• Title/Summary/Keyword: localized corrosion

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δ-Ferrite Behavior of Butt Weld Zone in Clad Steel Plates Depended on Holding Time of PWHT (클래드강 맞대기 용접부의 후열처리 유지시간에 따른 델타 페라이트 거동)

  • Park, Jae-Won;Lee, Chul-Ku
    • Journal of Welding and Joining
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    • v.32 no.2
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    • pp.29-36
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    • 2014
  • Recently, in order to enhance the function and usefulness of products, cladding of dissimilar materials that maximizes the performance of the material is being widely used in all areas of industry as an important process. Clad steel plate, produced by cladding stainless steel plate, an anticorrosive material, on carbon steel plate, is being used to produce pressure vessels. Stainless steel plate has good corrosion resistance, and carbon steel plate has good rigidity and strength; clad steel can satisfy all of these qualities at once. This study aims to find the ${\delta}$-ferrite behavior, mechanical properties, structure change, integrity and reliability of clad steel weld on hot rolled steel plates. For this purpose, multi-layer welding, repair welding and post weld heat treatment were implemented according to welding procedure specifications (WPS). In order to observe the mechanical properties and toughness of clad steel weld zone, post weld heat treatment was carried out according to ASME Sec. VIII Div.1 UW-40 procedure for post weld heat treatment. With heat treatment at $625^{\circ}C$, the hold time was used as the process variable, increased by intervals that were doubled each time, from 80 to 1,280 min. The structure of weld part was typical cast structure; localized primary austenite areas appeared near central vermicular ferrite and fusion line. The heat affected zone showed rough austenite structure created by the weld heat input. Due to annealing effects of heat treatment, the mechanical properties (tensile strength, hardness, impact value) of the heat affected area tended to decrease. From the results of this study, it is possible to conclude the integrity of clad steel welds is not affected much in field welding, repair welding, multi-layer welding, post weld heat treatment, etc.

Effects of Alloying Elements(Cr, Mo, N) on Repassivation Characteristics of Stainless Steels Studied by the Abrading Electrode Technique and A.C Impedance Spectroscopy (마멸 전극 기법과 교류 임피던스법으로 연구한 스테인리스강의 합금원소(Cr, Mo, N)가 재부동태 특성에 미치는 영향)

  • Ham Dong-Ho;Kim Suk-Won;Lee Jae-Bong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.4
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    • pp.211-218
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    • 2000
  • The effects of alloying elements, Cr, Mo, and N on repassivation characteristics of stainless steels were investigated by using the abrading electrode technique and a.c impedance spectroscopy. The role of alloying elements on the stability of passive film and their repassivation characteristics were examined using alloy steels such as Fe-Cr, Fe-Cr-Mo, 304, 304LN, 316, and 316LN. The electrochemical characteristics of the passive film were investigated by in-situ d.c. and a.c. electrochemical methods. Localized corrosion resistance is believed to have much to do with the stability and repassivation characteristics of the passive film. The effects of alloying elements on the current transients and repassivation kinetics were systematically examined by using the abrading electrode technique and a.c. impedance spectroscopy. The experimental results were analyzed in order to elucidate the relationship between passive film stability, repassivation characteristics, and alloying elements.

Limit Loads for Circular Wall-Thinned Feeder Pipes Subjected to Bending and Internal Pressure. (원형 감육이 발생한 중수로 피더관의 한계하중 평가)

  • Je, Jin-Ho;Lee, Kuk-Hee;Chung, Ha-Joo;Kim, Jong-Sung;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.11
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    • pp.1675-1680
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    • 2010
  • Flow Accelerated Corrosion (FAC) occurring during in-service conditions results in localized wall-thinning in the feeder pipes of CANDU. The wall-thinning of the feeder pipes is the main degradation mechanisms affecting the integrity of piping systems. In this paper, we assess the integrity of wall-thinned feeder pipes by limit load analysis. The limit loads for wall-thinning feeder pipes subjected to in-plane bending and internal pressure were determined on the basis of finte element limit analyses. The limit loads are determined from the results of limit analyses of elasticperfectly-plastic materials using the large geometry change. Closed-form approximations of limit load solutions for wall-thinning feeder pipes subjected to in-plane bending and pressure are proposed.

A Study on Crystalline Structural Variations of the Rigid Spherical-Tip scratch on the Surface of α-Titanium substrates via Molecular Dynamics Simulations (α-티타늄 평판표면에서 강체 구형팁의 스크래치로 인한 내부 결정구조 특성 변화에 대한 연구)

  • Yeri Jung;Jin Ho Kim;Taeil Yi
    • Tribology and Lubricants
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    • v.39 no.5
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    • pp.167-172
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    • 2023
  • Titanium alloys are widely recognized among engineering materials owing to their impressive mechanical properties, including high strength-to-weight ratios, fracture toughness, resistance to fatigue, and corrosion resistance. Consequently, applications involving titanium alloys are more susceptible to damage from unforeseen events, such as scratches. Nevertheless, the impact of microscopic damage remains an area that requires further investigation. This study delves into the microscopic wear behavior of α-titanium crystal structures when subjected to linear scratch-induced damage conditions, utilizing molecular dynamics simulations as the primary methodology. The configuration of crystal lattice structures plays a crucial role in influencing material properties such as slip, which pertains to the movement of dislocations within the crystal structure. The molecular dynamics technique surpasses the constraints of observing microscopic phenomena over brief intervals, such as sub-nano- or pico-second intervals. First, we demonstrate the localized transformation of lattice structures at the end of initialization, indentation, and wear processes. In addition, we obtain the exerted force on a rigid sphere during scratching under linear movement. Furthermore, we investigate the effect of the relaxation period between indentation and scratch deformation. Finally, we conduct a comparison study of nanoindentation between crystal and amorphous Ti substrates. Thus, this study reveals the underlying physics of the microscopic transformation of the α-titanium crystal structure under wear-like accidental events.

An Experimental Study on the Properties of Chloride Binding of Mg/Al-NO3 and Ca/Al-NO3 Layered Double Hydroxides in Solution (수용액내에서 Mg/Al-NO3 및 Ca/Al-NO3 층상이중수산화물(LDHs)의 염소이온 고정화 특성에 관한 실험적 연구)

  • Lee, Seung-Yeop;Yang, Hyun-Min;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.3
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    • pp.219-227
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    • 2016
  • Chloride ions ingress continuously in reinforced concrete through pores of it by $Cl^-$. Finally, it causes a localized corrosion of the rebar and then it generates cracks on concrete structures. Recently, new materials removing harmful anions have been developed. Layered double hydroxides(LDHs) has an excellent ability to remove harmful anions because various anions can be adsorbed in the interlayer space between divalent and trivalent cations. Thus, LDHs has been applied in various fields. Especially, LDHs is expected to be effective adsorbent binding chloride ions. In this study, $Ca/Al-NO_3$ and $Mg/Al-NO_3$ LDHs were prepared by using a co-precipitation method. $Ca/Al-NO_3$ and $Mg/Al-NO_3$ LDHs were compared and analyzed by using XRD, SEM analysis. Many nano size hexagonal crystals were observed by SEM. Experiments for binding chloride ions of LDHs were conducted by using potentiometric method. The experimental data were measured every 15 minutes. It was observed that the chloride ion content is reduced by increasing of LDHs mass fraction and the reaction rate of $Mg/Al-NO_3$ is faster than $Ca/Al-NO_3$. In future studies, binding chloride capacity in cement materials will be evaluated based on results of this study.