• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.5
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• pp.570-578
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• 1999

An experimental study has been performed on heat and mass transfer in a falling film absorber with a strong lithium bromide solution in small-sized household absorption chiller/heater. Components were concentrically arranged in a cylindrical form. from the center, low temperature generator, absorber and evaporator. This arrangement of helical-typed heat exchangers allows to make the machine much more compact than conventional one. Experimental measurements were conducted with a helical absorber and the obtained data were compared with data in the literatures. The comparison revealed that the helical absorber tube provides a similar performance to existing tube bundle absorber in heat and mass transfer. As a result, the heat and mass transfer characteristics of helical type absorber showed the possibility of the reduction in size and weight of small] capacity absorption chiller/heater.

• Journal of the Korean Electrochemical Society
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• v.18 no.2
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• pp.51-57
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• 2015

We report the effect of the impurities including water and bromide in the propylmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PMPyr-TFSI) on the electrochemical performance of lithium ion batteries. The several kinds of PMPyr-TFSI electrolytes with different amount of impurities are applied as the electrolyte to the cell with the high potential electrode, $LiNi_{0.5}Mn_{1.5}O_4$ spinel. It is found that the impurities in the electrolytes cause the detrimental effect on the cell performance by tracing the cycleability, voltage profile and Coulombic efficiency. Especially, the polarization and Coulombic efficiency go to worse by both impurities of water and bromide, but the cycleability was not highly influenced by bromide impurity unlike the water impurity.

• Journal of the Korean Chemical Society
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• v.42 no.3
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• pp.277-284
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• 1998

Dendritic macromolecules of the first to fourth generation were synthesized, using alkenylation and hydrosilation cycles with allylmagnesium bromide and dichloromethylsilane as building blocks and siloxane tetramer $(Me(CH_2=CH)SiO)_4$, as core molecule. By the reaction of the dichloromethylsilyl-capped generation (G4P) with p-bromophenol, p-phenylphenol and lithium phenyethynylide, dendrimers with specific functions (G4P-BP (Mw: 16,300), G4P-PP (16,121), and CAP-PA (11,764)) have been produced. Analysis of new dendrimers by NMR, UV and MALD1 mass spectrometry suggests that they are pure and unified.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.6
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• pp.714-720
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• 2003

Due to the electric power shortage in summer season and regulation of freon refrigerant, the application of gas absorption refrigeration and hot water systems are considerably increasing trend. But, this system consists of condenser, heat exchanger, supply pipe and radiator etc. which are easily corroded by acidity and dissolved oxygen and gases. In result, this system occurs scale attachment and corrosion damage like pitting and crevice corrosion. In this study, electrochemical polarization test of heat exchanger tubing material (copper, aluminium brass, 30% cupronickel(30% Cu-Ni)) was carried out in 60% lithium bromide solution at $95^{\circ}C$. As a result of polarization test, corrosion behavior by impressed potential and local corrosion. such as galvanic corrosion, pitting corrosion behavior, of tubing materials was investigated. The main results obtained are as follows: (1) The effect of pitting and crevice corrosion control of 30% cupronickel in 60% LiBr solution at $95^{\circ}C$ is very excellent. (2) Dissimilar metal corrosion of 30% cupronickel coupling to aluminium bronze is the most sensitive. (3) Current density behavior of tube materials by impressed potential is high in order of copper > aluminium brass > 30% cupronickel.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1548-1553
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• 2003

An experimental study of the absorption process of water vapor into a lithium bromide solution was performed. For the purpose of development of high performance absorption chiller/hater utilizing lithium bromide solution as working fluid, it is the most effective to improve the performance of absorber with the largest heat transfer area of the four heat exchangers. The experimental apparatus was composed of a plate type absorber which can increase the heat exchange area per unit volume to investigate more detail characteristics instead of the conventional type, horizontal tube bundle type. The size of plate absorbers were made for $0.4m{\times}0.6m$ and the design object of a refrigeration capacity was lRT. In this experiment, three kind plate absorbers which were flat plate, dimple plate and groove plate were used. The results were less than the design object values, that is, the refrigeration capacity was about $0.3{\sim}0.4RT$ and the overall heat transfer coefficient was $500{\sim}600kcal/m^2h^{\circ}C$ at the standard conditions.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.7
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• pp.642-648
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• 2000

Falling film heat transfer analyses with aqueous lithium bromide solution were peformed to investigate the transfer characteristics of the copper tubes. Finned(knurled) tube and a smooth tube were selected as test specimens. Averaged generation fluxes of water and the heat transfer performances(heat flux, heat transfer coefficient) were obtained. The results of this work were compared with the data reported previously. As the film flow rate of the solution increased, the generation fluxes of water decreased for both tubes. The reason is estimated by the fact that the heat transfer resistance with the film thickness increased as the film flow rate increased. The effect of the enlarged surface area at the knurled tube was supposed to be dominant at a small flow rate. The generation fluxes of water increased with the increasing degree of tube wall superheat. Nucleate boiling is supposed to occur at a wall superheat of 20 K for a smooth tube, and at 10 K for a knurled tube. The heat transfer performance of the falling film was superior to pool boiling at a low wall superheat below 10 K for both tubes tested. The knurled tube geometry showed good performance than the smooth tube, and the increased performance was mainly came from the effect of the increased heating surface area.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.120-123
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• 2008

Refrigeration plants using absorption principles have been around for many years with initial development taking place over 100 years ago. Although the majority of absorption cycles are based on water-LiBr cycle, many applications exist where ammonia-water can be used, especially where lower temperatures are desirable. In both systems water is used as working fluid, but in quite different ways: as a solvent for the ammonia system, and as refrigerant for the lithium bromide system. This explains that the lithium bromide absorption system is strictly limited to evaporation temperatures above $0^{\circ}C$. The main industrial applications for refrigeration are in the temperature range below $0^{\circ}C$, the field for the binary system ammonia-water.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.198-202
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• 2008

Refrigeration plants using absorption principles have been around for many years with initial development taking place over 100 years ago. Although the majority of absorption cycles are based on water-LiBr cycle, many applications exist where ammonia-water can be used, especially where lower temperatures are desirable. In both systems water is used as working fluid, but in quite different ways: as a solvent for the ammonia system, and as refrigerant for the lithium bromide system. This explains that the lithium bromide absorption system is strictly limited to evaporation temperatures above $0^{\circ}C$. The main industrial applications for refrigeration are in the temperature range below $0^{\circ}C$, the field for the binary system ammonia-water.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2004.05a
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• pp.201-212
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• 2004

An experimental study of the absorption process of water vapor into a lithium bromide solution was performed. For the purpose of developing high performance absorption chiller/hater utilizing lithium bromide solution as working fluid, it is important to improve the performance of absorber with the larger heat transfer area of the four heat exchangers. The experimental apparatus was composed of a plate type absorber which could increase the heat exchange area per unit volume to investigate more detail characteristics instead of the conventional type, that is, horizontal tube bundle type. The size of plate absorbers were made for 0.4m$\times$0.6m and the design objective of a refrigeration capacity was 1RT. In this experiment, three kinds of plate absorbers namely flat plate, dimple plate and groove plate were used. The obtained results were less than the design objective values, that is, the refrigeration capacity was about 0.3 ～0.4RT and the overall heat transfer coefficient was 500～600 kcal/$m^2$h$^{\circ}C$ at the standard conditions.

• Archives of Pharmacal Research
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• v.9 no.4
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• pp.237-242
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• 1986

The Synthesis of E, E, E-12-fluorofarnesol and E, Z-6-fluorofarnesol which are key intermediates for the study of biosynthesis of some sesquiterpenes, is described. E, E-Farnesyl acetate is treated with selenium dioxide to give E, E, E-12-hydroxy farnesyl acetate, whih is transformed by DAST into E, E, E-12-hydroxy farnesyl acetate, which is transformed by DAST into E, E, E,-12-fluorofarnesylacetate. The latter compound is hydrolyzed to E, E, E,-12-fluorofarnesol. The reformatsky reaction of 6-methyl-5-hepten-2-one with ethyl bromofluoroacetate affords ethyl 2-fluoro-3-hydroxy-3, 7 dimethyl-6-octanoate. This ester is acetylated and eliminated to give ethyl (Z)-2-fluoro-3, 7-dimethylocta-2, 6-dienoate, which is transformed to allyl bromide via allylic alcohol. The allyl bromide is treated with dianion of methyl acetate to give-keto ester. The $\beta$-keto ester is converted to diethyl phosphoryloxy compound. The conjugate addition of lithium dimethylcuprate to the latter compound gives fluoro ester, which is treated with DIBAL to afford E, Z-6-fluorofarnesol.