• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1754-1758
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• 2014

The nucleophilic substitution reactions of bis(Y-aryl) chlorothiophosphates (1) with X-pyridines are investigated kinetically in acetonitrile at $35.0^{\circ}C$. The free energy relationships with both X and Y are biphasic concave upwards with a break point at X = 3-Ph and Y = H, respectively. The sign of cross-interaction constants (CICs; ${\rho}_{XY}$) is positive with all X and Y. Proposed mechanism is a stepwise process with a rate-limiting leaving group departure from the intermediate with all X and Y. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). In the case of Y = electron-withdrawing groups, the cross-interaction between Y and Y, due to additional substituent Y, is significant enough to change the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1, indicative of the change of mechanism from a rate-limiting bond formation to bond breaking.

• Journal of the Korean Statistical Society
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• 제26권3호
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• pp.397-405
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• 1997

Recently maximum likelihood estimators using unconditional likelihood function are used for testing unit roots. When one wants to use this method the determinant term of initial values in the multivariate unconditional likelihood function produces a complicated function of the elements in the coefficient matrix and variance matrix. In this paper an approximation of the determinant term is calculated and based on this aproximation an approximated unconditional likelihood function is calculated. The approximated unconditional maximum likelihood estimators can be used to test for unit roots. When multivariate process has one unit root the limiting distribution obtained by this method and the limiting distribution using exact unconditional likelihood function are the same.

• 소성∙가공
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• 제9권4호
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• pp.379-388
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• 2000

This study aims to examine the influence of experimental and numerical factors on the results of the test and finite element simulation to evaluate the formability of sheet metals. The stretch-forming test with a hemispherical punch is carried out to obtain the limiting dome height (LDH) and forming limit diagram (FLD) for several kinds of aluminium and steel sheet. The results of the LDH and FLD tests are analysed to find any correlation with the uniaxial tensile properties. It proves that the size of the prescribed grid has great influence on the measured value of strain. The finite element analysis of the punch stretching process is also carried out and the result is compared with the experimental data. The influence of the numerical parameters such as friction coefficient, element size and anisotropy model on the simulation results tms out to be very considerable.

• Structural Engineering and Mechanics
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• 제35권6호
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• pp.699-715
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• 2010

This paper investigates the structural responses of axially restrained steel beams under fire conditions by a nonlinear finite element method. The axial restraint is represented by a linear elastic spring. Different parameters which include beam slenderness ratio, external load level and axial restraint ratio are investigated. The process of forming a mid-span plastic hinge at the mid-span under a rising temperature is studied. In line with forming a fully plastic hinge at mid-span, the response of a restrained beam under rising temperature can be divided into three stages, viz. no plastic hinge, hinge forming and rotating, and catenary action stage. During catenary action stage, the axial restraint pulls the heated beam and prevents it from failing. This study introduces definitions of beam limiting temperature $T_{lim}$, catenary temperature $T_{ctn}$ and warning time $t_{wn}$. Influences of slenderness ratio, load level and axial restraint ratio on $T_{lim}$, $T_{ctn}$ and $t_{wn}$ are examined.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1999년도 가을 학술발표회 논문집
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• pp.143-150
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• 1999

The LRFD Specification defines two sets of limiting width-to-thickness ratios. On the basis of these limiting values, steel sections we subdivided into three categories: compact, noncompact, and slender sections. A compact section is capable of developing a fully plastic stress distribution (plastic moment), and can sustain rotations approximately three times beyond the yield before the possibility of local buckling arises. Noncompact sections can develop the yield stress before local buckling occurs. They may not, however, resist local buckling at the strain levels required to develop the fully plastic stress distribution. In this paper, 1-Type girders of a 2 span continuous steel bridge are divided into compact and non-compact sections and analyzed. In the design process, an optimization skill was adopted and ADS, a Fortran program for Automated Design Synthesis, was used.

• 자원리싸이클링
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• 제14권1호
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• pp.55-63
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• 2005

This study investigated the electrochemical recovery of palladium in a HCl solution that is used for palladium leaching. The high acidity of HCl solution and the low concentration of Pd ions increased the cathodic overpotential and reduced the limiting current density. Lowering the current density produced dense deposits; however, they were under high tensile stress. Raising the temperature affected both the densification and the stress, which enabled the attainment of dense Pd deposits under low stress. Lowering the current density and raising the temperature up to 70$^{\circ}C$ was recommended for the recovery of palladium as sound bulk Pd deposits. Current efficiency was over 85% at the initial stage of recovery may decrease the current efficiency, since a low Pd ion concentration results in a low limiting current density.

• 한국광학회지
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• 제16권5호
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• pp.428-432
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• 2005

마이크로칼럼에 사용되는 전자렌즈는 MEMS 공정으로 정밀하게 가공되어 기존의 전자칼럼에 비하여 광학수차를 최소화 할 수 있으며, 이는 전자칼럼의 성능 향상에 주요한 요소로 작용한다. 따라서 반도체 공정 방식(습식식각과 건식식각)에 의해 형성되는 렌즈구조에 따른 전자 광학계 연구는 중요한 의미가 있다. 마이크로칼럼을 구성하고 있는 전자방출원, 소스렌즈, 디플렉터, 포커스렌즈(Einzel lens) 중에서 전자빔의 특성에 가장 큰 영향을 주는 것은 소스렌즈이다. 본 연구에서는 소스렌즈의 extractor와 limiting aperture의 구조에 따른 전자빔 특성을 조사하였다.

• 소성∙가공
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• 제7권3호
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• pp.225-232
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• 1998

This article is aimed primarily at establishing a process planning method for complex circular shells. For the deep drawing of complex shaped shell, the optimum process design is required to reduce the trial cost improve the quality, increase the productivity and shorten the delivery. The present approach which is related to the optimum process planning is based on the empirical knowledge through trial and error in the industrial field. In order to check the validity and the effectiveness of proposed work a sample process design has been applied to the multi-stepped deep drawing of com-plex shell considering the process variables such as drawing rate radius and blank development. In particular the difference between the limiting drawing rate and to optimum drawing rate has been discussed and the usefulness of present suggestion has been shown.

• 응용통계연구
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• 제7권1호
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• pp.103-112
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• 1994

본 논문에서는 비정상(단위근) 시계열이 포함된 다변량 시계열 자료에서 단위근에 해당되는 계수행렬 추정량의 극한 분포가 정상시계열의 유무에 상관없이 일정하다는 것을 밝혔다. 또한 단위근만 존재하는 다변량 시계열에서 다중단위근을 검정하는 검정통계량을 제안하였다.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1998년도 춘계학술대회논문집
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• pp.160-167
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• 1998

This article is aimed primarily at establishing a process planning method for complex circular shells. For the deep drawing of complex shaped shell, the optimum process design is required to reduce the trial cost, improve the quality, increase the productivity and shorten the delivery. The present approach which is related to the optimum process planning is based on the empirical knowledge through trial and error in the industrial field. In order to check the validity and the effectiveness of proposed work, a sample process design has been applied to the multi-stepped deep drawing of complex shell considering the process variables such as drawing rate, radius and blank development. In particular, the difference between the limiting drawing rate and the optimum drawing rate has been discussed and has been shown the usefulness of present suggestion.