• Title/Summary/Keyword: layer potential

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Potential Profiles and Capacitances of an Ideally Polarizable Electrode in a point Charged Electrolyte

  • Sang youl Kim;K. Vedam
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.585-591
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    • 1989
  • The effects of the charged metal on the overall electrostatic potential profiles and the capacitances of the electrical double layer are brought out. A model with a simplified jellium and a point-charged electrolyte is utilized in the present calculations. Electrons are assumed not to penetrate electrode surface due to a strong screening of electrolyte at the interface. Electron density functions and ion density functions are obtained, which are also based upon the Poisson equation and Boltzmann equation on either side of the interface. A complete potential profile starting from bulk electrode and ending at bulk electrolyte is obtained by connecting the two potential profiles (one inside the metal electrode, the other inside the electrolyte) with proper boundary conditions. In spite of the simplicity of the model, the present model reveals the importance of the effect of the charged metal on the electrostatic potential profile and the electrical double layer capacitances. The results are discussed and compared with the predictions by Gouy Chapman theory.

Surface Potential Change Depending on Molecular Orientation of Hexadecanethiol Self-Assembled Monolayers on Au(111)

  • Ito, Eisuke;Arai, Takayuki;Hara, Masahiko;Noh, Jaegeun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1309-1312
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    • 2009
  • Surface potential and growth processes of hexadecanethiol (HDT) self-assembled monolayers (SAMs) on Au(111) surfaces were examined by Kelvin probe method and scanning tunneling microscopy. It was found that surface potential strongly depends on surface structure of HDT SAMs. The surface potential shift for the striped phase of HDT SAMs chemisorbed on Au(111) surface was +0.45 eV, which was nearly the same as that of the flat-lying hexadecane layer physisorbed on Au(111) surface. This result indicates that the interfacial dipole layer induced by adsorption of alkyl chains is a main contributor to the surface potential change. In the densely-packed HDT monolayer, further change of the surface potential was observed, suggesting that the dipole moment of the alkanethiol molecules is an origin of the surface potential change. These results indicate that the work function of a metal electrode can be modified by controlling the molecular orientation of an adsorbed molecule.

Potential use of waste rubber shreds in drainage layer of landfills - An experimental study

  • Praveen, V.;Sunil, B.M.
    • Advances in environmental research
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    • v.5 no.3
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    • pp.201-211
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    • 2016
  • Laboratory tests were conducted to evaluate the performance of waste rubber shreds in leachate collection layer of engineered landfills. The study found that waste rubber shreds layer in combination with a gravel layer can be of potential use in landfill drainage system. To study the performance, conventional gravel along with waste rubber shreds were used in different combinations (with total layer thickness = 500 mm) as leachate collection media. For the laboratory study poly vinyl chloride (PVC) pipes were used. The size range of waste rubber shreds used were 25 mm to 75 mm in length and width = 10 to 20 mm. The gravel size used in the leachate collection media is 10 mm to 20 mm size. Performance study of 7 Test Cols. with different combinations of waste rubber shreds and gravel bed thickness were studied to find out the best combination. The study found that the Test Col.-3 having waste rubber shreds thickness = 200 mm and gravel layer thickness = 300 mm gave the best results in terms of percentage removal in various physicochemical parameters present in the leachate. Further to find the best size rubber shreds three more Test Cols - 8, 9 and 10 were constructed having the rubber shreds and gravel layer ratio same as that of Test Col.-3 but having rubber shreds width = 10 mm, 15 mm and 20 mm respectively. Based on the results obtained using Test Cols. 8, 9 and 10 the study found that smaller size rubber shreds gave bests results in terms of improvement in various leachate parameters.

Stochastic MAC-layer Interference Model for Opportunistic Spectrum Access: A Weighted Graphical Game Approach

  • Zhao, Qian;Shen, Liang;Ding, Cheng
    • Journal of Communications and Networks
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    • v.18 no.3
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    • pp.411-419
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    • 2016
  • This article investigates the problem of distributed channel selection in opportunistic spectrum access networks from a perspective of interference minimization. The traditional physical (PHY)-layer interference model is for information theoretic analysis. When practical multiple access mechanisms are considered, the recently developed binary medium access control (MAC)-layer interference model in the previous work is more useful, in which the experienced interference of a user is defined as the number of competing users. However, the binary model is not accurate in mathematics analysis with poor achievable performance. Therefore, we propose a real-valued one called stochastic MAC-layer interference model, where the utility of a player is defined as a function of the aggregate weight of the stochastic interference of competing neighbors. Then, the distributed channel selection problem in the stochastic MAC-layer interference model is formulated as a weighted stochastic MAC-layer interference minimization game and we proved that the game is an exact potential game which exists one pure strategy Nash equilibrium point at least. By using the proposed stochastic learning-automata based uncoupled algorithm with heterogeneous learning parameter (SLA-H), we can achieve suboptimal convergence averagely and this result can be verified in the simulation. Moreover, the simulated results also prove that the proposed stochastic model can achieve higher throughput performance and faster convergence behavior than the binary one.

The recess gate structure for the improvement of breakdown characteristics of GaAs MESFET (GaAs MESFET의 파괴특성 향상을 위한 recess게이트 구조)

  • 장윤영;송정근
    • Electrical & Electronic Materials
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    • v.7 no.5
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    • pp.376-382
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    • 1994
  • In this study we developed a program(DEVSIM) to simulate the two dimensional distribution of the electrostatic potential and the electric field of the arbitrary structure consisting of GaAs/AlGaAs semiconductor and metal as well as dielectric. By the comparision of the electric field distribution of GaAs MESFETs with the various recess gates we proposed a suitable device structure to improve the breakdown characteristics of MESFET. According to the results of simulation the breakdown characteristics were improved as the thickness of the active epitaxial layer was decreased. And the planar structure, which had the highly doped layer under the drain for the ohmic contact, was the worst because the highly doped layer prevented the space charge layer below the gate from extending to the drain, which produced the narrow spaced distribution of the electrostatic potential contours resulting in the high electric field near the drain end. Instead of the planar structure with the highly doped drain the recess gate structure having the highly doped epitaxial drain layer show the better breakdown characteristics by allowing the extention of the space charge layer to the drain. Especially, the structure in which the part of the drain epitaxial layer near the gate show the more improvement of the breakdown characteristics.

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A Study on Groundwater Contamination Potential of Pyungtaek-Gun Area, Kyunggi-Do Using GIS (GIS를 이용한 경기도 평택군 지역의 지하수 오염 가능성 평가 연구)

  • 조시범;민경덕;우남칠;이사로
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.2
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    • pp.87-94
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    • 1999
  • This study is providing Modified DRASTIC Model to which lineament density and land use are added as additional factors using geographic infomation system(GIS). and then to evaluate groundwater contamination potential of Pyungtek-Gun area in Kyunggi-Do. In this study. the reason for using additional factors is because. in case of lineament density. when we consider that most of aquifer is bedrock aquifer in hydrogeologic environment of the Korea, lineament is very important to flow of groundwater and contamination material. and because land use can reflect indirectly impact of point or non_point source in study area. For statistical analysis. vector coverage per each factor is converted to grid layer and after each correlation coefficient between factors, covariance, variance. eigenvalue and eigenvector by principal component analysis of 3 direction. are calculated. correlation between factors is analyzed. Also after correlation coefficients between general DRASTIC layer and rated lineament density layer and between general DRASTIC layer and rated land use layer are calculated. final modified DRASTIC Model is constructed by using them with each weighting. when modified DRASTIC Model was compared with general DRASTIC Model, comtamination potential in modified DRASTIC Model is fairly detailed and consequently. vulnerable area which has high contamination potential could be presented concretly.

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A Method for Simultaneous Measurement of Air Kerma, Half Value Layer and Tube Potential in Quality Control Procedure of Diagnostic x ray units

  • Katoh, Tsuguhisa;Saitoh, Hidetoshi;Ohtani, Hiroki;Negishi, Tooru;Myojoyama, Atsushi;Ohno, Yuusuke;Sasaki, Takehito
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2002.09a
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    • pp.294-297
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    • 2002
  • For the quality control procedure of diagnostic x ray units, a method for simultaneous measurement of air kerma, half value layer and tube potential was developed utilizing a computed radiography system for intraoral radiography and film badge case. The response of average pixel values under the windows were calibrated by x rays generated at tube potentials from 40 to 140 kV with filtration from 1.5 to 3.7 mmAl. The calibration curves for half value layer and tube potential were derived as functions of attenuation factors by the 1.4 mmAl filter and the 0.2 mmCu filter. The energy dependency of the open window response was corrected by the calibration factor as a function of the attenuation factor by the 1.4 mmAl filter. The uncertainty of the estimated half value layer, tube potential and air kerma were 0.2 mmAl, 3.6 % and 5 %, respectively. It was thus suggested that this system could be applied to quality control program to detect the variation of working condition of x ray units in clinical use.

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The Inflow Path of the East Sea Intermediate Water into the Ulleung Basin in July 2005

  • Shin, Chang-Woong
    • Ocean and Polar Research
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    • v.28 no.2
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    • pp.153-161
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    • 2006
  • To investigate inflow path of the East Sea Intermediate Water (ESIW) into the Ulleung Basin, hydrographic data surveyed in July 2005 were analyzed. The ESIW was characterized by the Salinity Minimum Layer (SML) within a depth range of 100 to 360 meters. Averaged potential temperature and salinity of the SML were $1.835^{\circ}C$ and 34.049 psu, respectively. Mean potential density $({\sigma}_{\theta})$ of the SML was 27.221 with a standard deviation of 0.0393. On isopycnal surfaces of 27.14 and 27.18 $({\sigma}_{\theta})$ which correspond to upper layers of the ESIW, the coastal low salinity water was separated from the offshore low salinity water by the relatively warm and saline water which might be affected by the Tsushima Warm Current Water. Relatively cold and fresh water, however, intruded into the Ulleung Basin from the region of Korean coast on isopycnal surfaces of 27.22 and 27.26 which was lower layer of the ESIW. The salinity distribution in the isopycnal layer of $27.14{\sim}27.26$ with acceleration potential on 27.22 up surface also showed clearly that the low salinity water flowed from the coastal area and intruded into the Ulleung Basin. This implies that the ESIW flows ken the north to the south along the east coasts of Korea and spreads into the Ulleung Basin in summer.

Osteogenic Potential of the Periosteum and Periosteal Augmentation for Bone-tunnel Healing

  • Youn Inchan;Suh J-K Francis;Choi Kuiwon
    • Journal of Biomedical Engineering Research
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    • v.26 no.2
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    • pp.101-110
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    • 2005
  • Periosteum and periosteum-derived progenitor cells have demonstrated the potential for stimulative applications in repairs of various musculoskeletal tissues. It has been found that the periosteum contains mesenchymal progenitor cells capable of differentiating into either osteoblasts or chondrocytes depending on the culture conditions. Anatomically, the periosteum is a heterogeneous multi-layered membrane, consisting of an inner cambium and an outer fibrous layer. The present study was designed to elucidate the cellular phenotypic characteristics of cambium and fibrous layer cells in vitro, and to assess whether structural integrity of the tendon in the bone tunnel can be improved by periosteal augmentation of the tendon­bone interface. It was found the cells from each layer showed distinct phenotypic characteristics in a primary monolayer culture system. Specifically, the cambium cells demonstrated higher osteogenic characteristics (higher alkaline phosphatase and osteocalcin levels), as compared to the fibrous cells. Also in vivo animal model showed that a periosteal augmentation of a tendon graft could enhance the structural integrity of the tendon-bone interface, when the periosteum is placed between the tendon and bone interface with the cambium layer facing toward the bone. These findings suggest that extra care needs to be taken in order to identify and maintain the intrinsic phenotypes of the heterogeneous cell types within the periosteum. This will improve our understanding of periosteum in applications for musculoskeletal tissue repairs and tissue engineering.

Construction and Operational Experiences of Engineered Barrier Test Facility for Near Surface Disposal of LILW (중.저준위 방사성폐기물의 천층처분을 위한 인공방벽 실증시험시설의 건설 및 운전 경험)

  • Jin-Beak Park;Se-Moon Park;Chang-Lak Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.1
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    • pp.23-34
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    • 2004
  • To validate the previous conceptual design of cover system, construction of the engineered barrier test facility is completed and the performance tests of the disposal cover system are conducted. The disposal test facility is composed of the multi-purpose working space, the six test cells and the disposal information space for the PR center. The dedicated detection system measures the water content, the temperature, the matric potential of each cover layer and the accumulated water volume of lateral drainage. Short-term experiments on the disposal cover layer using the artificial rainfall system are implemented. The sand drainage layer shows the satisfactory performance as intended in the design stage. The artificial rainfall does not affect the temperature of cover layers. It is investigated that high water infiltration of the artificial rainfall changes the matric potential in each cover layer. This facility is expected to increase the public information about the national radioactive waste disposal program and the effort for the safety of the planned disposal facility.

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