• 한국물환경학회지
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• 제28권4호
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• pp.551-560
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• 2012

The objectives of this study were to elucidate spatio-temporal heterogeneity of water chemistry and develop empirical models using trophic variables in Daechung Reservoir during 2005-2010 along with in situ tests of nutrient enrichment bioassays (NEB). The relations of water quality parameters in regard to precipitation showed that seasonal and interannual fluctuations of biological oxygen demand (BOD), total nitrogen (TN) and pH were minor, whereas conductivity, suspended solids (SS), and total phosphorus (TP) were largely varied in response to the magnitude of rainfall. The CHL maxima occurred immediately after the spate of TP during the high flow, indicating that phytoplankton growth was directly controlled by phosphorus. Empirical linear models of CHL-TP indicated that the variation of CHL in premonsoon was accounted 60% ($R^2$ = 0.60, p < 0.05, n = 54) by TP. In the mean time, empirical models of annual CHL-TN showed that the variation of CHL was weakly accounted ($R^2$ = 0.16, p < 0.001) by TN and more strongly ($R^2$ = 0.44, p < 0.001) by TP. Thus, the variation of CHL was more explained by the variation of TP than TN. In situ tests of Nutrient Enrichment Bioassays (NEBs) showed that the growth of CHL was greater in the P-treatments (as $PO_4-P$) than the control and N-treatment (as $NO_3-P$). Overall, our results suggest that phosphorus was aprimary limiting nutrient controlling the seasonal phytoplankton growth, based on the in situ experiments of NEBs.

• Journal of Astronomy and Space Sciences
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• 제21권4호
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• pp.453-466
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• 2004

한국천문연구원에서는 적외선관측기술 개발의 일환으로 지상망원경용 근적외선 카메라인 KAONICS(KAO Near-Infrared Camera System)를 개발하고 있다. 이러한 개발의 선행 연구 과정으로서 우리는 보현산천문대와 소백산천문대의 근적외선($1-5{\mu}m$) 관측 조건을 정량적으로 조사했다. KAONICS의 기본 파장 밴드인 J, H, K, L 에 대해 대기 투과 모델을 사용하여 PWV(Precipitable Water Vapour)에 따른 대기투과율을 계산했으며, 각각의 파장 밴드에서 관측 한계 등급을 계산했다. 계산 결과, 두 천문대 모두 근적외선 영역에서 관측이 가능하며, 서로 비슷한 관측 능력을 가지고 있다는 결론을 얻었다.

• 천문학회보
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• 제36권2호
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• pp.121-121
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• 2011

Thanks to KMTNet's wide field of view, it is time to implement imaging survey of extensive area of clusters of galaxies in the southern sky with modern instrument. As part of potential long-term survey of nearby (D < 50 Mpc) well-known clusters of galaxies, we propose a wide-field and deep survey of Fornax cluster as a first step of the project. By imaging the 400 square deg region (100 fields) enclosed within the five times virial radius of the Fornax cluster, in three SDSSfilters(g', r', i'), we can provide an unprecedented view of structure of Fornax cluster using sample from giant to dwarf galaxies. We will secure galaxies with brightness comparable to the limiting magnitude (r'=23.1 AB mag) of SDSS. Furthermore, we also request extremely deep (limiting surface brightness of ~ 28 mag $arcsec^{-2}$forr'band) survey for the central region (16 square degree, i.e., four fields) of Fornax cluster. This will allow us to detect the diffuse intracluster light (ICL) that permeates clusters as a valuable tool for studying the hierarchical nature of cluster assembly. In order to complete whole survey, about 285 hr observing time (without overhead) is required. By combining data available at other wavelengths, it will offer unique constraints on the formation of large-scale structure and also provide important clues for theories of galaxy formation and evolution. Our proposed survey will be implemented in the close collaboration with researchers in various countries (Germany, Australia, UK, USA) and ongoing project (e.g., SkyMapper).

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 A
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• pp.185-187
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• 2000

Fault current is flowed into 154/23kV M. Tr when line-to-ground fault occurs in power system. NGR(Neutral Grounded Reactor) is set up in order to prevent M.Tr fault by limiting magnitude of fault currents. Here, disconnection of NGR causes voltage increase by L-C resonance and line-to-ground fault in an unearthed system results in voltage increase at healthy phases. So Over Voltage Ground Relay(OVGR) is used for tripping M.Tr. Also, buses at second phases of M.Trs are all connected with section circuit breakers closed for the purpose of parallel operation and load shedding. In case of speciality buses are comprised of power cable in part for GIS connection. When no-load charged cable or bus is open by a section CB, unbalanced voltage charged on the bus is induced. Also discrepant opening time for circuit breakers on different phases gives rise to unbalanced zero sequence voltage. It was observed that this zero sequence voltage detected in the 22.9kV P.T (Potential Transformer for bus) mal-operated 59GT and tripped M.Tr. The zero sequence voltage of which vanishing time is longer than relay operating time came out by EMTDC simulation. Also, it was shown that the voltage waves of actual test are similar to those of simulation. On the basis of above results, R-C circuit complement on the relay without any effect on a power system made operating time of the relay longer than vanishing time of distorted waves. Consequently, operating time of the relay was delayed and magnitude of distorted waves was decreased by increasing time constant of the relay.

• 천문학회지
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• 제50권3호
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• pp.71-78
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• 2017

We present the characteristics and the performance of the new CCD camera system, SNUCAM-II (Seoul National University CAMera system II) that was installed on the Lee Sang Gak Telescope (LSGT) at the Siding Spring Observatory in 2016. SNUCAM-II consists of a deep depletion chip covering a wide wavelength from $0.3{\mu}m$ to $1.1{\mu}m$ with high sensitivity (QE at > 80% over 0.4 to $0.9{\mu}m$). It is equipped with the SDSS ugriz filters and 13 medium band width (50 nm) filters, enabling us to study spectral energy distributions (SEDs) of diverse objects from extragalactic sources to solar system objects. On LSGT, SNUCAM-II offers $15.7{\times}15.7$ arcmin field-of-view (FOV) at a pixel scale of 0.92 arcsec and a limiting magnitude of g = 19.91 AB mag and z=18.20 AB mag at $5{\sigma}$ with 180 sec exposure time for point source detection.

• Bulletin of the Korean Chemical Society
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• 제24권8호
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• pp.1135-1140
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• 2003

The kinetics and mechanism of the pyridinolysis $(XC_5H_4N)$ of Y-aryl phenyl isothiocyanophosphates (1;$(YC_6H_4O)\;(C_6H_5O)$P(=O)NCS) are investigated in acetonitrile at 55.0 ℃. The Hammett plots for substituent (Y) variations in the substrate (log k₂ vs σY) exhibit a convex upward biphasic type with breaks at Y = H. For electron-donating Y groups the Hammett coefficients, ρY, are positive and cross-interaction constant ρXY is negative, while those for electron-withdrawing Y groups ρY values are negative with a positive ρXY. These results are interpreted to indicate mechanistic change at the breakpoint (σY = 0) from a concerted to a stepwise mechanism with rate-limiting expulsion of the $^-NCS$ group from a trigonal bipyramidal pentacoordinated (TBP-5C) intermediate. Biphasic plots of log k₂ vs σX or $pK_a$(X) with steeper slopes for the more basic nucleophiles are obtained suggesting an equatorial nucleophilic attack in contrast to an apical attack for the less basic nucleophiles with smaller magnitude of ρX or βx.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1945-1950
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• 2011

The pyridinolysis of methyl phenyl phosphinic chloride is investigated kinetically in acetonitrile at -20.0 $^{\circ}C$. The Hammett and Br${\o}$nsted plots for substituent X variations in the nucleophiles are biphasic concave downwards with a break point at X = H, and unusual positive ${\rho}_X$ (= 2.94) and negative ${\beta}_X$ (= -0.48) values are obtained for the strongly basic nucleophiles. A stepwise mechanism with a rate-limiting step change from bond breaking for the weakly basic pyridines to bond formation for the strongly basic pyridines is proposed on the basis of biphasic concave downward Hammett and Br${\o}$nsted plots. Unusual positive ${\rho}_X$ and negative ${\beta}_X$ values are rationalized by the isokinetic relationship. The pyridinolyses and anilinolyses of four $R_1R_2$P(=O)Cl-type substrates, dimethyl, diethyl, methyl phenyl, and diphenyl phosphinic chlorides in acetonitrile are compared to obtain systematic information on phosphoryl transfer reaction mechanism. The combination of the two ligands, Me and Ph, shows unexpected kinetic results for both the anilinolysis and pyridinolysis: greatest magnitude of $k_H/k_D$ (= 2.10) involving deuterated anilines $[XC_6H_4NH_2(D_2)]$ for the anilinolysis, and exceptionally fast rate and biphasic concave downward free energy correlation for the pyridinolysis.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.1406-1416
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• 2008

Soil nailing is used as a method of slope stabilization and excavation support. The design method of soil nail are based on experience or assumption of interaction between soil and reinforcement. Most design methods simply considers the tension of reinforcement for analysis of slope stabilization. Soil nails interact with soils under combined loading of shear and tension. Jewell & Pedley(1990) suggested a design equation of shear force with bending stiffness and discussed that the magnitude of the maximum shear force is small in comparison with the maximum axal force. However, they have used a very conservative limiting bearing stress on nails. This paper discusses that the shear strength of soil nails should not be disregarded with proper bearing stresses on nails. The modified FHWA design method was proposed by considering shear forces on nails with bending stiffness.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4304-4308
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• 2011

Kinetic studies of the reactions of O,O-dimethyl Z-S-aryl phosphorothioates with X-benzylamines have been carried out in dimethyl sulfoxide at $85.0^{\circ}C$. The Hammett (log $k_2$ vs ${\sigma}_X$) and Br$\ddot{o}$nsted [log $k_2$ vs $pK_a$(X)] plots for substituent X variations in the nucleophiles are discrete with a break region between 4-Me and H, while the Hammett plots (log $k_2$ vs ${\sigma}_Z$) for substituent Z variations in the leaving groups are linear. The sign of the cross-interaction constant (${\rho}_{XZ}$) is positive for both the strongly and weakly basic nucleophiles. Greater magnitude of ${\rho}_{XZ}$ (= 2.54) value is observed with the weakly basic nucleophiles compared to with the strongly basic nucleophiles (${\rho}_{XZ}$ = 0.17). The deuterium kinetic isotope effects ($k_H/k_D$) involving deuterated benzylamines [$XC_6H_4CH_2ND_2$] are primary normal ($k_H/k_D$ > 1). The proposed mechanism is a stepwise with a rate-limiting leaving group expulsion from the intermediate involving a frontside nucleophilic attack with a hydrogen bonded, four-center-type transition state for both the strongly and weakly basic nucleophiles.

• Applied Microscopy
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• 제38권1호
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• pp.63-72
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• 2008

Allen et al. (2004)에 의해 개발된 IWFR 방법에 대해서 응용성에 관심을 가지고 고찰되었다. 이 고찰에는 문헌에 보고된 GaAs, $YBa_2CuO_7$ 및 $Al_2CuMg$의 재료에 대한 HRTEM 연구물들이 이용되었다. 이 고찰 과정에서 이 방법의 타당성에 대한 이론적 근거, 제한조건 및 정보한계들을 명확히 제시되었다. IWFR 방법을 통해 얻은 결정 밑 표면에 전자 파동함수의 상(phase)-영상은 구면수차에 의한 영상 왜곡이 교정된 정보한계 범위 내에서 원자분해상을 나타낼 뿐만 아니라 결정의 구성원자의 원자번호에 대체적으로 비례하는 강도 분포를 나타내는 강한 경향이 있음이 특히 주목되었다.