• Title/Summary/Keyword: lime treatment

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Chemical Strengthening Involving Outward Diffusion Process of Na+ Ion in Iron-containing Soda-lime Silicate Glass

  • Choi, Hyun-Bin;Kang, Eun-Tae
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.133-136
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    • 2015
  • The outward diffusion of $Na^+$ ions in iron-bearing soda lime silicate glass via oxidation heat treatment before the ion exchange process is artificially induced in order to increase the amount of ions exchanged during the ion exchange process. The effect of the addition process is analyzed through measuring the bending strength, the weight change, and the inter-diffusion coefficient after the ion exchange process. The glass strength is increased when the outward diffusion of $Na^+$ ions via oxidation heat treatment before the ion exchange process is added. For the glass subjected to the additional process, the weight change and diffusion depth increase compared with the glass not subjected to the process. The interdiffusion coefficient is also slightly increased as a result of the additional process.

Loess and Lime Treatment for Modification of Waterworks Sludges (황토와 석회의 혼합처리에 의한 정수 슬러지의 개질화에 관한 연구)

  • Lim, Sung-Jin;Cho, Jae-Jun;Lee, Jae-Bok
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.4
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    • pp.318-327
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    • 2000
  • Sludge production from water treatment plants is increasing each year because water resources deterioration is proceeding and water supply facilities are growing due to water demand increase. Water treatment plant sludges can be modified to soil cover in sanitary landfilling site through the lime treatment and other alternatives. The compression strength of $1.0kg/cm^2$ is necessary for the dozer operation on soft son cover material at municipal landfilling site. Modified sludge was experimentally produced in this study with lime, bentonite, loess, and activated loess dosing. X-ray diffraction patterns of the limed water treatment plant sludge confirmed the presence of calcium carbonate and ettringite. Unconfined compression strength properties of modified sludges showed material property improvement applicable for soil cover alternatives. When adding 20-30% activated loess to water treatment plant sludges. the modified sludges could reach the compression strength for cover soil after 7 days solidification reaction, but decrease of compression strength was intentioned in 28 days reaction period. Solidification effect of the modified sludge with activated loess was observed through the scanning electron microscope.

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A Development of Landfill Liner by Utilizing Waste Lime (폐석회를 이용한 매립지 차수재 개발)

  • 김준섭;이승학;박준범
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.521-528
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    • 1999
  • As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

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Soil-Lime and Additives Stabilization (석회와 여러 첨가제에 의한 토질안정처리)

  • 민덕기;황광모;박근호
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.657-664
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    • 2000
  • Weak and soft compressible clay deposits are commonly found in natural subgrade soils. These Soils need to be stabilized for using the subbase materials of highway constructions. This paper presents that a chemical treatment using chemical additives comprised of sulfate(SO$_4$) and chloride(Cl) is evaluated for stabilizing soft clay deposits and lime. The physical and mechanical characteristics of soil-lime and additives are described by means of a laboratory study. The study results indicate that the presence of chlorides encouraged the efficiency of lime stabilization, and the use of calcium chloride with quicklime is the best additive for improving soil behavior. The treated soil with lime-calcium chloride can have the adaptability to the subbase materials of highway constructions.

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The study of chemical treatment of pulp mill bleaching waste liquor using sea water (해수를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구)

  • 정병곤;이헌모;윤종호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.39-48
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    • 1997
  • The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

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폐탄광지역 퇴적물의 중금속 존재형태 및 안정화에 관한 연구

  • Lee Jeong-Ran;Lee Jae-Yeong;Kim Hwi-Jung
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.253-259
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    • 2005
  • Mine is quickly decline, Nowadays, many of abandoned and closed mines. AMD is abandoned surface water by accumulated yellowboy and caused environmental pollution by amount of heavy metals. The aim of this study waste lime was mixed with the sediment to produce an aggregate far the purpose of neutralizing the acidity and stabilization the heavy metal in the aggregate structure .to pozzolan effect. The result of Waste lime and sediment mixed(5%, 10%, 20%)ration by curing days(3, 7, 38days), After 28 curing days as 5% mixed waste lime leaching solution concentration of all heavy metals is satisfied with regulation limit. Also, the result of fractionate heavy metals to stabilization as 28 curing days very decrease exchangeable and reducible type, and then increase carbonate type. With the above results, waste lime the most effective for the sediment treatment and useful for the recycling waste resource.

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부산석회를 활용한 휴ㆍ폐 석탄광산 폐기물에서 유출된 침출수의 안정화

  • 김휘중;양재의;옥용식;유경열;박병길;이재영;전상호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.48-58
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    • 2004
  • Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing neutralizing the AMD from runoff and leachate in an attempt find the sink to dispose the lime wastes and alleviate the environmental problems caused by the closed coal mines. The pH changes of the runoff and leachate collected in the tanks at the end of the experimental plots, averaged over measurements from April to August, indicated that the runoff pH of the coal overburden was 4.3 but increased significantly to the ranges of 6.7 to 7.1 with treatments of tile calcites and lime wastes. This might be related with the decreases in Fe concentrations in the runoff and leachate from the coal overburdens. The Fe concentrations in tile runoff seemed to increase with the amounts of precipitation. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

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Phosphorus removal by lime-natural mineral dissolved solutions

  • Joohyun, Kim;Sunho, Yoon;Jueun, Jung;Sungjun, Bae
    • Membrane and Water Treatment
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    • v.14 no.1
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    • pp.27-33
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    • 2023
  • In previous studies, solely ferric (Fe3+) and calcium (Ca2+) ions were commonly used for removal of PO4-P (considered as T-P in this study) in wastewater via chemical precipitation. Herein, the removal of total phosphorus (T-P) in wastewater was performed using various mineral and lime dissolved solutions. The dissolution kinetics of different minerals (feldspar, olivine, elvan, illite, sericite, and zeolite) and lime was compared and used their solutions for T-P removal of real wastewater. The highest T-P removal (almost 90%) was obtained by the lime dissolved solution and followed by zeolite, illite, feldspar, and others. We observed a significant co-relationship (R of 0.96) between the amount of initial Ca2+ and T-P removal. This was induced by formation of hydroxyapatite-like mineral via Ca-P precipitation reaction at high pH solution. Furthermore, additional removal of suspended solid (SS) and chemical oxygen demand (COD) was achieved by only lime dissolved solution. Finally, the lime-feldspar dissolved solutions were prepared at different ratios (10-50%), which showed a successive T-P removal up to two times by samples of 40 and 50%.

Bending strength of alumina coated with bioglass and soda lime glass and the precipitation on the surface of coated alumina in PBS (생체 유리와 소다 유리침투에 따른 알루미나 세라믹의 굴곡 강도 및 PBS에서의 표면 생성물 연구)

  • Yuu, Jae-Yang
    • Journal of Technologic Dentistry
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    • v.30 no.2
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    • pp.39-45
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    • 2008
  • Titanium and its alloys are widely used as dental implants materials because of their excellent mechanical properties. However, the alumina and zirconia ceramics are preferred to use as the substitute of Ti implants because there is a problems in esthetics and biocompatibility in Ti implant. The the glass infiltrated alumina ceramics are studied to increase the toughness and biocompatibility. The 45S5 and soda-lime glass powder was mixed with ethanol at ratio of 1:1 and brushed on the surface of alumina. Then it was heat treated in the electric furnace at $1400^{\circ}C$ from 30 min. to 5 hours. The glass powder was controlled from 200 to $350{\mu}m$ using ball milling. After heat treatment, the glass infiltrated specimen was tested in universal testing machine to measure the bending strength. The surface microstructure of each specimen was observed with SEM. The biocompatibility of 45S5 and soda-lime glass coated alumina was investigated using PBS at $36.5^{\circ}C$ incubator. The specimen was immersed in PBS for 3, 5, 7, 10 days. After that, the surface morphology was investigated with SEM. As the results of experiment, the 45S5 bioglass infiltrated alumina show the increase of bending strength according to the increasing of heat treatment time from 30 min. to 5 hours at $1400^{\circ}C$ Finally the 1370N bending strength of alumina increased to 1958N at 5 hours heat treatment, which shows 1.4 times higher. In contrast to this, the soda lime glass infiltrated alumina ceramics shows the convex curve according to heat treatment time. Thus it shows maximum bending strength of 1820N at 1 hour heat treatment of $1400^{\circ}C$ It gives 1.3 times higher. However, the bending strength of soda lime glass infiltrated alumina is decreasing with increasing heat treatment time after 1 hour. The precipitation on the surface of 45S5 glass infiltrated alumina was revealed as a sodium phosphate ($Na_{6}P_{6}O_{24}6H_{2}O$) and the amount of precipitation is increasing with increasing of immersion time in PBS. In contrast to this, there is no precipitation are observed on the surface of soda lime glass infiltrated alumina. This implies that 45S5 glass infiltrated alumina brings more biocompatible when it is implanted in human body.

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Composting using the Lime Stabilization of Dewatering Sludge from Centralized Swine Wastewater Treatment Facility (석회안정화 방법을 이용한 돈사분뇨공공처리시설에서 발생하는 탈수슬러지의 퇴비화)

  • Hwang, In-Su;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.687-694
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    • 2006
  • Dewatering sludge using inorganic chemicals with polymer has been evaded for reuse on account of the risks of high heavy metals contained and soil acidification. Composting feasibility of coagulation & dewatering sludges produced from livestock waste treatment plant was investigated. The results of analysis prove that dewatering sludge is valuable matter with suitable elements for composting if high quality ferric chloride ($FeCl_3$) is used for coagulation & dewatering process. In pot-cultivation of harvestes, using effects of dewatering sludge improved with lime treatment was very effective. The results of pot-cultivation proved that harms of crops according to different acid tolerances were not detected. But it was not applied to crops with weak acid tolerance or greenhouse for free from gas damage. Also, Further studies and monitorings are necessary to use sludges because results of pot-cultivation were generated differently by characteristics of soil, nutrient demand of plants, mature degree of sludge, consecutive cultivation and etc.