• Title/Summary/Keyword: lacquer analysis

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Grade Classification of Urushi Lacquer (II) Grade Classification of Urushi Lacquer by Scientific Methods (옻칠의 품등 구분 (II) 과학적 방법에 의한 옻칠의 품등 구분)

  • Roh, Jeong-Kwan;Kim, Yun-Geun
    • Journal of the Korea Furniture Society
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    • v.19 no.5
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    • pp.307-318
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    • 2008
  • Scientific methods for grading urushi lacquer includes general properties (viscosity, pH etc), and quantitative analysis of moisture, urushiol, gum, laccase content etc, and properties of coating layer such as set to touch drying time, gloss, color difference, delamination strength, tensile strength of film. The grading results evaluated by scientific method showed n order with chinese urushi lacquer (E) > domestic urushi lacquer (A) > japanese urushi lacquer (C) > chinese urushi lacquer (D) > domestic urushi lacquer (B). It is different from hose of traditional methods. Therefore, a more accurate grading of urushi lacquer should be ade by combining traditional method with scientific method.

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Conservation of Lacquer-wares (수침칠기의 보존)

  • Yi, Yong-Hee;Kim, Chang-Suk;Jung, Kwang-Yong;Han, Sung-He
    • 보존과학연구
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    • s.14
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    • pp.77-93
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    • 1993
  • In order to study for the production techniques and the materials of using in Korean Lacquer Antiques, we examined the section structure by SEM and Microscope, the qualitative analysis of lacquer layer by XRF and XRD, the qualitative analysis of Golhae layer by XRF and XRD, the qualitative analysis of Golhae by EDS on the locquer-wares which was excavated from Anapchi Pond Site in Kyungju and Miruksa Temple Site in Iksan. In the lacquer-wares excavated from Anapchi Pond Site, the lacuqer-wares layers made by a cloth attached on the surface of wooden vessel and Golhae-a mixture of clay and lacquer-covered on the cloth and finally finished with the red lacqure, being mixed with pure mercury sulfide(HgS) and lacquer. And raw materials of Golhae made of clay. The lacquer-wares excavated from Miruksa Temple Site in Iksan, we presumed that the lacquer-wares used fine born grains in place of clay for the raw materials of Golhae. Expecially in case of black lacquer-tray, we found that lacquer put on the surface of wooden vessel without cloth attaching and Golhae covering and the production of wooden vessel was used power-driven machine.

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Correlation Analysis on Several Factors and Collection Amount of Rhus Lacquer by the Sex of Rhus verniciflua (옻나무의 암수에 따른 주요인자와 옻채취량의 상관분석)

  • Song Byong-Min;Lee Cheol
    • Korean Journal of Plant Resources
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    • v.18 no.2
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    • pp.279-284
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    • 2005
  • The study was conducted to investigate the correlation and regression analysis between the factors - diameter, hight and crown width - and collection amount of Rhus lacquer by the sex of Rhus verniciflua. The relationship between the diameter and the collection amount of the lacquer by the sex of the lacquer tree indicated that, for both of the male and the female, the lacquer amount was likely to increase as the diameter got larger. In general, the male trees tended towards the higher amount of the lacquer than the female. The relationship between the crown width and the collection amount of the lacquer by the sex showed little difference. As the crown became wider, however, the lacquer amount showed the increasing trend. The regression analysis by the sex of the tree indicated that the major factors of the female had larger influence on the lacquer amount than those of the male. The no differences of statistical significance were found among the diameter, the height, the crown width, and the lacquer amount.

UV-Degradation Chemistry of Oriental Lacquer Coating Containing Hindered Amine Light Stabilizer

  • Hong, Jin Hu;Park, Mi Yeong;Kim, Hyeon Gyeong;Choe, Jeong O
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.61-64
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    • 2000
  • FT-IR/ATR analysis shows that the oriental lacquer coating network degrades mostly in the unsaturated side chain. The rate of increase in carbonyl intensity (a measure of photodegradation) during the accelerated weathering test was substantially different for the unstabilized and stabilized samples; adding 2 wt% HALS into the oriental lacquer formulation enhanced photostabilization up to three times. Weight loss measurements, another indication of photodegradation, and SEM analysis support this conclusion. Despite the presence of the photo-stabilizer, the other properties of the lacquer were not significantly affected. In particular, the curing behavior of purified lacquer (PL) and HALS-stabilized samples is similar, although the in-situ DETA analysis showed that addition of HALS can slightly retard the cure reaction rate in oriental lacquer coating. It is hypothesized that this cure retardation may be related to the salt formation between HALS and acid of oriental lacquer.

Analysis of Flat Board-shaped Lacquer ware Excavated from Daho-ri in Changwon, Korea (다호리 출토 판상 칠기의 재질 분석)

  • Kim, Soochul;Park, Minsoo;Yun, Eunyoung
    • Conservation Science in Museum
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    • v.13
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    • pp.33-36
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    • 2012
  • Analysis of Flat board-shaped Lacquer ware excavated from Daho-ri was conducted. The result of species identification is identifed as Pinus spp. As a result of microscopic observation, lacquer fragment is consist of 5 layers and its thickness is about 100 ㎛. Infrared spectroscopy of the lacquer ware revealed that they had a very similar absorption band as refined lacquer, confirming that they were painted with lacquer. Result of Analysis for Circular metal ornament is alloy smelted by tin and lead. It is called Pewter. While The species of wooden objects investigated until now is broad-leaved tree; the species of flat board-shaped lacquer ware is conifer.

Observation by the Microscopic Analysis of Lacquer Layer for Identification of Lacquer-ware Function (칠 기법 규명을 위한 칠도막의 현미경 관찰)

  • Kim, Soo-Chul;Lee, Kwang-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.96-104
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    • 2008
  • In this study, the observation of test pieces with an optical microscope was carried out after fabricating 4 groups of standard lacquer, in order to inquire into the ancient lacquering techniques. Group I had transparent reddish brown color, and the part of layer was indefinite, and the layer polished was easily distinguished. Group II had mostly transparent yellowish brown color, and it was possibility distinguished the layers when they were varnished with mixed lacquer after prime coating, and when they were varnished with lacquer as the prime coating. Group III set up membrane in the hardening process of the lacquer, and the lacquer and the unsaturated fatty acid of internal part was dried, so the top layer and the lacquer layer were separated and observed. Group IV: When the lacquer coat film of Group IV test pieces were observed in polarized light, the ferrous components were seen as the black and red color were mixed, and the silica crystals of silty soil were distinguished by reflection of lights. And the colors were distinguished as the lacquer layer of ruddle had red color, and the mixed lacquer of reddish lacquer and ruddle had the deep red color at the top and the bottom, but the middle part had the bright red color.

Change of Lacquer Surface by Radiation (방사선에 의한 옻칠표면의 변화)

  • Yoon, Guk-joung
    • Journal of Radiation Industry
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    • v.12 no.4
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    • pp.333-336
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    • 2018
  • Natural lacquer was cured at room temperature at a relative humidity of 60% at $27^{\circ}C$ to obtain a lacquer film. Photolysis of lacquer was investigated by irradiating 1~75 kGy of gamma ray to this lacquer film. No significant changes were observed in the range of 1~10 kGy radiation. As the radiation doses were increased, the white spots were increased in the scanning electron microscope photographs. The increase of the white dots of the lacquer surface shows that the lacquer is degradation by radiation. As a result of IR spectral analysis of the lacquer surface with increasing irradiation dose, there was no significant change in $3,445cm^{-1}$ hydroxide group, $2,900cm^{-1}$ hydrocarbon group, and $993cm^{-1}$ triene group. However, the $1,745cm^{-1}$ carbonyl group was found to increase, and the $1,715cm^{-1}$ unsaturated hydrocarbon group and the $1,463cm^{-1}$ methylene group showed a tendency to decrease.

Lacquer Techniques in the Late Joseon Dynasty

  • Junghae PARK;Jaewan CHOI;Uicheon LEE;Minji KANG;Soochul KIM
    • Journal of the Korean Wood Science and Technology
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    • v.51 no.2
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    • pp.69-80
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    • 2023
  • This study conducted scientific analyses on eight objects of wooden lacquerware to understand the manufacturing techniques of wooden lacquerware in the late Joseon Dynasty. The results of lacquer layer analysis with a microscope and scanning electron microscopy-energy dispersive X-ray spectrometry revealed that most samples were composed of 1-3 lacquer layers. Moreover, a red-colored layer was found to be red ocher and cinnabar, and Fourier-transform infrared spectroscopy analysis was carried out to determine the components of the lacquer layer. The detected components were mostly lacquer and partially cashew shell nut liquid.

Analysis of Lacquer and CNSL Using Infrared Spectrometer and Pyrolysis-GC/MS (적외선분광분석과 Py-GC/MS를 이용한 옻칠 및 캐슈칠도막 분석)

  • Choi, Jaewan;Kim, Soo-Chul
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.1
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    • pp.1-9
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    • 2018
  • Nowadays, synthetic resin varnish such as cashew nut shell liquid (CNSL) is being used as well as traditional lacquer. The code of ethics states that material must be identical to the original when preserving cultural heritage. Therefore, lacquer should be used. However, problem is that even experts have difficulties differentiating lacquer and CNSL as they have similar components. Therefore, this study was carried out to identify the difference between lacquer and CNSL using IR and Py-GC/MS. As a result of IR, in lacquer, $720cm^{-1}$ peak was detected and in CNSL, $750cm^{-1}$, $720cm^{-1}$ and $700cm^{-1}$ peaks were detected. The results of Py-GC/MS detect benzene compounds and alkyl chains for both varnishes. However, hexanoic acid was detected from CNSL but not lacquer. Using these analytical methods, the differences between lacquer and CNSL can be identified on the scene. This is expected to be applied to the authentic conservation and restoration of lacquerware.

A Study on the Physical Properties and Coating of Metal Surface Using Traditional Lacquer Technique (전통 옻칠 기법을 이용한 금속표면 코팅 및 물성 연구)

  • Cho, Sung Mo;Oh, Han Seo;Cho, Nam Chul
    • Journal of Conservation Science
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    • v.37 no.3
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    • pp.302-311
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    • 2021
  • This study uses traditional lacquer techniques to coat the metal surface and evaluates its physical properties to check the applicability of the lacquer coating. For this purpose, a total of six specimens were produced by setting the variation conditions for the number of times (1, 2, 3) and the heating temperature (120℃, 150℃) using SS275 metal(60*60 mm) and 'Wonju lacquer'. For analysis, chromaticity measurements, contact angle/surface energy measurements, Chemical Resistance, and cross-cut tests were used. The analysis showed that the corrosivity was improved and the adhesion of lacquer to the metal surface was excellent. There was no significant change in contact angle/surface energy. Also, there was no significant difference in color. Through this study, it was confirmed that lacquer on metal surfaces improves waterproofing and has a anticorrosion effect. We could also check the proper number of lacquer and heating temperature. Additional physical characteristics such as hardness and wear rate should be studied. It is also necessary to study how lacquer can be painted with a certain thickness.