• Title/Summary/Keyword: large pores

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Critical State of Crushable Jeju Beach Sand (파쇄성이 큰 제주해사의 한계상태 특성)

  • Lee, Moon Joo;Bae, Kyung Doo;An, Sung Mo;Lee, Woo Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.2C
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    • pp.133-140
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    • 2010
  • A series of triaxial test was performed in order to determine critical state parameters of calcareous Jeju sand, which comprises angular shape particles with many pores in the surface. It is observed that Jeju sand mainly shows the contractive behavior during triaxial shear due to high extreme void ratios and large compressibility. The peak friction angle of Jeju sand decreases slightly with increasing mean effective stress due to the particle crushing of carbonate materials. However, the peak friction angle of Jeju sand is higher than that of other silica sands because of the more angular particle shape. The critical state friction angle of Jeju sand gradually decreases when the mean effective stress at a critical state increases. Whereas, there is not a clear influence of void ratio on the critical state friction angle. Critical state parameters of Jeju sand are similar to those of calcareous sands, but significantly larger than those of common sands.

Properties of Iron Powder and Activated Carbon mixed Matrix for the Improvement of Cold Weather Concrete (한중콘크리트 개선을 위한 철가루와 활성탄 혼입 경화체 기초연구)

  • Kim, Won-Jong;Kim, Won-Sik;Kim, Gyu-Yong;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.175-176
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    • 2022
  • By studying the characteristics of matrix insulated through heat generated through oxidation of iron powder, the basic research results on the possibility of buffering and applicability of Cold weather concrete as a curing method are presented. In order to prevent freezing due to a sharp decrease in temperature in the initial stage of curing, iron powder (Fe), powder activated carbon, which is a small amount of porous carbonaceous adsorbent, and salt (NaCl) as an oxidizing agent are replaced with iron powder admixture. As the curing temperature increases, the strength tends to increase, and when replacing the admixture at the same curing temperature, the strength slightly decreases. This is determined as a result of generating iron oxide through an oxidation reaction of iron powder, activated carbon, and NaCl generating a large amount of pores in the matrix. In addition, the internal temperature tends to increase as the mixing substitution rate increases, and it is judged that the oxidation heat of the iron powder mixture affects the increase of the internal temperature during curing. The higher the replacement rate of the iron powder mixture, the slightly lower the strength, but it is determined that freezing and melting that may occur in the early stage of curing can be prevented due to an increase in the initial internal temperature.

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Development of Highly Efficient Oil-Water Separation Materials Utilizing the Self-Bonding and Microstructuring Characteristics of Aluminum Nitride Nanopowders (질화알루미늄 나노분말의 자가 접착과 미세구조화 특성을 활용한 고효율 유수분리 소재 개발)

  • Heon-Ju Choi;Handong Cho
    • Journal of the Korean Society of Industry Convergence
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    • v.27 no.3
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    • pp.601-607
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    • 2024
  • The discharge of oily wastewater into water bodies and soil poses a serious hazard to the environment and public health. Various conventional techniques have been employed to treat oil-water mixtures and emulsions; Unfortunately, these approaches are frequently expensive, time-consuming, and unsatisfactory outcomes. Porous materials and adsorbents are commonly used for purification, but their use is limited by low separation efficiencies and the risk of secondary contamination. Recent advancements in nanotechnology have driven the development of innovative materials and technologies for oil-contaminated wastewater treatment. Nanomaterials can offer enhanced oil-water separation properties due to their high surface area and tunable surface chemistry. The fabrication of nanofiber membranes with precise pore sizes and surface properties can further improve separation efficiency. Notably, novel technologies have emerged utilizing nanomaterials with special surface wetting properties, such as superhydrophobicity, to selectively separate oil from oil-water mixtures or emulsions. These special wetting surfaces are promising for high-efficiency oil separation in emulsions and allow the use of materials with relatively large pores, enhancing throughput and separation efficiency. In this study, we introduce a facile and scalable method for fabrication of superhydrophobic-superoleophilic felt fabrics for oil/water mixture and emulsion separation. AlN nanopowders are hydrolyzed to create the desired microstructures, which firmly adhere to the fabric surface without the need for a binder resin, enabling specialized wetting properties. This approach is applicable regardless of the material's size and shape, enabling efficient separation of oil and water from oil-water mixtures and emulsions. The oil-water separation materials proposed in this study exhibit low cost, high scalability, and efficiency, demonstrating their potential for broad industrial applications.

Structure of the Male Reproductive System in the Freshwater Prawn Macrobrachium nipponense (징거미새우, Macrobrachium nipponense 수컷 생식기의 구조)

  • 김대현;한창희
    • Journal of Life Science
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    • v.8 no.5
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    • pp.582-588
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    • 1998
  • The male reproductive system of Macrobrachium nipponense consists of a pair of lobulate testes enveloped within a mesenteric sheath extending the length of the carapace. The paired vasa deferentia originated from the mid-lateral region of each testis and extended to the genital pores at the base of the fifth walking legs. The vas deferens has four morphologically distinct regions, i.e., a short and slender proximal region, a long convoluted region, an elongate distal region and an ejaculatory duct that terminates at the genital pore. The sperm mass produced in the testes is surrounded by a basophilic matrix adjacent to the high columnar epithelium and an eosinophilic matrix adjacent to the simple columnar epithelium. The sperm cord is stored in the ejaculatory duct until it is ejaculated. Androgenic gland is found near the subterminal region of the ejaculatory duct between the muscles of the coxopodite of the last thoracic leg. The cell of the androgenic gland is about 6~8 $\mu$m in length, characterized by with extended chromatin in the large nucleus that stained weakly with hematoxylin and there is a large quantity of cytoplasm. The sperm of M. nipponense are typical of the palaemonid type, having a convex, cup shaped head and an elongated spike extending from the centre of the convex head. The spermatophore consisted of an eosinophilic matrix, a basophilic matrix and paired sperm masses which was surrounded by the basophilic matrix. It generally shows a bilaterally symmetrical structure.

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Physical Properties of Sintered Body for Coal Fly Ash-clay Slip of Varying Dispersion State (석탄회-점토계 슬립의 분산상태에 따른 소결체의 물리적 특성)

  • 강승구;이기강;김유택;김정환
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.677-682
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    • 2003
  • The physical properties of sintered body made from 3 kinds of slip, F (Flocculated), M (Moderate), and D (Dispersed) for coal fly ash 70-clay 30 (wt%) were studied in terms of slip states and pore size distribution of sintered bodies. The floc particle size distribution for slip F was wider than slip D and the slip F contained flocs larger than 11 $\mu\textrm{m}$. The pore size distribution of the green body of all slips ranged over 1∼4 $\mu\textrm{m}$. The pores smaller than 1 $\mu\textrm{m}$ almost disappeared during the sintering process, while the larger pore of 2.5∼3 $\mu\textrm{m}$ growed by 1 $\mu\textrm{m}$. The pore distribution for the green body of slip F became a narrow in width and high in height after sintering and the large pore limit in a slip F sintered body was 5.1 $\mu\textrm{m}$ which is smaller than that of other slip. The slip F rather flocculated was favorable over slip D well dispersed, in offering a higher compressive strength. From these results, the mechanical strength of sintered body is dependent on the pore distribution which could be controlled by dispersion state of the slips.

Investigation of Degradation Mechanism of High Alumina Refractory in a Coal Gasifier (석탄 가스화기에서의 고알루미나 내화물의 손상 기구 규명)

  • Kim, Yuna;Lee, Jae Goo;Oh, Myongsook S.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.638-645
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    • 2009
  • High alumina refractory used in a coal gasifier was analyzed and the degradation mechanism by molten slag was investigated. The depth of refractory severely damaged by slag varied between 12~40 mm, including the adhered slag layer. The sample also showed the cracks formed in parallel to the slag/refractory interface. The degree of degradation varied with the micro-structures in the refractory. Fused alumina grains showed the uneven boundary and pore formation just along the edges, while the tablet alumina showed the slag penetrated between sintered alumina around which the formation of Al-Fe phase was observed. Calcium aluminate cements were not observed at the high temperature zone near the slag/refractory interface, probably due to dissolution into molten slag. Around large grains of alumina, rod shape alumina, which appeared to be recrystallized during cooling, were observed, and large pores were also formed around those grains. Therefore, in high alumina refractories, hot molten slag dissolves the bonding phase and rod-shape alumina phase is recrystallized upon cooling. During this process, cracks are developed due to structural change, and the degradation occurs by physical causes such as structural spalling.

The Fundamental Properties of Foamed Concrete as the Eco-friendly Ground Repair System for Cast in Site Using the CSA (CSA를 사용한 친환경 지반보수용 현장 기포콘크리트의 기초 특성 검토)

  • Woo, Yang-Yi;Park, Keun-Bae;Ma, Young;Song, Hun-Young
    • Resources Recycling
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    • v.29 no.1
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    • pp.53-61
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    • 2020
  • This study aimed to develop a foam concrete material for a ground repair system that has low strength and low fluidity by using an eco-friendly binder, which substitutes industrial by-products for more than 90% of cement. Basic properties were evaluated after substituting a small amount of calcium sulfo aluminate (CSA) for the binder to improve the sinking depth rate and volume change, commonly found when it had a large amount of industrial by-products. The substitution rates of CSA for the eco-friendly binder used for the foam concrete were 2.5, 5, and 10%. Fresh properties, hardened properties, pore structure, and hydrates were analyzed. Experimental results showed that using only 2.5% of CSA could improve the deep sinking depth which occurred when using an eco-friendly binder. As a result, the weight difference between the upper, middle, and lower parts of cast specimens was improved even after being hardened. The addition of CSA also contributed to the formation of small, uniformly sized closed pores and improved initial strength. However, when the proportion of CSA increased, the long-term strength decreased. However, it satisfied the target strength when 5% or less of CSA was used. The results of this study revealed that it was possible to manufacture foam concrete with low strength and high fluidity for repairing ground satisfying target qualities by adding 2.5% of CSA to the eco-friendly binder containing a large amount of industrial by-products.

Anatomical Studies on Tumorous Tissue Formed in a Stem of Ailanthus altissima Swingle by Artificial Banding and Its Subsequent Removing Treatment -Characters of Individual Elements- (인위적(人爲的)인 밴드결체(結締) 및 해체처리(解締處理)로 형성(形成)된 가죽나무(Ailanthus altissima Swingle) 수간(樹幹)의 종양조직(腫瘍組織)에 관한 해부학적(解剖學的) 연구(硏究) -조직(組織) 구성세포(構成細胞)의 특성(特性)-)

  • Eom, Young Geun;Lee, Phil Woo
    • Journal of Korean Society of Forest Science
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    • v.78 no.3
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    • pp.287-301
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    • 1989
  • A tree of Ailanthus altissima Swingle was fastened with a plastic band, 19mm wide, around the stem 180cm above ground level and was left to grow under this condition for one year, By removal of this band the tumorous tissue gradually developed and the tree bearing distinct tumorous tissue, an overgrowth surrounding the stem, was harvested two years after the band removal. For the investigation of this tumorous part and its comparison with adjacent normal parts in the anatomical features of individual elements, the tumorous part and parts directly and 40cm above and below the tumorous part were obtained from the tree. The tumor wood having remarkably wider growth increment occurred in the 3rd growth ring the first year after removal of the fastened band, and the barrier zone which delimited the discolored wood from the normal-colored wood inwards appeared u1 the intra-2nd growth ring produced during the fastened period in the tumorous part and the false ring-like zones equivalent to barrier Zone were shown in the normal-colored 2nd growth rings of the parts directly and 40cm above and below the tumorous part, as well. The tumor wood, the 3rd growth ring, and proportion of the 2nd growth ring formed after barrier zone in the tumorous part shared common characteristics in the irregular growth ring boundary, misshapen and shorter individual fibers and vessel elements, and large ray widths and heights. The springwood pores were smaller in diameter in the tumor wood, and the larger radial and smaller tangential diameters of summerwood solitary pores and individual pores consisting of pore multiples in proportion of the 2nd growth ring formed after the barrier zone were transformed into near-isodiametric in the tumor wood, the 3rd growth ring, in the tumorous part. Only in proportion of the 2nd growth ring formed after the barrier zone were transformed into near-isodiametric in the tumor wood, the 3rd growth ring, in the tumorous part, ray densities greatly increased. And the massive tumor wood was caused not by cell size but by cell number because the radial and tangential diameters of fibers in the tumor wood, the 3rd growth ring, in the tumorous part were not sufficiently different from those in the same aged growth rings of the directly and 40cm above and below the tumorous part.

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Three Dimensional Measurements of Pore Morphological and Hydraulic Properties (토양 공극 형태와 수문학적 특성에 대한 3 차원적 측정)

  • Chun, Hyen-Chung;Gimenez, Daniel;Yoon, Sung-Won;Heck, Richard;Elliot, Tom;Ziska, Laise;Geaorge, Kate;Sonn, Yeon-Kyu;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.4
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    • pp.415-423
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    • 2010
  • Pore network models are useful tools to investigate soil pore geometry. These models provide quantitative information of pore geometry from 3D images. This study presents a pore network model to quantify pore structure and hydraulic characteristics. The objectives of this work were to apply the pore network model to characterize pore structure from large images to quantify pore structure, calculate water retention and hydraulic conductivity properties from a three dimensional soil image, and to combine measured hydraulic properties from experiments with calculated hydraulic properties from image. Soil samples were taken from a site located at the Baltimore science center, which is located inside of the city. Undisturbed columns were taken from the site and scanned with a computer tomographer at resolutions of 22 ${\mu}m$. Pore networks were extracted by medial-axis transformation and were used to measure pore geometry from one of the scanned samples. Water retention and unsaturated hydraulic conductivity values were calculated from the soil image. Properties of soil bulk density, water retention and unsaturated hydraulic conductivity were measured from three replicates of scanned soil samples. 3D image analysis provided accurate detailed pore properties such as individual pore volumes, pore length, and tortuosity of all pores. These data made possible to calculate accurate estimations of water retention and hydraulic conductivity. Combination of the calculated and measured hydraulic properties gave more accurate information on pore sizes over wider range than measured or calculated data alone. We could conclude that the hydraulic property computed from soil images and laboratory measurements can describe a full structure of intra- and inter-aggregate pores in soil.

Formation of Porous Boehmite for Supporting Enzyme Catalyst (효소촉매 담지체용 다공성 베마이트 제조)

  • Yem, Hye Suk;Kim, Ki Do;Jun, Chang Lim;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.188-193
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    • 2006
  • Synthesis of Boehmite particles were performed through the precipitation of aluminium nitrate ($Al_{3}(NO_{3})_3{\cdot}9H_{2}O$) with ammonia water ($NH_{4}OH$) by changing solution pH, mixing procedure, temperature, and feeding flux. The influence of the synthesis condition, which affected on the pH range of the Boehmite formation, particle morphology and pore property, was investigated. The Boehmite particles were formed in the reaction solution of pH 7.5~9. The particles prepared by P2jet type which maintained the pH uniformly during the precipitation resulted in homogeneous particles and pores because of the constant concentration of the reacted ion in the solution. It was resulted in the improvement of the specific surface area and pore volume of the particle at the same time. With the increasing of temperature and the decreasing of the feeding flux, it was occurred the large specific surface area and pore volume. Also it was presented the fibrillar shaped particles upper $60^{\circ}C$ of the reaction temperature. In this study, the optimal condition of the porous Boehmite was in P2jet type with $90^{\circ}C$ of reaction temperature and 2.5 mL/min of the feeding flux. At this time, the specific surface area, pore volume, and average pore size was $385.46m^2/g$, 1.0252 mL/g, 10 nm, respectively.