• Title/Summary/Keyword: liquid rubber

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Evaluation of Hot Mix Asphalt Properties using Complex Modifiers (복합개질제를 이용한 아스팔트 혼합물의 물성 평가)

  • Lee, Kwan-Ho;Kim, Seong-Kyum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.5
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    • pp.146-152
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    • 2018
  • In this study, to improve the performance of asphalt mixtures for plastic deformation occurring mainly in Korea, complex modifiers were prepared by mixing powders and liquid type modifiers. The main constituents were powdery diatomaceous earth, mica and carbon black, and liquid type solid 70% SBR latex. The tensile strength ratios for the two asphalt mixtures used in the test were above 0.80 for the Ministry of Land Transportation (2017) asphalt mixture production and construction guidelines. The effects of increasing the tensile strength in the dry state was more than 14% when the composite modifier was added. The deformation rate per minute by the wheel tracking test load was an average of 0.07 to 0.147 for each mixture. The strain rate per minute was improved by the modifier, and the dynamic stability was improved by almost 100% from 295 to 590. In addition, the final settling was reduced from 11.38 mm to 9.57 mm. A plastic deformation test using the triaxial compression test showed that the amount of deformation entering the plastic deformation failure zone at the end of the second stage section and in the third stage plastic deformation section was 1.76 mm for the conventional mixture and 1.50 mm for the complex modifier mixture. The average slope of the complex modifier asphalt mixture mixed with the multi-functional modifier was 0.005 mm/sec. The plastic deformation rate is relatively small in the section where the road pavement exhibits stable common performance, i.e. the traffic load.

Synthesis and Selective Gas Permeability of Liquid Crystalline Poly(allyl sulfone) Networks (액정폴리알릴술폰의 합성 및 기체 선택투과 특성)

  • Jo, Byung-Wook;Choi, Jae-Kon;Kim, Joon-Seop;Choi, Soo-Kyung
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.136-142
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    • 2005
  • Liquid crystalline poly(allylsulfone) networks having $SO_2$ in a main chain and mesogens in a side chain were synthesized and their gas permeability and permselectivity were determined. The monomer II having two allyl groups on the each end group was able to form polymer networks by polymerization reaction, while the monomer I having only one allyl group was not. Molecular motion of the poly(allylsulfone) networks were retarded with increasing the cross-linking density, and the segmental motion of networks was developed enough to show isotropic phase transition. Gas permeabilities of poly(II-5 $01/I-OCH_3$ 99) were 2.58 baller for $O_2$ and 18.4 barrer for $H_2$. It means that hydrogen gas are 7 times more permeable than oxygen. Its permselectivities were high as 23.9 for ${\alpha}(H_2/N_2)$. The permselectivity was increased with increasing the cross-linking density. For example, ${\alpha}(H_2/N_2)$ was 36.8 in poly(II-5 $10/I-OCH_3$ 90), which was shown to be the highest value among these poly(allylsulfone) networks.

Performance Characteristics with Various Fuel Composition and Temperature for an External Type Fuel Pump in LPLi System (LPLi 시스템에서 외장형 펌프의 연료조성 및 온도에 따른 성능특성 연구)

  • Nam, Deok-Woo;Yoon, Jun-Kyu;Lim, Jong-Han
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.566-575
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    • 2011
  • Since LPG (Liquefied petroleum gas) fuel supply system has an advantage of low emission characteristics, many studies have been conducted. In spite of the advantage of LPG supply system, a higher vapor pressure and lower viscosity than diesel or gasoline fuel may cause unstable running of fuel pump by the deterioration in lubrication performance and chemical reaction with rubber parts than that of diesel and gasoline fuel. Therefore its physical properties can cause the deterioration of durability. In this research, we developed an external type LPG pump which has the advantage of the price competitiveness and the convenient maintenance for LPLi system. The experiments were carried out in order to assess characteristics of the external type fuel pump at different fuel composition and temperature. As a result, there aren't any differences between internal and external type pump performance. It is observed that the same level of efficiency was maintained for both pumps as flow rate was increased with higher fuel temperature and more contents of propane in the fuel. And the pressure difference in LPLi system is maintained at constant with the various fuel compositions and temperatures due to their own characteristics of fuel supply system.

Assessment of Underwater Penetration Performance for the Shape of the External Device of Shaped Charge (성형폭약 외부장치 형상에 따른 수중 관입성능 평가)

  • Suk, Chul-Gi;Noh, You-Song;Ko, Young-Hun;Park, Hoon;Cho, Sang-Ho;Yang, Hyung-Sik
    • Explosives and Blasting
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    • v.34 no.4
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    • pp.1-9
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    • 2016
  • For underwater steel structure, cut that underwater shaped charge device that combines a spring hose, which is an external device of pressure resistance and flexibility with flexible shaped charge, was invented. As a basic experiment for an optimum condition design, an penetration performance was compared by external device shape. To evaluate the result of an experiment, image analysis was carried out after obtaining the model by using the liquid rubber for the penetrated steel plate. To simulate the penetrating process of shaped charge, the AUTODYN program has been used. As a result of analysis, while the average penetration depth of circular and square shaped external devices were similar, the penetration quality was more uniform in the case of circle. In addition, water infiltration occurred in square case, displacement and strain rate according to the increase of the water pressure were measured high.

A Fact-finding Research Exercise into the Handling Abilities of Experimental Apparatus by Elementary School Students (초등학생의 실험 기구 조작 능력에 대한 실태 조사)

  • Park, Jae-Won;Yoon, Sang-Mi;Won, Jeong-Ae;Paik, Seoung-Hey
    • Journal of Korean Elementary Science Education
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    • v.26 no.2
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    • pp.161-170
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    • 2007
  • This study aims at helping us improve the methods used to teach elementary school students how to handle experimental apparatus by examining their manual skills and their understanding of the alcohol lamp, spuit and thermometer. To evaluate their ability to handle each experimental apparatus, a practical skills test and knowledge evaluation sheets were developed. The evaluation was carried out with 270 students from 2 classes each in the 3rd, 4th, 5th and 6th grade of D Elementary School located in Daejeon City. For their handling ability of the alcohol lamp, the results for the practical skills test showed that the students had a very low ability in placing objects in the center of the apparatus for safe use and also in adjusting the height of the trivet to place objects so that they contact the outer flames correctly. For the spuit, the pass rate of the skills test was generally low in regards to how students should grasp a spuit and the timing and method of depressing the rubber part before dipping it into liquid. For the thermometer, on the other hand, the pass rate was relatively high in every respect. The knowledge evaluation results for the use of experimental apparatus showed a very high rate of correct answers for alcohol lamps and thermometers. The test results for spoils also produced a relatively high rate of correct answers, with the exception of the test item regarding the way that students should grasp them.

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IATROGENIC CHEMICAL BURN ON FACIAL SKIN BY 37% PHOSPHORIC ACID ETCHANT (37% 인산 부식제에 의해 발생한 안면피부의 화학 화상)

  • Park, Jong-Hyun;Shin, Hye-Jin;Park, Se-Hee;Kim, Jin-Woo;Cho, Kyung-Mo
    • Restorative Dentistry and Endodontics
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    • v.34 no.1
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    • pp.38-41
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    • 2009
  • When we use the total-etch dentin adhesive system for composite resin restorations, gel or liquid acid etchant such as 37% phosphoric acid is commonly used. Thirty seven percentage phosphoric acid is very powerful erosive agent, and can cause severe harmful effects when it contacts with an oral mucosa and facial skin. This case describes iatrogenic chemical burn on facial skin caused by phosphoric acid which was happened during composite resin restorative procedure. Chemical burn by acid etchant can be evoked by careless handling of remnant and syringe. In order to prevent these iatrogenic injuries, we should check the complete removal of the etching agent both in intra and extra-oral environments after etching and rinsing procedure and it is necessary to use of the rubber dam or isolation instruments. If accidental burn were occurred. immediate wash with copious water. And bring the patient to the dermatologist as soon as possible.

A Study on Curing Reaction of 1-Chlobutadiene-Butadiene Copolymer by Moisture (1-Chlorobutadiene-Butadiene Copolymer의 수가교반응(水架橋反應)에 관한 연구(硏究)(I))

  • Yoo, Chong-Sun;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.22 no.3
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    • pp.195-203
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    • 1987
  • In this study, as one of the developing ways of the functional elastomer, improvement of the functionality of CB-BR was attempted through moisture curing reaction. The curing reaction of CB-BR was determined with an use of 3-aminopropyltriethoxysilane(APS) as a crosslinking agent, also a solution reaction with an active chlorine of CB-BR was elucidated by using a reaction kinetics theory and a study of physical property was made through moisture curing on the compound of 3-aminopropyltriethoxysilane and CB-BR The results of this study obtained are as follows : 1) CB-BR reacted easily with APS in the liquid state and the reaction rate coefficient and activation energy were as follows : 2) Optimum pressure condition of moisture cured elastomer(CB-BR+APS) was 20 minutes at $150^{\circ}C$, and the crosslinked elastomer was close to the theoretical value (q=1) for Flory's equation($\frac{\alpha}{\alpha-1}=q{\nu}RT$)

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Effect of Molecular Weight on Thermal Behavior of Polyurthanes Containing Mesogen Unit (분자량이 메소겐기를 포함한 폴리우레탄의 열적거동에 미치는 영향)

  • Hong, Sung-Chul;Lee, Woo-Young;Nam, Byeong-Uk;Lee, Sang-Won
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.212-221
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    • 2005
  • Polyurethanes containing mesogen unit (MPU-6) were prepared from 4,4'-diphenylmethane diisocyanate (MDI) and 4,4'-bis(6-hydroxy hexoxy)biphenyl (BP-6) having flexible chain composed of 6 carbons. Intrinsic viscosities of MPU-6s were in the range of $0.23{\sim}0.56 dL/g$. The mesomorphic behaviors of MPU-6 were observed in X-ray and polarizing microscopy analysis. However, MPU-6s demonstrated a 'virtual liquid crystal' behavior, which did not exhibit mesophase on slow heating and slow cooling. MPU-6 having lower molecular weight exhibited higher crystallization rate and melting crystallization temperature due to increased mobility of polymer chains. The increased mobility of polymer chains facilitate the orientation of mesogen units that may act as a nucleating agent.

Evaluation of vibration damping rate performance according to polymer mixing rate of polymer mixed mortar through ultrasonic pulse analysis (초음파 펄스 분석을 통한 폴리머 혼입 모르타르의 폴리머 혼입률에 따른 진동감쇠율 성능 평가)

  • Jeong, Min-Goo;Jang, Jong-Min;Lee, Gwang-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.71-72
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    • 2022
  • In this paper, the performance evaluation of the vibration damping ratio according to the polymer mixing ratio of the polymer modified mortar used as the floor finishing material of the apartment building structure was evaluated. To compare the vibration damping rate, ordinary potland cement (OPC) mortar and polymer modified mortar (PMM) were prepared. In addition, the mixed polymer was mixed with Styrene Butadiene Rubber (SBR) liquid polymer with a solid content of about 49%. Accordingly, the W/C of the test specimen was adjusted and compounded, and the experiment was conducted by mixing 5 types of the test specimen: OPC-60, PMM-5%, PMM-10%, PMM-15%, and PMM-20%. In addition, in order to adjust the W/C of the specimen, the fluidity of each specimen was set as 210 (±5) mm. The specimens measured density and flow in fresh mortar and after curing for 28 days, flexural strength, compressive strength and ultrasonic pulse were measured. The attenuation rate was shown. The experimental results showed that the density increased according to the mixing of the polymer, the flexural strength increased as the mixing rate of the polymer increased, and the compressive strength was decreased. In addition, it was shown that the vibration damping rate increases with the increase in the amount of polymer incorporated.

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Performance Experiments and Analysis of Nonlinear Behavior for HDRB using in Seismic Isolation (면진용 고감쇠 적층고무베어링의 성능 특성 실험 및 비선형 거동해석)

  • Koo, Gyeong-Hoi;Lee, Jae-Han;Yoo, Bong
    • Journal of the Earthquake Engineering Society of Korea
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    • v.2 no.4
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    • pp.73-86
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    • 1998
  • The purpose of this paper is to evaluate the shear stiffness, hysteretic behavior, and ultimate behavior of HDRB(High Damping Rubber Bearing), which will be included in the seismic isolation design guideline as requirements. To do this, two 1/8 scaled HDRB are designed, fabricated, and tested to show the mechanical characteristics. The shear stiffness obtained from the proposed equation of the shear stiffness shows a good agreement with those of the experiments. For analysis of the hysteretic behavior of HDRB using the modified rate model, the parameter equations are obtained from the experiments. Using the obtained parameter equations for the modified rate model, the seismic response analyses are carried out for 1-D system. The results of analysis well follow the hysteretic behavior of HDRB obtained from the experiments. To evaluate the ultimate behavior of HDRB used in this paper, the analyses are carried out using the modified macro model, which can consider the large shear deflection. The critical shear strain(CSS) is defined to express the maximum allowable shear strain and vertical load. From the analyses, the CSS, showing the instability, decreases significantly as increased the vertical loads. The CSS is not appeared for the design vertical load in the used HDRB. In analysis using about 5 times of design vertical load, the HDRB start to show the instability transient and for about 7 times, the CSS is about 350%.

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