• Title/Summary/Keyword: lead optimization

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Determination of Trace Amounts of Lead and Copper in Water Samples by Flame Atomic Absorption Spectrometry after Cloud Point Extraction

  • Shemirani, Farzaneh;Abkenar, Shiva Dehghan;Khatouni, Asieh
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1133-1136
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    • 2004
  • The need for highly reliable methods for the determination of trace metals is recognized in analytical chemistry and environmental science. A method based on the cloud-point extraction (CPE) technique for the trace analysis of Pb and Cu in water samples is described in this study. The analytes in the initial aqueous solution are complexed with pyrogallol, and 0.1%(w/v) Triton X-114 is added as surfactant. Following phase separation at $50^{\circ}C$, based on the cloud point of the mixture and dilution of the surfactant-rich phase with acidified methanolic solution, the enriched analytes are determined by flame atomic absorption spectrometry. After optimization of the complexation and extraction conditions, the enrichment factors of Pb and Cu were found to be 72 and 85, respectively. Under optimum conditions, the preconcentration of 60 mL of samples in the presence of 0.1%(w/v) Triton X-114 permitted the detection of 0.4 ${\mu}gL^{?1}$ of Pb and 0.05 ${\mu}gL^{?1}$ of Cu. The proposed method was applied successfully to the determination of Pb and Cu in water samples.

Synthesis of a Novel Series of Imidazo[1,2-α]pyridines as Acyl-CoA: Cholesterol Acyltransferase (ACAT) Inhibitors

  • Jin, Ying-Lan;Rho, Mun-Chual;Gajulapati, Kondaji;Jung, Hwa-Young;Boovanahalli, Shanthaveerappa K.;Lee, Jee-Hyun;Song, Gyu-Yong;Choi, Jung-Ho;Kim, Young-Kook;Lee, Kyeong;Choi, Yong-Seok
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1297-1304
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    • 2009
  • A novel series of imidazo[1,2-$\alpha$]pyridines was designed, synthesized, and tested for their ability to inhibit acyl- CoA:cholesterol acyltransferase. Preliminary lead optimization efforts resulted in the identification of ACAT inhibitors represented by analogues 5b, 5c, 6a, 6c, 7b, and 7c. The ACAT inhibitory activity of these compounds was further established by potent inhibition of cholesteryl ester formation in HepG2 cells by a representative analogue 7b.

Analysis of Power Variation and Design Optimization of a-Si PV Modules Considering Shading Effect (음영효과를 고려한 a-Si PV모듈의 출력 변화 및 최적 설계조건에 관한 연구)

  • Shin, Jun-Oh;Jung, Tae-Hee;Kim, Tae-Bum;Kang, Ki-Hwan;Ahn, Hyung-Keun;Han, Deuk-Young
    • Journal of the Korean Solar Energy Society
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    • v.30 no.6
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    • pp.102-107
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    • 2010
  • a-Si solar cell has relatively dominant drift current when compared with crystalline solar cell due to the high internal electric field. Such drift current make an impact on the PV module in the local shading. In this paper, the a-Si PV module output characteristics of shading effects was approached in terms of process condition, because of the different deposition layer of thin film lead to rising the resistance. We suggested design condition to ensure the long-term durability of the module with regard to the degradation factors such as hot spot by analyzing the module specification. The result shows a remarkable difference on module uniformity for each shading position. In addition, the unbalanced power loss due to power mismatch of each module could intensify the degradation.

Life-Cycle Cost Optimization of Slab Bridges with Lightweight Concrete (경량 콘크리트를 이용한 슬래브교의 생애주기비용 최적설계)

  • 정지승;조효남;최연왕;민대홍;이종순
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2002.04a
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    • pp.257-264
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    • 2002
  • This study presents a life-cycle cost (LCC) effectiveness of a concrete with lightweight aggregate. A number of researchers have made their efforts to develop a lightweight concrete, since it is difficult to apply conventional concrete using general aggregate to heavy self-weight structures such as long span bridges. In this study, an optimum design for minimizing the life-cycle cost of concrete slab bridges is performed to evaluate the life cycle cost effectiveness of the lightweight concrete relative to conventional one from the standpoint of the value engineering. The data of physical properties for new concrete can be obtained from basic experimental researches. The material properties of conventional one are acquired by various reports. This study presents a LCC effectiveness of newly developed concrete, which is made by artificial lightweight aggregate. A number of researchers have made their efforts to develop a lightweight concrete, since it is difficult to apply conventional concrete using general aggregate to heavy self-weight structures such as long span bridges. From the results of the numerical investigation, it may be positively stated that the new concrete lead to, the longer span length, the more economical slab bridges compared with structures using general concrete.

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Investigation of Burst Pressures in PWR Primary Pressure Boundary Components

  • Namgung, Ihn;Giang, Nguyen Hoang
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.236-245
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    • 2016
  • In a reactor coolant system of a nuclear power plant (NPP), an overpressure protection system keeps pressure in the loop within 110% of design pressure. However if the system does not work properly, pressure in the loop could elevate hugely in a short time. It would be seriously disastrous if a weak point in the pressure boundary component bursts and releases radioactive material within the containment; and it may lead to a leak outside the containment. In this study, a gross deformation that leads to a burst of pressure boundary components was investigated. Major components in the primary pressure boundary that is structurally important were selected based on structural mechanics, then, they were used to study the burst pressure of components by finite element method (FEM) analysis and by number of closed forms of theoretical relations. The burst pressure was also used as a metric of design optimization. It revealed which component was the weakest and which component had the highest margin to bursting failure. This information is valuable in severe accident progression prediction. The burst pressures of APR-1400, AP1000 and VVER-1000 reactor coolant systems were evaluated and compared to give relative margins of safety.

A Numerical Study on the Improvement of the Performance of a Vehicle Paint Drying Process (자동차 도장 건조 공정의 건조 성능 향상을 위한 수치해석 연구)

  • Choi, Jongrak;Hur, Nahmkeon;Kim, Dongchoul;Kim, Hee-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.12
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    • pp.867-874
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    • 2012
  • In the present study, three-dimensional transient numerical simulations were carried out to improve the performance of a vehicle paint drying process. In order to describe the movement of a vehicle, the techniques of moving boundary condition and multiple reference flames (MRF) were used. For the validation of the numerical analysis, the predicted temperature on the surface of a vehicle was compared to the experimental data, and a good agreement was achieved. With validated numerical procedure, various operating conditions of the temperature and the flow rate of the supply air were investigated to improve the drying performance of the facility. It is shown that the optimization of the operating condition can lead to energy savings and faster line speed of the production.

An Approximation Approach for Solving a Continuous Review Inventory System Considering Service Cost (서비스 비용을 고려한 연속적 재고관리시스템 해결을 위한 근사법)

  • Lee, Dongju;Lee, Chang-Yong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.38 no.2
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    • pp.40-46
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    • 2015
  • The modular assembly system can make it possible for the variety of products to be assembled in a short lead time. In this system, necessary components are assembled to optional components tailor to customers' orders. Budget for inventory investments composed of inventory and purchasing costs are practically limited and the purchasing cost is often paid when an order is arrived. Service cost is assumed to be proportional to service level and it is included in budget constraint. We develop a heuristic procedure to find a good solution for a continuous review inventory system of the modular assembly system with a budget constraint. A regression analysis using a quadratic function based on the exponential function is applied to the cumulative density function of a normal distribution. With the regression result, an efficient heuristics is proposed by using an approximation for some complex functions that are composed of exponential functions only. A simple problem is introduced to illustrate the proposed heuristics.

Cross-Layer Reduction of Wireless Network Card Idle Time to Optimize Energy Consumption of Pull Thin Client Protocols

  • Simoens, Pieter;Ali, Farhan Azmat;Vankeirsbilck, Bert;Deboosere, Lien;Turck, Filip De;Dhoedt, Bart;Demeester, Piet;Torrea-Duran, Rodolfo;Perre, Liesbet Van der;Dejonghe, Antoine
    • Journal of Communications and Networks
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    • v.14 no.1
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    • pp.75-90
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    • 2012
  • Thin client computing trades local processing for network bandwidth consumption by offloading application logic to remote servers. User input and display updates are exchanged between client and server through a thin client protocol. On wireless devices, the thin client protocol traffic can lead to a significantly higher power consumption of the radio interface. In this article, a cross-layer framework is presented that transitions the wireless network interface card (WNIC) to the energy-conserving sleep mode when no traffic from the server is expected. The approach is validated for different wireless channel conditions, such as path loss and available bandwidth, as well as for different network roundtrip time values. Using this cross-layer algorithm for sample scenario with a remote text editor, and through experiments based on actual user traces, a reduction of the WNIC energy consumption of up to 36.82% is obtained, without degrading the application's reactivity.

EA Experiences of Korea in Public Sector: Past, Present and Future (공공부문에서 한국의 EA 과거, 현재 그리고 미래)

  • Oh, Seung Woon;Shin, Daul;Shin, Dongik
    • Journal of Information Technology and Architecture
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    • v.10 no.4
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    • pp.411-421
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    • 2013
  • The study focuses on EA experiences of Korea in public sector in terms of three distinguishing periods: preparation, adaptation, and utilization. Analyzing those experiences would lead to understanding of EA performance in Korea, and to derivation of future policy directions. EA efforts of Korea shows results in several areas, especially in prevention of duplicative investments, savings in IT expenses, and optimization of information resource management. The study suggests sustainable strategy for futre EA growth.

Efficiency Optimization with a Novel Magnetic-Circuit Model for Inductive Power Transfer in EVs

  • Tang, Yunyu;Zhu, Fan;Ma, Hao
    • Journal of Power Electronics
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    • v.18 no.1
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    • pp.309-322
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    • 2018
  • The technology of inductive power transfer has been proved to be a promising solution in many applications especially in electric vehicle (EV) charging systems, due to its features of safety and convenience. However, loosely coupled transformers lead to the system efficiency not coming up to the expectation at the present time. Therefore, at first, the magnetic core losses are calculated with a novel magnetic-circuit model instead of the commonly used finite-element-method (FEM) simulations. The parameters in the model can be obtained with a one-time FEM simulation, which makes the calculation process expeditious. When compared with traditional methods, the model proposed in the paper is much less time-consuming and relatively accurate. These merits have been verified by experimental results. Furthermore, with the proposed loss calculation model, the system is optimized by parameter sweeping, such as the operating frequency and winding turns. Specifically, rather than a predesigned switching frequency, a more efficiency-optimized frequency for the series-parallel (SP) compensation topology is detected and a detailed investigation has been presented accordingly. The optimized system is capable of an efficiency that is greater than 93% at a coil separation distance of 200mm and coil dimensions of $600mm{\times}400mm$.