• Bulletin of the Korean Chemical Society
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• v.33 no.5
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• pp.1470-1474
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• 2012

The pharmacokinetics of prunasin after oral administration of amygdalin or a decoction of peach seeds was determined and compared in rats. A $C_{18}$ column was used for separation at a column temperature of $25^{\circ}C$. The mobile phase consisted of 20% aqueous acetonitrile, and the flow rate was 0.5 mL/min. After oral administration of a decoction of peach seeds, prunasin was absorbed rapidly, reaching a maximum plasma concentration ($C_{max}$) of 62.1 mg/L within 45 min. After oral administration of amygdalin, the absorption of prunasin was delayed. The $C_{max}$ of prunasin was 42.9 mg/L and was reached at 60 min. Values for the pharmacokinetic parameters of prunasin, including $T_{max}$, $C_{max}$, AUC, $T_{1/2}$, CL/F, and V1/F, were significantly different for the oral administration of amygdalin compared with that of a decoction of peach seeds.

• Journal of the Korean Ceramic Society
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• v.50 no.1
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• pp.18-24
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• 2013

This study was conducted to recycle fly ash containing an abundance of CaO generated from combustion in a circulating layer as a carbon storage medium. The study utilized XRD, TG-DTA and XRF analyses during the hydration of fly ash and identified calcium substances within fly ash that could be used in a carbonation process. $Ca^{2+}$ ions in the calcium substances were easily converted to hydrates. A carbonation experiment was done, which used the method of $CO_2$ gas injection to produce suspensions by mixing fly ash with distilled water. The results were analyzed using TG-DTA, XRD, and pH meter measurements. The study was able to verify that the reaction was completed at a $CO_2$ flow rate of 300cc/min approximately 30 minutes after an injection into a solution with a solid-liquid ratio of 1 : 10 of fly ash and distilled water. Moreover, the stirring time of the suspensions did not influence the reaction, and the reaction time was found to diminish as the portion of the fly ash became smaller. Thus, this study produced carbon storage fly ash having a $CO_2$ storage rate of about 71% through the utilization of the CaO content contained within fly ash.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.28 no.1
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• pp.71-78
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• 2015

The reliable sloshing assessment methods for LNG CCS(cargo containment system) are important to satisfy the structural strength of the systems. Multiphase fluid flow of LNG and Gas Compressibility may have a large effect on excited pressures and structural response. Impinging jet model has been introduced to simulate the impact of the LNG sloshing and analyze structural response of LNG CCS as a practical FSI(fluid structure interaction) method. The practical method based on fluid structure interaction analysis is employed in order to evaluate the structural strength in actual scale for Mark III CCS. The numerical model is based on an Euler model that employs the CVFEM(control volume based finite element method). It includes the particle motion of gas to simulate not only the interphase interaction between LNG liquid and gas and the impact load on the LNG insulation box. The analysis results by proposed method are evaluated and discussed for an effectiveness of FSI analysis method.

• Plant Journal
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• v.16 no.3
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• pp.42-46
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• 2020

In the large LNG process in FLNG or FSRU, sudden temperature drops of the steel in the event of LNG leaks may cause brittle fracture of the structure. In this paper, we investigate the principle and process of forming a cryogenic fluid on a steel plate through a cryogenic spillage experiment, and analyze the correlation of the temperature distribution of the steel plate according to the distance from the nozzle and exposure time. Two types of cryogenic fluids were used: LN2 and LNG. The cyogenic liquid was released on the steel plate at 1.6L/min for LN2 and 1.5L/min for LNG. For the steel, DH was used and the temperature was measured at 10 points in total. The Leidenfrost effect was observed on the steel plate, and the temperature distribution of the steel was varied according the flow path and the heat of evaporation of the fluid.

• Journal of ILASS-Korea
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• v.23 no.3
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• pp.122-127
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• 2018

Recently, registrated passenger cars have increased and were close about seventy million at the end 2017 year in Korea. Among the passenger car using gasoline fuel make up forty six percentage of total registrated vehicles. In this study, investigation on real driving emission characteristics in the passenger car using gasoline fuel with various engine displacements were carried out. The real driving emission characteristics were measured and analyzed by using PEMS (Portable Emission Measurement System). PEMS was composed of gas analyzer, emission flow meter and sample conditioning system et al. Also, test six vehicles were selected to the gasoline passenger car with engine displacement from 1.6L to 3.7L. Two test routes with engine start of cold and hot conditions were applied to analyze the emission characteristics of RDE, respectively. The results show that the $CO_2$ emission have a increasing trend as the engine displacement and vehicle weight. Also, it is guessed that the $CO_2$ emission and vehicle weight were more correlated than the engine displacements. On the other hand, NOx emissions of RDE have not increasing or decreasing tendency according engine displacements or vehicle weight because the activation of three-way catalyst in the gasoline vehicles.

• Proceedings of the KSME Conference
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• 2001.06e
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• pp.125-130
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• 2001

Experimental and analytical researches have been conducted on the twin-fluid atomizers for better droplet breakup during the past decades. But, the studies on the disintegration mechanism still present a great challenge to understand the drop behavior and breakup structure. In an effort to describe the aerodynamic behavior of the sprays issuing from the internal mixing counter-swirling nozzle, the spatial distribution of axial (U) radial (V) and tangential (W) components of droplet velocities are investigated across the radial distance at several axial locations of Z=30, 50, 80, 120 and 170mm, respectively. Experiments were conducted for the liquid flow rates which was kept constant at 7.95 g/s and the air injection pressures were varied from 20 kPa to 140 kPa. Counter-swirling internal mixing nozzles manufactured at angles of $15^{\circ},\;30^{\circ},\;45^{\circ}$ and $60^{\circ}$ the central axis with axi-symmetric tangential-drilled holes was considered. The distributions of velocities and turbulence intensities are comparatively analyzed. PDPA is installed to specify spray flows, which have been conducted along the axial downstream distance from the nozzle exit. Ten thousand of sampling data was collected at each point with time limits of 30 second. 3-D automatic traversing system is used to control the exact measurement. It is observed that the sprays with all swirl angle have the maximum SMD for on air injection pressure of 20 kPa and 140 kPa with centerline, respectively. The nozzle with swirl angle of $60^{\circ}$ has vest performance.

• The Korea Journal of Herbology
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• v.22 no.2
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• pp.97-102
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• 2007

Objectives : This study presents a high performance liquid chromatography - electrospray ionization-mass spectrometer (HPLC-MS/MS) methods for the quantitative and qualitative analysis of various active components in Samul-tang, which is composed of four crude herbs. Methods : HPLC-ESI-MS/MS for the determinations of paeoniflorin and 5-HMF (5-hydroxymethyl 2-furaldehyde) in the Samul-tang, the separation method was performed on an COSMOS1L 5C18-AR-Il (2.0 X 150 mm I.D.) column by gradient elution with 0.1% acetic acid and 5% CH3CN in water (A)-0.1% acetic acid and 5% H20 in CH3CN (B) as the mobile phase at a flow-rate of 300 ${\mu}L/min$ with detection at quadrupole mass spectrometer. The all marker substances were always detected as the base peaks in the positive ion mode. Results : The paeoniflorin of Paeoniae Radix in Samul-tang showed a strong base peak [M+H2O]+ in the positive detection mode to give the following as; paeoniflorin (498.109 [M+H2O]+, 479.8 [M]+, 301 [M-glucose]+, 179.3 [glucose]+). Based on the HPLC retnetion time and MS of standard compounds confirmed the identity of active compounds in Rehmanniae Radix Preparata as follows; 5-HMF (127.0[M+H]+, 109.3 [M-OH]+) in the positive ion mode. Conclusion : According to the above results, HPLC-ESI-MS method permits assignment of tentative structures such as paeoniflorin and 5-HMF in the Samul-tang.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.2
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• pp.146-152
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• 2018

In the construction sector, new demands for aesthetics are increasing due to structural stability and improvement of living standard and consciousness level. On the other hand, Red Mud sludge is generated from aluminum hydroxide extraction process from Bauxite. Red mud sludge contains about 20% of $Fe_2O_3$ and represents a natural reddish brown. It is highly applicable to the construction industry. In this paper, red mud sludge with a water content of 50%, which is a by - product of the industry, was prepared as a liquid phase. The liquefied red mud was added to cement mortar and the strength and color difference of cement mortar were investigated according to the addition amount of liquefied red mud. As a result, the compressive strength decreased with increasing amount of liquefied red mud. The color of cement mortar containing liquefied red mud was found to be distributed in the range of YR series in all samples. As the amount of liquefied red mud increased, the color became darker.

• The Korea Journal of Herbology
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• v.26 no.2
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• pp.11-15
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• 2011

Objectives : In the present study, the contents of cinnamic acid and cinnamaldehyde in three different parts of Cinnamomi Ramulus (CR) (the whole body, the bark part, and the wood part) was evaluated using UPLC (ultra performance liquid chromatography) in order to investigate a suitable cutting method. Methods : Analysis was performed on SMART LC with UV detector. Reference compounds were separated on Inertsil ODS-4 column ($2.1mm{\times}50mm$, $3{\mu}m$, GL Science, Japan) using isolation elution with water and acetonitrile each containing acetic acid at a flow rate of $500{\mu}L/min$. Additionally, samples of CR were purchased from pharmacy of medicinal herb. Results : The correlation coefficients of the cinnamic acid and cinnamaldehyde levels showed good linearity ($r^2{\geq}0.9999$) over the linear ranges. Furthermore, the bark part exhibited higher concentration levels of reference compounds than the wood part in all samples. In addition the bark exfoliation rates in oblique and perpendicular-long cut samples of CR were lower than the perpendicular-short cut samples. Conclusions : These results suggested that the optimal cutting method would be able to reduce the bark exfoliation. Therefore, the oblique or perpendicular-long cutting method is considered to be a better cutting type than the perpendicular-short cutting method.

• Journal of Environmental Health Sciences
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• v.22 no.1
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• pp.36-44
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• 1996

A comparison was made of two detection methods(UV absorbence detection and fluorescence detection with pre-column derivatization, with trifluoroacetic acid) coupled with HPLC for the simultaneous determination of aflatoxin $B_1, B_2, G_1$ and $G_2$. A good separation of the four aflatoxins was achieved on a reversed-phase $C_{18}$ column (30 cm x 3.9 mm) with methanol-acetonitrile-water(20+20+60) for absorbence detection or acetonitrile-water(25+75) for fluorescence detection at the flow rate of 1.0 ml/min. The calibration graphs were linear over the ranges 100 ppb-1 ppm for $B_1/G_1$ and 30~300 ppb for $B_2/G_1$ with absorbence detection, and 1~500 ppb for $B_1/G_1$ and 0.3~150 ppb for $B_2/G_2$ with fluorescence detection. The correlation coefficients were greater than 0.94 and 0.99 for absorbance detection and for fluorescence detection, respectively. The detection limit was 100 ng for $B_1/G_1$ and 30 ng for $B_2/G_2$ with absorbence detection, and 1 ng for $B_1/G_1$ and 0.3 ng for $B_2/G_2$ with fluorescence detection. Recovery rates of aflatoxin $B_1, B_2, G_1$ and $G_2$ added to yeast-extract sucrose broth medium were 66.6%, 59.4%, 67.5% and 59.2%, respectively, for absorbence detection and 82.9%, 71.5%, 80.0% and 69.3%, respectively, for fluorescence detection. The four aflatoxins in culture medium were quantitatively detected by the two methods. The aflatoxins in the rice sample were not detected the absorbence detection method, but were below 10 ppb using the fluorescence detection method. Analysis of aflatoxins by both the absorbence and fluorescence methods coupled with HPLC showed acceptable linearity and good recovery. The absorbence detection was less timeconsuming and safer for treatment. The fluorescence detection was more elective and sensitive though elevated $B_1$ and $G_1$ contents were determined from the TFA-induced conversion of $B_1$ to $B_{2a}$ and $G_1$ to $G_{2a}$.