• Title/Summary/Keyword: limestone area

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A Study on Gas-Liquid Contact in a Perforated Plate-Type $SO_2$ Absorber at Flooding Conditions

  • Han, Seung-Ho;Soowoo Kwon;Sangwon Jung;Jaehyuk Junk;Yang, Chang-Ryung;Carl Weilert
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.E
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    • pp.17-28
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    • 1999
  • Gas-liquid contact tests above a perforated-plate were conducted with air and water at flooding gas-flow conditions in order to study two-phase flow characteristics in a limestone-gypsum SO2 absorber. Gas layers were in the form of air pockets and confined to the limited areas around each duct pipe, while the remaining tary area were in the wet condition. The liquid above the tray was always in the flooded and even fluidized conditions at gas flows over the range studied, although vigorous bubbly or churn-turbulent two-phase regime was only observed in the immediate vicinity of the gas hole exit at low gas loads. The froth zone was extremely active to provide intimate contact between gas and liquid so that the necessary mass transfer operation can take place, which is the primary purpose of high-performance SO2 absorbers. Howefer, the absorber $\Delta$P was 250mmH2O for the initial water level at 150mm, which is an important issue to be resolved for economical operation of the SO2 absorber. It was seen in the liquid level-and gas flow-transient tests that changes in the absorber liquid inventory were much more pronounced for intimate gas-liquid contact than changes in the gas flow. Based on the 4- and 8-duct pipe test results, grouping the duct pipes near the center of the test tray seemed to promote better recirulation of liquid from gas-liquid contact zone back to the reaction tank so that the absorbed SO2 can be neutralized.

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Evaluating the Stability of Large-scale Gangways Mined in a Limestone Mine Using Rock Classification Schemes (암반분류법을 이용한 석회석 광산 내 대규격 갱도의 안정성 평가)

  • Yoon, Yong-Kyun;Lee, Hong-Woo
    • Tunnel and Underground Space
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    • v.17 no.6
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    • pp.503-510
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    • 2007
  • Rock classification schemes such as RMR, Q-system were applied to investigate the stability of large-scale gangways mined in a limestone mine. 22 areas for engineering geological surveys were selected and rock classifications at each survey point had been carried out. Considering the fact that the observed gangways have not experienced some severe failure and have been stably maintained till now, it is found that Q-system is more reasonable than RMR in evaluating the stability of unsupported span. Also, extended Mathews stability graph method which is a kind of revised Q-system was used to assess the stability of gangways and the results represent that all gangways except for one area are under stable condition. Based on above the mentioned results, the empirical equations to design the maximum unsupported span and critical height of a large-scale gangway are suggested.

A Study of Carvernous Limestone Aquifer of Jeon Cheon Basin (전천 석회암 대수층에 관한 연구)

  • 한종상
    • Water for future
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    • v.16 no.3
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    • pp.171-179
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    • 1983
  • In the Jeon Cheon Basin, unconsolidated alluvium and marine clay beds overlying Tertiary conglomerate and impermeable mudstone, and Cambro-Ordovician sedimentary rocks composed of mainly cavernous limestones, and age-unknowned crystalline rocks are occured. Most productive rock is Cambro-Ordovician limestones containing a lot of solution openings and secondary porosities and shows its transmissivity of 1836$m^2$/day and storativity of 1.47 $\times$ $10^{-3}$. The storage of deep seated groundwater in linestone aquifer is estimated about 1059 $\times$ $10^6$ metric tons, being equivalent to 6 years total precipitation of the basin. The safe yield of the groundwater to be abstracted from the aquifer is about 126,000 tons/day. To pump at least 100,000 tons/day of groundwater from the said aquifer, a well field comprising 34 deep wells ranging in depth from 80 to 100 meter and penetrating the cavernous limestone aquifer shall be established at middle and down stream area.

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Stratigraphy and Tectonics of Okcheon System in the Area between Chungju and Munkyeong (충주문경간(忠州聞慶間)의 옥천계(沃川系)의 층서(層序)와 구조(構造))

  • Kim, Oku Joon
    • Economic and Environmental Geology
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    • v.1 no.1
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    • pp.35-46
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    • 1968
  • Some of geologists in Korea recently postlated that Okchon system previously known to be precambrian age was the metamorphosed sediments of post-Chosen (Ordovician and pre-Kyeongsang (late Jurassic to Cretaceous) periods, or even definitely of Triassic period simply on the basis of the fact that Okcheon system overlies the Great Limestone series of Chosen system of Camber-ordovician age, and of other few assumptions of minor importance. As a result of such correlation, thick series of metasediments and Okcheon system of unknown age were established in this particular region and vaguely correlated to Paleozoic and Mesozoic sediments. Recent study done by the author reveled that: 1) only the upper Okcheon bed of S. Nakamura was true Okcheon system, and the middle and lower Okcheon beds were excluded, because they were correlated to Cambrian and Permian sediments resfectively, 2) Sangnaeri, Seochangri, and rengam formations of unknown age, and Baekhwasan, Jobong, and Ihwaryeong formations of Okcheon system of also unknown age were the metamorphosed Yangdeok system of Cambrian age, all of these formations were differentiated by the previous workers and were equivalent to the middle Okcheon system of S. Nakamure, and. 3) These metamorphosed Yangdeok system overlaid apparently the Great Limestone series in forms of overthrust and klippe which were produced by the orogeny took place during post-Daedong and pre-Kyeongsang period (probably middle to the Jurassic). The Sobaeksan Range, folded mountain Chains was also formed by this orogeny. Thus, Okcheon system newly defined by the author is precambrain age and consists in ascending order of Kemyenogsan, Hyangsan dolomite, and Daehangsan quartzite formation which were previously classified into metasediments of unknown age, and Munjuri, and Hwangkanri, formations which were differentiated into Okcheon system unknown age by the previous workers, but are of reversed sequence. Myeongori and Bukrori formations of Okcheon System are regard by the author as part of Hwangkanri formation. Few other assumption of minor important taken by the previous workers as their positive evidences are carefully explained that they were misinterpreted.

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Study on The Contact Metamorphism of Weolagsan Granite (월악산화강암(月岳山花崗岩)의 접촉변성(接觸變成)에 관(關)하여)

  • Lee, Dai Sung;Kang, Jun Nam
    • Economic and Environmental Geology
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    • v.11 no.4
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    • pp.169-182
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    • 1978
  • The Weolagsan area consists of four units; (1) Low grade meta-sediments of the upper members of Ogcheon age unknown group such as Changri (mainly black slate and phyllitic rock), Majeonri (mainly alternation of slate, limestone and chert) and Hwanggangri Formation (pebble bearing phyllitic sediments); (2) Samtaesan Formation of Chosun System of Ordovician; (3) So called meta-volcanics and (4) Weolagsan Granite and its associations which intruded above mentioned meta-sediments and meta-volcanics. This study was focused to know the Woelagsan granite and its metasomatic effects to the country rocks petrographically and petrochemically. According to the field survey, microscopic work and some chemical analysis, the granite is a "normal granite" based on the Streckeisen's classification and belongs to a mass of the Central-zone younger group in Ogcheon geosynclinal belt. The granite metasomatized the country rocks along its northern contact zone. Zone of calcareous and cherty rocks (Majeonri formation) was silicified partly and skarned locally at the contact with the granite. The chemical analysis of the zone show no difinite variations in contents of $SiO_2$ and CaO with the distance from the granite. It seems to be indicated that the silicification of this part was not so metasomatized by the granite body, but thermally affected as much as to be partially remelted in the specific parts of the formations. Meta-volcanic rock zone was slightly chloritized near contact with the granite. Limestone of Samtaesan Formation was silicified and skarned along the contact zone by the granite body. The chemical analysis of the zone show some noticiable changes in compositions of $SiO_2$ and CaO with distance from the granite boundary. It can be imagined that the silicification of this zone was metasomatically originated by Woelagsan Granite. According to chemical analysis on several trace elements, the ratio of Zn/Cr and Ni/Cr are relatively higher than that of Cu/Cr in the above mentioned silicified zones. Generally the variation of these metal elements in the zones tend to be regular with distance from the granite body.

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Development of fiber reinforced self-compacting concrete (FRSCC): Towards an efficient utilization of quaternary composite binders and fibers

  • Fediuk, Roman;Mosaberpanah, Mohammad A.;Lesovik, Valery
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.387-395
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    • 2020
  • This study has been carried out in two-phases to develop Fiber Reinforced Self-Compacting Concrete (FRSCC) performance. In the first phase, the composition of the quaternary composite binder compromised CEM I 42.5N (58-70%), Rice Husk Ash (25-37%), quartz sand (2.5-7.5%) and limestone crushing waste (2.5-7.5%) were optimized. And in the second phase, the effect of two fiber types (steel brass-plated and basalt) was investigated on the SCC optimized with the optimum CB as disperse reinforcement at 6 different ratios of 1, 1.2, 1.4, 1.6, 1.8, and 2.0% by weight of mix for each type. In this study, the theoretical principles of the synthesis of self-compacting dispersion-reinforced concrete have been developed which consists of optimizing structure-formation processes through the use of a mineral modifier, together with ground crushed cement in a vario-planetary mill to a specific surface area of 550 m2 / kg. The amorphous silica in the modifier composition intensifies the binding of calcium hydroxide formed during the hydration of C3S, helps reduce the basicity of the cement-composite, while reducing the growth of portlandite crystals. Limestone particles contribute to the formation of calcium hydrocarbonate and, together with fine ground quartz sand; act as microfiller, clogging the pores of the cement. Furthermore, the results revealed that the effect of fiber addition improves the mechanical properties of FRSCC. It was found that the steel fiber performed better than basalt fiber on tensile strength and modulus of elasticity; however, both fibers have the same performance on the first crack strength and sample destruction of FRSCC. It also illustrates that there will be an optimum percentage of fiber addition.

Characteristics of Polymetallic Occurrence in Kau Loc Area within Northern Vietnam: Preliminary Study (베트남 북부 카우록 다중금속 산출지의 특성: 예비연구)

  • Heo, Chul-Ho;Chi, Se-Jung;Park, Sung-Won;Lee, Jae-Ho
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.345-357
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    • 2011
  • It was carried out to the survey on the lead-zinc and tungsten occurrences in the Kau Loc mineralized belt within northern Vietnam. The lead-zinc occurrence bear the ore body parallel to the bedding of limestone formation. Assuming the surface grade and geological reserve, Pb+Zn deposit is estimated to the small to medium-sized ore deposit. On the other hand, considering the distribution of small-scale stock intruding the Devonian limestone, it is thought that the tungsten occurrence has the proper geological conditions anticipating the presence of skarn mineralization. However, there is no evidence to recognize economic feasibility in the present situation because of the absence of detailed geology and ore deposit survey on the tungsten occurrence.

Behavior Analysis of Discharged DIC Concentrated Seawater through Towed Pipe Injection from Ship

  • Kwon, Seong-Min;Kim, Kang-Min;Song, Hyeon-Woo;Lee, Joong-Woo
    • Journal of Navigation and Port Research
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    • v.43 no.2
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    • pp.79-85
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    • 2019
  • Climate change is a very vital issue that can be no longer avoided. Korea has been a top-level country Iin dealing with carbon dioxide emissions since 1960. Many studies have been conducted to suppress or eliminate carbon dioxide emissions, which account for a large portion of greenhouse gases. Carbon Capture and Storage (CCS), the most practical method of them, plays a significant role. However, these methods have the disadvantage of the limits of geographical distribution and high possibility of re-emission into the atmosphere. Recently, ocean storage has been studied using Accelerated Weathering of Limestone (AWL), a technique for storing carbon dioxide in the ocean as an alternative to CCS, an underground storage. AWL is a method of converting carbon dioxide into concentrated water in the form of bicarbonate ion and discharging it to the ocean to dilute and store it. It does not cause re-emission to the atmosphere, and the discharged concentrated water increases the alkalinity of the ocean to prevent marine acidification. The objective of this study was to understand the behavior of DIC (Dissolved Inorganic Carbon) including carbon dioxide during the ocean discharge of bicarbonate ion concentrated water in AWL method. This study area was set near Ulleung-do where sufficient water depth and operational efficiency were secured. CORMIX model was used to calculate the material diffusion by submerged discharge using ship.

Developing for Reduction Technology of AMD through Coating on the Surface of Pyrite Using Minerals (천연광물을 이용한 황철석 표면 코팅을 통한 폐광산 산성배수 저감 기술 개발)

  • Yun, Hyun-Shik;Gee, Eun Do;Ji, Min Kyu;Lee, Woo Ram;Yang, Jung-Seok;Park, Young-Tae;Kwon, Hyun-ho;Ji, Won-Hyun;Kim, Kijoon;Jeon, Byong-Hun;Choi, Jaeyoung
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.2
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    • pp.15-22
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    • 2011
  • In this study, the effect of surface coating on iron-sulfide mineral for preventing the product acid mine drainage(AMD) was progressed by oxidation process of sulfide minerals abandoned mine Area. Three abandoned mines, Yongdong coal mine, Sil Lim mine, and Il Koang mine were selected as a sulfide mineral resource due to higher contamination rate. Six coating agents, apatite, limestone, mangnite, dolomite, bentonite, and cement were used for preventing the AMD with $H_2O_2$ and NaClO as a oxidizing agent helping for oxidizing process on sulfide minerals. Experimental results showed that sulfide mineral surface was coated effectively. Cement has a higher ability of preventing AMD when the ratio of cement to mineralis 1:1 and experimental condition is maintaining 4Days.

Mineralogical Studies on Sulfide Ore Species of the Tong Myeong Tungsten Deposits (동명중석광산산(東明重石鑛山産) 유화광물(硫化鑛物)의 광물학적(鑛物學的) 연구(硏究))

  • Lee, Pyeong-Koo;So, Chil-Sup;Kim, Se-Hyun;Yun, Seong-Taek;Kim, Moon-Young
    • Economic and Environmental Geology
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    • v.19 no.spc
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    • pp.207-226
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    • 1986
  • The skarn type tungsten deposits in Jechon area are developed in the contact aureole of Jurassic granodiorite and lower Paleozoic limestone beds. The Tong Myeong mine contains scheelitebearing skarns found at and near the contacts between crystalline limestone and hornfels. Although the skarns are heterogeneous, there are clear patterns in the preferred associations and nonassociations of minerals on all scales. The skarn show a zonal arrangement from limestone to hydrothermal vein as follow: wollastonite skarn, clinopyroxene skarn, clinopyroxene-garnet skarn, garnet skarn, and vesuvianite skarn. Scheelite, abundant in all skarn units except wollastonite skarn and also in quartz veins near orebodies, is everywhere strongly correlated with pyrrhotite. It is implied that it was a stable phase throughout the evolution of the zoned skarns, at least in pyrrhotite.forming environments. Deposition of scheelite was probably widely caused by increasing $a_{Ca^{2+}}$ in the fluid, resulting from associated and interrelated reactions: $FeCl_2\;aq+H_2S\;aq{\rightarrow}FeS+2H^{+}+2Cl^-$; and $CaCO_3+2H^+{\rightarrow}Ca^{+2}+H_2CO_3$. The spectral reflection powers of nine sulfide species were studied, for three mineralization stage. The shapes and characteristics of the spectral reflectivity profiles are significant in their control of other optical properties. The characteristics of the Vickers microhardness and the optical symmetry for the minerals studied are discussed. Broad radicle groupings of the sulfides can be made with regard to the reflectivity-microhardness values.

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