• 제목/요약/키워드: linking attack

검색결과 14건 처리시간 0.017초

수전해용 공유가교 SPEEK/Cs-TPA/Ceria 복합막의 제조 및 특성 연구 (The Preparation and Characteristics of Covalently Cross-Linked SPEEK/Cs-TPA/Ceria Composite Membranes for Water Electrolysis)

  • 송민아;하성인;박대영;유철휘;문상봉;강안수;정장훈
    • 한국수소및신에너지학회논문집
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    • 제23권5호
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    • pp.437-447
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    • 2012
  • Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted tungstophosphoric acid (Cs-TPA) with cross-linking agent contents of 0.01 mL. In conclusion, CL-SPEEK/Cs-TPA/ceria (1%) membrane showed the optimum results such as 0.130 S/cm of proton conductivity at $80^{\circ}C$, 2.324 meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 65.03 MPa of tensile strength which were better than Nafion 117 membrane.

결합재의 함량에 따른 순환굵은골재 사용 무세골재 폴리머 콘크리트의 성능 발현 특성 (Performance Characteristics of No-Fines Polymer Concrete using Recycled Coarse Aggregate with Binder Contents)

  • 김도헌;정혁상;김동현
    • 한국건설순환자원학회논문집
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    • 제9권4호
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    • pp.433-442
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    • 2021
  • 이 연구에서는 폴리머 결합재(불포화 폴리에스터 수지), 플라이 애시, 그리고 순환굵은골재(60%)와 부순굵은골재(40%)를 사용하여 폴리머 결합재 함량의 변화에 따른 무세골재 폴리머 콘크리트의 성질(9개항)에 대하여 연구하였다. 폴리머 결합재 함량(4.0-6.0wt.%)을 실험 변수로 한 이유는 비용측면에서 가장 큰 비중을 차지할 뿐만 아니라 각종 성능에 미치는 영향이 크기 때문이다. 연구결과 밀도, 압축강도, 휨강도, 동결융해 후 휨강도는 폴리머 결합재 함량이 증가함에 따라 증가하였고, 흡수율, 공극률, 연속공극률, 투수계수, 내산성(산에 의한 밀도 감소율)은 폴리머 결합재 함량이 증가함에 따라 감소하였다. 특히 폴리머 결합재 함량 6wt.%에서는 공극률이 18.4%, 투수계수가 7.3mm/sec 임에도 압축강도는 38.0MPa, 휨강도는 10.0MPa로서 기존의 연구결과들에 비해 월등히 높고, 흡수율, 내산성 등 다른 성질들도 우수한 것으로 나타났다. 이러한 결과는 가교제의 첨가에 의해 높아진 결합재의 부착력과 폴리머 결합재가 가진 표면 소수성에 기인하는 것이라고 하겠다.

태풍 내습 시의 고파 재현성 개선방안 연구 (A Study on the Methods to Improve High-Wave Reproducibility during Typhoon)

  • 백종대;류경호;이종인;정원무;장연식
    • 한국해안·해양공학회논문집
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    • 제34권6호
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    • pp.177-187
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    • 2022
  • 본 연구는 2020년 해양수산부에서 제시한 개정된 천해설계파 추산방법인 바람장을 이용하여 부산항 신항을 대상으로 태풍 내습 시 설계파를 추산하고 파랑 관측자료와의 검증을 통해서 신뢰할 수 있는 천해설계파 산출방법을 제안하였다. 부산항 신항에 영향을 미친 태풍에 대해서 현업에서 일반적으로 많이 사용하고 있는 태풍 바람장과 SWAN 수치모델을 이용하여 태풍파를 추산한 결과 태풍 KONG-REY(1825), MAYSAK(2009)을 제외하고 재현성이 불량한 것으로 나타났다. 특히 부산항 신항에 가장 크게 영향을 미쳤던 태풍 MAEMI(0314)의 경우 최대유의 파고가 파랑 관측치에 비해서 약 35.0% 작게 추산되었다. 이에 바람장을 보정한 방법과 Boussinesq 방정식 수치모델을 이용하는 방법을 각각 적용하여 태풍파 재현성 개선방안을 검토하였다. 검토결과 바람장을 보정한 경우는 바람장 보정전과 동일하게 재현성이 떨어지는 것으로 나타났으나, 바람장 자료와 SWAN 모델 실험결과 그리고 Bou ssinesq 수치모델을 연계하는 방법으로 태풍 MAEMI(0314) 내습 시 태풍파를 추산한 결과 파랑 관측치와 최대유의파고가 유사하게 나타나 재현성이 양호한 것으로 검토되었다.

「전간기 영국의 전략 우선순위 논의와 영국해군의 대응, 1919-1939」 (Discussion on the Strategic Priorities and Navy's Coping in the Interwar Period Britain, 1919?1939)

  • 전윤재
    • Strategy21
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    • 통권32호
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    • pp.123-159
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    • 2013
  • The purpose of this research paper is to re-valuate the factors that affected the Royal Navy's rearmament and preparation for war by conducting analysis on the discussion held in the Britain on the strategic priorities and Navy's coping measures adopted during the interwar period. After the end of the WWI, each of the military arms of the Britain faced significant difficulty in securing budget and increasing their military power all throughout the interwar period, and the Navy was not an exception. The WWII that got started on September 1939 was the turning point in which this difficulty led to full-fledged crisis. Immensely many criticisms followed after the war and problems were identified when it comes to the Royal Navy's performance during the war. This type of effort to identify problem led to the attempt to analyze whether Royal Navy's preparation for war and rearmament policy during interwar period were adequate, and to identify the root causes of failure. Existing studies sought to find the root cause of failed rearmament from external factors such as the deterioration of the Britain itself or pressure from the Treasury Department to cut the budget for national defense, or sought to detect problems from the development of wrong strategies by the Navy. However, Royal Navy's failed preparation for the war during interwar period is not the result of one or two separate factors. Instead, it resulted due to the diverse factors and situations that the Britain was facing at the time, and due to intricate and complex interaction of these factors. Meanwhile, this research paper focused on the context characterized by 'strategic selection and setting up of priorities' among the various factors to conduct analysis on the Navy's rearmament by linking it with the discussion held at the time on setting up strategic priorities, and sought to demonstrate that the Navy Department's inadequate counter-measures developed during this process waned Royal Navy's position. After the end of WWI, each of the military arms continued to compete for the limited resources and budget all throughout the interwar period, and this type of competition amidst the situation in which the economic situation of Britain was still unstable, made prioritization when it comes to the allocation of resources and setting up of the priorities when it comes to the military power build-up, inevitable. Amidst this situation, the RAF was able to secure resources first and foremost, encouraged by the conviction of some politicians who were affected by the 'theory of aerial threat' and who believed that curtailing potential attack with the Air Force would be means to secure national security at comparatively lower cost. In response, Navy successfully defended the need for the existence of Navy despite the advancement of the aerial power, by emphasizing that the Britain's livelihood depends on trade and on the maintenance of maritime traffic. Despite this counter-measuring logic, however, Navy's role was still limited to the defense of overseas territory and to the fleet run-off instead of sea traffic route production when it comes to the specific power build-up plan, and did not understand the situation in which financial and economic factors gained greater importance when it comes to the setting up of strategic priorities. As a result, Navy's plan to build its powers was met with continual resistance of the Treasury Department, and lost the opportunity to re-gain the status of 'senior service' that it had enjoyed in the past during the competition for strategic prioritization. Given that the strategic and economic situation that Korea faces today is not very different from that of the Britain during the interwar period, our Navy too should leverage the lessons learned from the Royal Navy to make the effort to secure viable position when it comes to the setting of priorities in case of national defense strategy by presenting the basis on why maritime coping should be prioritized among the numerous other threats, and by developing the measures for securing the powers needed effectively amidst the limited resources.

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