat treatment schedules appear to be influenced by microstructural changes such as carbide redistribution occurring during the heat treatments, which affected the thermal conductivity.

스퍼터링 법으로 증착한 CdS 박막의 광전도도 특성 평가

  • Heo, Seong-Gi;Jang, Dong-Mi;Choe, Myeong-Sin;An, Jun-Gu;Seong, Nak-Jin;Yun, Sun-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.81-81
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    • 2008
  • Applications of CdS films in this study are to exhibit a high conductivity when they are exposed at light with visible wavelength and sequentially to show a low conductivity in dark state. For this purpose, CdS films should have a high photosensitivity, still maintaining a high conductivity at a visible light. In this study, CdS films were prepared at room temperature on glass substrates by rf magnetron sputtering. In order to increase the photo-conductivity in visible light, various defect levels should be located within the CdS band gap. In order to nucleate the defect sites within the CdS band gap, CdS films were deposited on glass substrates at room temperature using various $H_2$/(Ar+$H_2$) flow ratios by an rf magnetron sputtering. Through the investigation of the structural and photoconductive properties of CdS films by an addition of hydrogen, the relationship between photo- and dark-resistance in CdS films was investigated in detail. 200-nm-thick CdS films for photoconductive sensor applications were prepared at various $H_2$/(Ar+$H_2$) flow ratios on glass substrates at room temperature by rf magnetron sputtering. Sulfur concentration in CdS films crystallized at room temperature with (002) preferred orientation depends directly on the hydrogen atmosphere and the surface roughness of the films gradually increases with increasing hydrogen atmosphere. Films deposited at 8% of $H_2$/(Ar+$H_2$) exhibit an abrupt decrease of dark- and photo-resistance, showing a low photo-sensitivity ($R_{dark}/R_{photo}$). Onthe other hand, films deposited at a hydrogen atmosphere of 42% exhibit a photo-sensitivity of $5\times10^3$, maintaining a photo-resistance of an approximately $2\times10^4\Omega$/square. The dark- and photo-resistance values of CdS films were related with a composition, surface roughness, and defect sites within the band gap.

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A new thermal conductivity estimation model for weathered granite soils in Korea

  • Go, Gyu-Hyun;Lee, Seung-Rae;Kim, Young-Sang;Park, Hyun-Ku;Yoon, Seok
    • Geomechanics and Engineering
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    • v.6 no.4
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    • pp.359-376
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    • 2014
  • Thermal conductivity of ground has a great influence on the performance of Ground Heat Exchangers (GHEs). In general, the ground thermal conductivity significantly depends on the density (or porosity) and the moisture content since they are decisive factors that determine the interface area between soil particles which is available for heat transfer. In this study, a large number of thermal conductivity experiments were conducted for soils of varying porosity and moisture content, and a database of thermal properties for the weathered granite soils was set up. Based on the database, a 3D Curved Surface Model and an Artificial Neural Network Model (ANNM) were proposed for estimating the thermal conductivity. The new models were validated by comparing predictions by the models with new thermal conductivity data, which had not been used in developing the models. As for the 3D CSM, the normalized average values of training and test data were 1.079 and 1.061 with variations of 0.158 and 0.148, respectively. The predictions became somewhat unreliable in a low range of thermal conductivity values in considering the distribution pattern. As for the ANNM, the 'Logsig-Tansig' transfer function combination with nine neurons gave the most accurate estimates. The normalized average values of training data and test data were 1.006 and 0.954 with variations of 0.026 and 0.098, respectively. It can be concluded that the ANNM gives much better results than the 3D CSM.

Effect of Current Density on Ion Conductivity of Membrane in Proton Exchange Membrane (고분자전해질 연료전지에서 고분자막의 이온전도도에 미치는 전류밀도의 영향)

  • Hwang, Byungchan;Oh, Sohyung;Lee, Daewoong;Chung, Hoi-Bum;You, Seung-Eul;Ku, Young-Mo;Na, Il-Chae;Lee, Jung-Hoon;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.1-5
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    • 2018
  • In this work, we study the ion conductivity by analyzing the impedance to the high current density range that the PEMFC (Proton Exchange Membrane Fuel Cell) is actually operated. The effect of GDL (Gas Diffusion Layer)presence on impedance was investigated indirectly by measuring hydrogen permeability. When the RH (Relative Humidity)was higher than 60% in the low current range (< $80mA/cm^2$), the moisture content of the polymer membrane was sufficient and the ion conductivity of the membrane was not influenced by the current change. However, when RH was low, ion conductivity increased due to water production as current density increased. The ion conductivity of the membrane obtained by HFR (High Frequency Resistance) in the high current region ($100{\sim}800mA/cm^2$)was compared with the measured value and simulated value. At RH 100%, both experimental and simulated values showed constant ion conductivity without being influenced by current change. At 30~70% of RH, the ionic conductivity increased with increasing current density and tended to be constant.

Electrical Conductivity of a $TiO_2$ Thin Film Deposited on $Al_2O_3$ Substrates by CVD

  • Hwang, Cheol-Seong;Kim, Hyeong-Joon
    • The Korean Journal of Ceramics
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    • v.1 no.1
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    • pp.21-28
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    • 1995
  • Electrical conductivity of $TiO_2$ thin films, deposited on $Al_2O_3$ substrates by metal organic chemical vapor deposition (MOCVD), was measured by four-point probe method in a temperature range from $800^{\circ}C$ to $1025^{\circ}C$ and an oxygen partial pressure range from $2.7{\times}10^{-5}$ atm to 1 atm. In the low oxygen partial pressure region n-type conduction was dominant, but in the high oxygen partial pressure region p-type conduction behavior appeared due to substitution of Ti ions by Al ions, which were diffused from the substrate during post deposition annealing process. Electrical conductivity of the film decreases in the n-type region and increases in the p-type region as the oxygen partial pressure increases. The transition points, which show the minimum conductivity, shifted to the higher oxygen partial pressure region as the measuring temperature increased, but it shifted to lower oxygen partial pressure region with an increase in the post annealing temperature. The results were also discussed with the possible defect models.

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Effects of Nb and Ti Addition and Surface Treatments on the Electrical Conductivity of 316 Stainless Steel as Bipolar Plates for PEMFC (고분자전해필 연료전지 분리판용 316 스테인리스강의 전기전도도에 미치는 Nb, Ti 첨가 및 표면처리 효과)

  • Lee, Seok-Hyun;Kim, Jeong-Heon;Kim, Min-Chul;Chun, Dong-Hyun;Wee, Dang-Moon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.324-324
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    • 2006
  • Nb and Ti were added to 316 stainless steel, and then heat-treatments and surface treatments were performed on the 316 stainless steel and the Nb- and Ti-added alloys. All samples indicated enhanced electrical conductivity after surface treatments, whereas they showed low electrical conductivity before surface treatments due to the existence of non-conductive passive film on the alloy surface. In particular, the Hb- and Ti-added alloys showed remarkable enhancement of electrical conductivity compared to the original alloy, 316 stainless steel. Surface characterization revealed that small carbide particles formed on the alloy surface after surface treatments, while the alloys indicated flat surface structure before surface treatments. $Cr_{23}C_6$ mainly formed on the 316 stainless steel, and NbC and TiC mainly formed on the Nb- and Ti-added alloys, respectively. We attribute the enhanced electrical conductivity after surface treatments to the formation of these carbide particles, possibly acting as a means of electro-conductive channel through the passive film. Furthermore, NbC and TiC are supposed to be more effective carbides than $Cr_{23}C_6$ as electro-conductive channels of stainless steel

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Effects of Mg Content on the Properties and Casting Characteristics of Al-2Zn-0.2Fe-xMg Alloys (Al-2Zn-0.2Fe-xMg 합금의 물성 및 주조특성에 미치는 Mg함량의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ki-Tae;Ko, Se-Hyun
    • Journal of Korea Foundry Society
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    • v.32 no.2
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    • pp.86-90
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    • 2012
  • Aluminium-silicon based casting alloys have received an attention for high electrical and thermal conductivity applications, however relatively low conductivity of Al-Si alloys often limits the application. Efforts have been made to develop new high conductivity aluminium casting alloys containing no or less silicon. In this study Al-Zn-Fe based alloys were selected as the new alloys, and the effect of Mg additions on their properties and casting characteristics were investigated. As the magnesium content was increased, the tensile strength of Al-2Zn-0.2Fe based alloy was remarkably increased, while the electrical conductivity was deteriorated. It was observed that the fluidity of the alloys was generally inversely proportional to the Mg content but the hot cracking resistance was rather proportional to it. Cooling curve analyses were carried out to measure the actual solidification range and dendrite coherency temperature.

The Model and Experiment for Heat Transfer Characteristics of Nanoporous Silica Aerogel

  • Mingliang, Zheng
    • Korean Journal of Materials Research
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    • v.30 no.4
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    • pp.155-159
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    • 2020
  • Nanoporous silica aerogel insulation material is both lightweight and efficient; it has important value in the fields of aerospace, petrochemicals, electric metallurgy, shipbuilding, precision instruments, and so on. A theoretical calculation model and experimental measurement of equivalent thermal conductivity for nanoporous silica aerogel insulation material are introduced in this paper. The heat transfer characteristics and thermal insulation principle of aerogel nano are analyzed. The methods of SiO2 aerogel production are compared. The pressure range of SiO2 aerogel is 1Pa-atmospheric pressure; the temperature range is room temperature-900K. The pore diameter range of particle SiO2 aerogel is about 5 to 100 nm, and the average pore diameter range of about 20 ~ 40 nm. These results show that experimental measurements are in good agreement with theoretical calculation values. For nanoporous silica aerogel insulation material, the heat transfer calculation method suitable for nanotechnology can precisely calculate the equivalent thermal conductivity of aerogel nano insulation materials. The network structure is the reason why the thermal conductivity of the aerogel is very low. Heat transfer of materials is mainly realized by convection, radiation, and heat transfer. Therefore, the thermal conductivity of the heat transfer path in aerogel can be reduced by nanotechnology.

Electrical Conduction Property of the Carbon Black-Filled Polyethylene Matrix Composites Below the Percolation Threshold (문턱스며들기 이하 카본블랙 충진 폴리에칠렌기지 복합재료의 전기전도 특성)

  • Shin, Soon-Gi
    • Korean Journal of Materials Research
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    • v.20 no.5
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    • pp.271-277
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    • 2010
  • In this paper two aspects of the percolation and conductivity of carbon black-filled polyethylene matrix composites will be discussed. Firstly, the percolation behavior, the critical exponent of conductivity of these composites, are discussed based on studying the whole change of resistivity, the relationship between frequency and relative permittivity or ac conductivity. There are two transitions of resistivity for carbon black filling. Below the first transition, resistivity shows an ohmic behavior and its value is almost the same as that of the matrix. Between the first and second transition, the change in resistivity is very sharp, and a non-ohmic electric field dependence of current has been observed. Secondly, the electrical conduction property of the carbon black-filled polyethylene matrix composites below the percolation threshold is discussed with the hopping conduction model. This study investigates the electrical conduction property of the composites below the percolation threshold based on the frequency dependence of conductivity in the range of 20 Hz to 1 MHz. There are two components for the observed ac loss current. One is independent of frequency that becomes prevalent in low frequencies just below the percolation threshold and under a high electrical field. The other is proportional to the frequency of the applied ac voltage in high frequencies and its origin is not clear. These results support the conclusion that the electrical conduction mechanism below the percolation threshold is tunneling.

Thermal Conductivity Measurement of Grouting Materials for Geothermal Heat Exchanger (그라우트 재료에 따른 지중 열교환기의 열전도도에 관한 실험적 연구)

  • Lim Hyo Jae;Kong Hyoung Jin;Song Yoon Seok;Park Seong Koo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.364-369
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    • 2005
  • An experimental study was conducted on the thermal conductivity of various grouting materials for geothermal heat exchanger which is used as a heat sink or source in the heat pump system. The grouting of the vertical heat exchanger is important for environmental and heat transfer reasons and is generally accomplished by the placement of a low permeability material into the annular space between the borehole wall and the pipes suspended in the borehole. In this study, a lab scale test apparatus was made and measured the thermal conductivity of four grouting materials. As a result, the temperature rising tendency was similar among them, but the increasing rate was different. Thus the thermal conductivity showed a maximum difference of $27\%$ among grouting materials.