• Title/Summary/Keyword: lateritic clay

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Removal of hexavalent chromium Cr (VI) by adsorption in blended lateritic soil

  • Sunil, B.M.;Faziludeen, Saifiya
    • Advances in environmental research
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    • v.4 no.3
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    • pp.197-210
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    • 2015
  • Hexavalent chromium [Cr (VI)] adsorption on lateritic soil and lateritic soil blended with black cotton (BC) soil, marine clay and bentonite clay were studied in the laboratory using batch adsorption techniques. In the present investigation the natural laterite soil was blended with 10%, 20% and 30% BC soil, marine clay and bentonite clay separately. The interactions on test soils have been studied with respect to the linear, Freundlich and Langmuir isotherms. The linear isotherm parameter, Freundlich and Langmuir isotherm parameters were determined from the batch adsorption tests. The adsorption of Cr (VI) on natural laterite soil and blended laterite soil was determined using double beam spectrophotometer. The distribution coefficients obtained were 1.251, 1.359 and 2.622 L/kg for lateritic soil blended with 10%, 20% and 30% BC soil; 5.396, 12.973 and 48.641 L/kg for lateritic soil blended with marine clay and 5.093, 8.148 and 12.179 L/kg for lateritic soil blended with bentonite clay respectively. The experimental data fitted well to the Langmuir model as observed from the higher value of correlation coefficient. Soil pH and iron content in soil(s) has greater influence on Cr (VI) adsorption. From the study it is concluded that laterite soil can be blended with clayey soils for removing Cr (VI) by adsorption.

Characterization of Ferrallitique Soils (Ferrallitique토양(土壤)의 특성(特性)에 관(關)한 연구(硏究))

  • Sin, Cheon-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.3
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    • pp.260-264
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    • 1985
  • Ferrallitique soils are real tropical soils, with an oxic B horizon such a horizon is at least 30cm thick, has > 15% clay, diffuse horizon boundaries, no weatherable minerals and a CEC of clay < 16 me per 100g. These soils are in general the real reddish or yellowish very uniform tropical clay soils with an orchric A horizon and a deep B horizon, otherwise almost characterless. The soil profile looks uniform and maybe some metres thick. It is well drained, has a good permeability and a stable structure. As there is little or no weatherable mineral, because these soils are old and exhausted of bares, natural fertility is very low. There has been a complicated process of soil formation. Intensive and continuous weathering over a very long period has resulted in leaching of bases and silica, in relative accumulation of resquioxides and in formation of kaolinitic clay. Until recently, there has been much confusion in classifing and naming tropical soils. Particularily what are now Ferralsols in the FAO scheme, and Oxisols in Soil Taxonomy. Old names of various classification system are: Lateritic soils, Latosols, Ferrallitic soils. For agriculture, these soils are important, but chemically very poor, not only because of a low CEC but also because of deficiency of bases, especially Ca, Mg, and K, strong P fixation and high exchangeable Al percentage.

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USE OF NEAR INFRARED FOR THE QUANTITATIVE ANALYSES OF BAUXITE

  • Walker, Graham S.;Cirulis, Robyn;Fletcher, Benjimin;Chandrashekar, S.
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1171-1171
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    • 2001
  • Quantitative analysis is an important requirement in exploration, mining and processing of minerals. There is an increasing need for the use of quantitative mineralogical data to assist with bore hole logging, deposit delineation, grade control, feed to processing plants and monitoring of solid process residues. Quantitative analysis using X-Ray Powder Diffraction (XRD) requires fine grinding and the addition of a reference material, or the application of Rietveld analysis to XRD patterns to provide accurate analysis of the suite of minerals present. Whilst accurate quantitative data can be obtained in this manner, the method is time consuming and limited to the laboratory. Mid infrared when combined with multivariant analysis has also been used for quantitative analysis. However, factors such as the absorption coefficients and refractive index of the minerals requires special sample preparation and dilution in a dispersive medium, such as KBr to minimize distortion of spectral features. In contrast, the lower intensity of the overtones and combinations of the fundamental vibrations in the near infrared allow direct measurement of virtually any solid without special sample preparation or dilution. Thus Near Infrared Spectroscopy (NIR) has found application for quantitative on-line/in line analysis and control in a range of processing applications which include, moisture control in clay and textile processing, fermentation processes, wheat analysis, gasoline analysis and chemicals and polymers. It is developing rapidly in the mineral exploration industry and has been underpinned by the development of portable NIR spectrometers and spectral libraries of a wide range of minerals. For example, iron ores have been identified and characterized in terms of the individual mineral components using field spectrometers. Data acquisition time of NIR field instruments is of the order of seconds and sample preparation is minimal. Consequently these types of spectrometers have great potential for in-line or on-line application in the minerals industry. To demonstrate the applicability of NIR field spectroscopy for quantitative analysis of minerals, a specific example on the quantification of lateritic bauxites will be presented. It has been shown that the application of Partial Least Squares regression analysis (PLS) to the NIR spectra can be used to quantify chemistry and mineralogy in a range of lateritic bauxites. Important, issues such as sampling, precision, repeatability, and replication which influence the results will be discussed.

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A Study on the Chemical Weathering Characteristics of the Weathered Granite Residual Soils prone to Laterization (적황색토화된 화강암질 풍화잔적토의 화학적 풍화특성에 관한 연구)

  • 정두영;이광준
    • Geotechnical Engineering
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    • v.12 no.4
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    • pp.115-130
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    • 1996
  • The definition of laterite or lateritic soils is discussed on a climatic condition of tropical and semitropical regions, and the weathering index is indicated by the chemical composition. The chemical composition of$(Fe_2O_3+Al_2O_3)$ of the weathered granite residual soils in tropical and the temperate regions which shelus laterization usually ranges from 0.2 to 0.5. This study shows that the chemical ratio of the Chonju Ajung site is about 0.2U, and that of the regions along the shore of the western sea of Hongsong and Taechon is about 0.33. The chemical ratio of the non-laterite is less than 0.2, and the Kyougju Pulguksa site confirmed about 0.17, The X-Ray diffraction test shows that the clay mineral of the laterite soils is made of kaolinite, this X -Ray result indicates the same characteristics compared with the wrathered granite residual soils of other sites.

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The Morphology, Physical and Chemical Characteristics of the Red-Yellow Soils in Korea (우리나라 전토양(田土壤)의 특성(特性) (저구릉(低丘陵), 산록(山麓) 및 대지(臺地)에 분포(分布)된 적황색토(赤黃色土)를 중심(中心)으로))

  • Shin, Yong Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.1
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    • pp.35-52
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    • 1973
  • Red Yellow Soils occur very commonly in Korea and constitute the important upland soils of the country which are either presently being cultivated or are suitable for reclaiming and cultivating. These soils are distributed on rolling, moutain foot slopes, and terraces in the southern and western parts of the central districts of Korea, and are derived from granite, granite gneiss, old alluvium and locally from limestone and shale. This report is a summary of the morphology, physical and chemical characteristics of Red Yellow Soils. The data obtained from detailed soil surveys since 1964 are summarized as follows. 1. Red-Yellows Soils have an A, Bt, C profile. The A horizon is dark colored coarse loamy or fine loamy with the thin layer of organic matter. The B horizon is dominantly strong brown, reddish brown or yellowish red, clayey or fine loamy with clay cutans on the soil peds. The C horizon varies with parent materials, and is coarser texture and has a less developed structure than the Bt horizon. Soil depth, varied with relief and parent materials, is predominantly around 100cm. 2. In the physical characteristics, the clay content of surface soil is 18 to 35 percent, and of subsoil is 30 to 90 percent nearly two times higher than the surface soil. Bulk density is 1.2 to 1.3 in the surface soil and 1.3 to 1.5 in the subsoil. The range of 3-phase is mostly narrow with 45 to 50 percent in solid phase, 30 to 45 percent in liquid one, and 5 to 25 percent in gaseous state in the surface soil; and 50 to 60 solid, 35 to 45 percent liquid and less than 15 percent gaseous in the subsoil. Available soil moisture capacity ranges from 10 to 23 percent in the surface soil, and 5 to 16 percent in the subsoil. 3. Chemically, soil reaction is neutral to alkaline in soils derived from limestone or old fluviomarine deposits, and acid to strong acid in other ones. The organic matter content of surface soil varying considerably with vegetation, erosion and cultivation, ranges from 1.0 to 5.0 percent. The cation exchange capacity is 5 to 40 me/100gr soil and closely related to the content of organic matter, clay and silt. Base saturation is low, on the whole, due to the leaching of extractable cations, but is high in soils derived from limestone with high content of lime and magnesium. 4. Most of these soils mainly contain halloysite (a part of kaolin minerals), vermiculite (weathered mica), and illite, including small amount of chlorite, gibbsite, hematite, quartz and feldspar. 5. Characteristically they are similar to Red Yellow Podzolic Soils and a part of Reddish Brown Lateritic Soils of the United States, and Red Yellow Soils of Japan. According to USDA 7th Approximation, they can be classified as Udu Its or Udalfs, and in FAO classification system to Acrisols, Luvisols, and Nitosols.

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Studies on the Absorption Capacity of Phosphorus of Korean Top-soils (우리나라 표층토(表層土)의 인산흡수력(燐酸吸收力)에 관(關)한 연구(硏究))

  • Park, C.S.;Han, K.H.;Lim, S.K.;Lee, J.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.2 no.1
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    • pp.1-13
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    • 1969
  • A total of 129 surface(upto 30 cm depth) soil samples were selected from the profile samples collected during reconnaissance soil survey in 1967, for the determination of phosphorus absorption co-efficient. The distribution range for each soil association has been established. The physicochemical factors affecting the phosphorus absorption coefficient have also been examined. The following general conclusions can be drown: 1. In general, the phosphorus absorption coefficient of the soil association of presently arable land are lower than the soils which are not in cultivation. 2. The higher the cation exchange capacity of soils, the higher is the phosphorus absorption coefficient. The factors governing phosphorus absorption coefficient in various soil associations are as follows: Parent Material Soil Association Governing Factor Fluvio marine Low Humic Gley Fluvio marine Alluvial Complex Narrow valley Siliceo mafic materials Red-yellow podzolic Redish Siliceo mafic materials Brown Lateritic Clay content Siliceous crystalline materials Lithosols C.E.C. & Clay content Alluvium Low Humic Alluvium Gley Alluvial Organic matter Siliceous crystalline materials Red-Yellow Podzolic Organic matter and clay content 4. The relation between phosphorus absorption coefficient determined by $(NH_4)_2HPO_4(y)$ and by the P 700 ppm $NaH_2PO_4(x)$ is $Y=2.716X+37(r=0.96^{**})$ which shows highly significant positive correlation and linear regression.

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