• Title/Summary/Keyword: leaching stability

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Posttreatment Effects of Castor Bean Oil and Heating in Treated Jabon Wood on Boron Leaching, Dimensional Stability, and Decay Fungi Inhibition

  • PRIADI, Trisna;LESTARI, Marini Dwi;CAHYONO, Tekat Dwi
    • Journal of the Korean Wood Science and Technology
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    • v.49 no.6
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    • pp.602-615
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    • 2021
  • Red jabon wood is a potential fast-growing species for veneer, furniture, and many other wood products, but its durability is very low. The purpose of this study was to investigate the effects of castor bean oil and heating on boron leaching, dimensional stability, and resistance to decay fungi in treated jabon wood. Red jabon wood was preserved with boron solutions containing 5% boron (boric acid, borax, or borax-boric acid). Following that, castor bean oil impregnation and heating were used as posttreatments. Furthermore, all the wood samples were tested in terms of leaching, dimensional stability, and resistance against Schizophyllum commune and Fomitopsis palustris fungi. This study discovered that boron compounds, castor bean oil, and heating treatments influenced the leaching, dimensional stability, and resistance of red jabon wood to decay fungi. The double impregnation of boric acid or borax and castor bean oil, followed by heating at 160℃, significantly reduced water absorption and leaching while increasing the dimensional stability and resistance of red jabon wood against the two tested decay fungi.

A Study on The Comparison of Leaching Methods and Stability of Cement Mortar Solidified Cadmium sludge (시멘트고화에 의한 카드뮴슬러지의 안정성 및 용출실험방법 비교 검토)

  • 주소영;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.17 no.3
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    • pp.21-30
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    • 2002
  • This study was Performed to evaluate the effective solidification of Cd sludge using cement and power plant fly ash as cement admixture, to identify the leaching characteristics of the heavy metal Cd sludge solidified, and to develope proper KLT(Korean Leaching Test) of hazardous waste. KLT was compared with EPT(Extraction Procedure Toxicity) and TCLP(Toxicity Characteristics Leaching Procedure). Fly ash contents ranged from 0% to 30% of cement weight. The experimental results showed that the optimum amount of fly ash replaced was 10% to 15% and KLT was less appropriate than EPA and TCLP. Also the purpose of the study was to suggest the modification factors on the leaching test currently used, based on the above mentioned aspects. The effects of pH, leaching time, leaching for agitating intensity, and leaching solvent were investigated. As the result of test, the leaching potential was relatively high when the pH and agitation intensity of leaching solution were 5 and 150rpm, respectively. Leaching time of six hours was found to be sufficient and the use of acetic acid as a leaching solvent is more useful in landfill site particularly.

Dimensional Stability, Color Change, and Durability of Boron-MMA Treated Red Jabon (Antochephalus macrophyllus) Wood

  • PRIADI, Trisna;ORFIAN, Gema;CAHYONO, Tekat Dwi;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.315-325
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    • 2020
  • Boron compound had many advantages as wood preservative, but it was prone to leaching. Improving boron preservation was required to extend the service life of fast growing and low durability red jabon (Antochephalus macrophyllus) hardwood. This study aimed to evaluate the dimensional stability, color change and durability of modified red jabon wood by double impregnation with boron and methyl methacrylate (MMA) and heat treatment. Impregnation I used boric acid or borax, and impregnation II used MMA, while heat treatment used temperatures of 90 ℃ or 180 ℃ for 4 hours. The dimensional stability, leachability, water absorption, color change and decay resistance of modified red jabon wood were tested. The results showed that MMA impregnation increased the dimensional stability of red jabon wood, while the leaching and water absorption in the wood significantly reduced. Heating at 180 ℃ caused less water absorption and higher dimensional stability of the wood than that of heating at 90 ℃. Impregnation with boric acid and MMA followed by heating at 90 ℃ resulted in the highest wood ASE, 89.9%. The color change (∆E*) of wood increased significantly after MMA impregnation and heating at 180 ℃. Boric acid impregnation caused more resistant wood than borax impregnation against decay fungi and termites. Impregnation with boric acid and MMA followed with heating at 180 ℃ increased significantly the wood resistance against decay fungi and termites.

Evaluation of Leaching Stability of Preservative Treated Wood in the Seawater for the use of a Fish-breeding Ground (해양어초사용을 위한 방부목재의 해수 용탈성 평가)

  • Lee, Myung Jae;Lee, Dong-Heub;Son, Dong-Won
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.3 s.131
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    • pp.53-63
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    • 2005
  • This study attempted to obtain the basic data of utilizable possibility of preservative treated wood as a material used in a marine ranch. To evaluate the leaching stability of CCA-, CCFZ-, and ACQ-treated woods in seawater, the specimens treated with 2% and 3% (w/v) of CCA, CCFZ, and ACQ were exposed to deionized water, synthetic seawater and natural seawater for 41 days and then each component released was periodically determined. There was little amount of copper and chromium released from CCA-treated wood exposed in both deionized and seawater. Although relatively large amount of arsenic was released from CCA-treated wood, the release rate in seawater was lower than that in deionized water. The release rate of chromium and zinc from CCFZ-treated wood were somewhat greater in deionized water, but lower in seawater than in deionized water. Retention level and salinity of synthetic seawater had little effect on the release rate of components. The ACQ-treated wood had greater copper release than CCA- and CCFZ-treated wood, and the amount of copper released did not affected by leaching media used.

The evaluation of the compatibility of recycling melting slag from incinerator ashes as construction materials (소각재 용융슬래그의 건설재료로서 재활용시 적합성 평가)

  • 한영수;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.30-33
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    • 2001
  • Melting is one of the most effective treatments for stabilizing heavy metals and also creates high value by-products. In this study, authors evaluated the leaching characteristics of heavy metals in melting slag obtained from incinerator ashes. In order to evaluate the environmental compatibility of the recycled melting slag, the samples analysed various leaching tests of heavy metals were raw incinerator ashes, melting slag and the construction materials recycled from melting slag. As the results: (1) The leaching concentrations of tile melting slag were lower than those of the raw incinerator ashes in the experiment performed in accordance with Korea Standard Leaching Test (KSLT). (2) The result of leaching test with the method of RG Min-StB 93. FGSV Forschungsgesellschaft fur Stra $\beta$ en- und Verkehrswesen) met the requirements in German. (3) The compressive strengths of mortar samples used for evaluating the feasibility of recycling the melting slag as construction materials also showed the suitable range for recycling (4) Melting slag was considered the stable materials with respect to the chemical stability against chemical solutions with various pH conditions.

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Evaluation on stability of scour countermeasures using geobag and recycled aggregates (재생골재를 활용한 지오백 세굴보호공법의 안정성 평가)

  • Lee, Ju-Hyung;Park, Jae-Hyun;Chung, Moon-Kyung;Kwak, Ki-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.233-244
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    • 2009
  • A new bridge scour countermeasure using geobags and recycled aggregates which is more stable and economical than existing methods is proposed, and its stability was verified through material tests. PP short staple nonwoven geotextile and PET long staple nonwoven geotextile produced in Korea were selected, and a series of strength tests and a test of hydraulic characteristics were conducted to determine a suitable geotextile for geobags. A series of leaching test was also conducted to assess the potential environmental risk of recycled concrete produced in Korea when it is utilized as a material for protecting bridge piers against scour.

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Leaching of Metal Sulfides and the Stability of Reaction Intermediates (황화광의 침출반응 및 중간생성물의 안정도)

  • Lee, Man Seung;Choi, Seung Hoon
    • Resources Recycling
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    • v.27 no.3
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    • pp.3-7
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    • 2018
  • Development of extractive metallurgical processes for metal sulfides has become of importance owing to the depletion of oxide ores with rich metal contents. Most of the leaching reactions of metal sulfides is electrochemical reaction and can be classified as $H_2S$, S, and ${SO_4}^{2-}$ evolution type. The acidity of leaching solution and the presence and concentration of an oxidizing agent affect the formation of reaction intermediates containing sulfur. Frost diagram of sulfuroxoanion indicates that the oxoanions with higher oxidation number are more thermodynamically stable in the presence of oxidizing agents.

Study of the environmental assessment of heavy metals bearing slag utilization (중금속 함유 폐기물의 재사용을 위한 환경적 평가에 관한 연구)

  • Bae, Hae-Ryong;Gwon, Yeong-Bae;Moszkowicz Pierre
    • 연구논문집
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    • s.28
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    • pp.161-172
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    • 1998
  • In the recycling industry, the recuperation of zinc from Electric Arc Furnace dust by the Waelz process generates important quantities of slag. This slag presents good mechanical properties, and for the most siliceous slag. a high stability which would enable its use by total or partial substitution of certain granulates in civil engineering Our study (within the framwork of a European programme cofunded by the European Commission-DGXII) concerns the physico-chemical and mineralogical characterization and leaching behaviour of several types of Waelz slag. The leaching tests are regulatory tests and specific characterization tests of leaching behaviour. They take into account the influence of several main parameters of the valorization scenarios envisaged for the slag(e.g. pH, Redox potential, chemical nature of the leachant, type of contact-liquid/ solid etc.).

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Order-disorder structural tailoring and its effects on the chemical stability of (Gd, Nd)2(Zr, Ce)2O7 pyrochlore ceramic for nuclear waste forms

  • Wang, Yan;Wang, Jin;Zhang, Xue;Li, Nan;Wang, Junxia;Liang, Xiaofeng
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2427-2434
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    • 2022
  • Series of unequal quantity Nd/Ce co-doped ceramic nuclear waste forms, (Gd, Nd)2(Zr, Ce)2O7, were prepared to tailor its ordered pyrochlore or disordered fluorite structure. The phase transition, microtopography, and elemental composition of the ceramic samples were systematically investigated, especially the effect of order-disorder structure on the chemical stability. It was confirmed that unequal quantity of Nd/Ce could synchronously replace the Gd/Zr-sites of Gd2Zr2O7. And the phase transition of order-disorder structure could be successfully tailored by regulating the average cationic radius ratio of (Gd, Nd)2(Zr, Ce)2O7 series. The elements of Gd, Nd, Zr, and Ce are uniformly distributed in the ordered or disordered structures. The MCC-1 leaching results showed that (Gd, Nd)2(Zr, Ce)2O7 pyrochlore ceramic nuclear waste forms had excellent chemical stability, whose elements' normalized leaching rates were as low as 10-4-10-7 g·m-2·d-1 after 7 days. In particular, the chemical stability of disordered structure was superior to that of ordered structure. It was proposed that the force constant and the closest packing were changed with the structure transformation resulting the chemical stability difference.

Assessment on the Mechanical-Chemical Stabilities of Coal Ash Blocks in Sea Water (석탄회 블록의 해양환경에서 역학적-화학적 안정성 평가)

  • Kim, Pil-Geun;Sung, Kyu-Youl;Park, Maeng-Eon
    • Economic and Environmental Geology
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    • v.41 no.4
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    • pp.383-392
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    • 2008
  • This study aims to evaluate the mechanical-chemical stability of used coal ash blocks, for improving fishing grounds. The surface of weathered ash blocks in seawater showed a decrease in the Ca and an increase in the Mg contents, compared to that of fresh blocks. This result reflects the substitution of Ca by Mg in seawater. The compressive strengths of ash blocks submerged into seawater during 12 months ranged from 235.23 to $447.43\;kgf/cm^2$; this is higher than the standard strength of wave-absorbing blocks($180\;kgf/cm^2)$ that are used for harbor construction. In addition, the compressive strength of ash blocks tends to increase with increasing installation time in seawater. The result of leaching experiments on coal ash blocks by Korean Standard Leaching Test(KSLT) method showed that leached concentrations of most metals except Cr(that leached up to 50 ppb, approaching standard concentration) do not exceed the seawater quality standards. A long-term(112 days) heavy metal leaching test to analyze seawater without mixing-dilution also showed that the concentrations of leached heavy metals, except for Cu, under anaerobic conditions do not exceed the seawater quality standards. Accordingly, the use of coal ash blocks in marine environments appears to be safe from chemical and mechanical factors that decrease the efficiency of concrete. Also, leaching concentration of Cu seems to be stable by decrease of leaching concentration due to dilution of seawater.