• 상하수도학회지
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• 제29권6호
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• pp.609-615
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• 2015

This study was carried out for characterization of MIO synthesized in our laboratory by co-precipitation method and applied isotherm and kinetic models for adsorption properties. XRD analysis were conducted to find crystal structure of synthesized MIO. Further SEM and XPS analysis was performed before and after phosphate adsorption, and BET analysis for surface characterization. Phosphate stock solution was prepared by KH2PO4 for characterization of phosphate adsorption, and batch experiment was conducted using 50 ml conical tube. Langmuir and Freundlich models were applied based on adsorption equilibrium test of MIO by initial phosphate solution. Pseudo first order and pseudo second order models were applied for interpretation of kinetic model by temperature. Surface area and pore size of MIO were found $89.6m^2/g$ and 16 nm respectively. And, the determination coefficient ($R^2$) value of Langmuir model was 0.9779, which was comparatively higher than that of Freundlich isotherm model 0.9340.

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1603-1604
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• 2014

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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• pp.17-23
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• 2000

Knock in SI engines causes physical damage to the piston and combustion chamber and lowers the thermal efficiency. The increase in compression ratio which can improve the thermal efficiency and engine performance has been limited by engine knock. So the need of making clear the knocking phenomenon has increased. This paper reviews the methods of knock detection, characterization and prediction of knock with the reduced chemical kinetic modeling.

• 한국연소학회지
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• 제5권2호
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• pp.29-35
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• 2000

Knock in SI engines causes physical damage to the piston and combustion chamber and lowers the thermal efficiency. The increase in compression ratio which can improve the thermal efficiency and engine performance has been limited by engine knock. So the need of making clear the knocking phenomenon has increased. This paper reviews the methods of knock detection, characterization and prediction of knock with the reduced chemical kinetic modeling.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2000년도 추계학술대회
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• pp.275-276
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• 2000

• 대한화학회지
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• 제65권2호
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• pp.83-87
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• 2021

• BMB Reports
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• 제39권4호
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• pp.426-431
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• 2006

Embryonic stem cells (ESCs), representing a population of undifferentiated pluripotent cells with both self-renewal and multilineage differentiation characteristics, are capable of spontaneous differentiation into cardiomyocytes. The present study sought to define the kinetic characterization of lactate dehydrogenase (LDH) and creatine kinase (CK) of ESC- and neonatal-derived cardiomyocytes. Spontaneously differentiated cardiomyocytes from embryoid bodies (EBs) derived from mouse ESC line (Royan B1) and neonatal cardiomyocytes were dispersed in a buffer solution. Enzymes were extracted by sonication and centrifugation for kinetic evaluation of LDH and CK with spectrophotometric methods. While a comparison between the kinetic properties of the LDH and CK of both groups revealed not only different Michaelis constants and optimum temperatures for LDH but also different Michaelis constants and optimum pH for CK, the pH profile of LDH and optimum temperature of CK were similar. In defining some kinetic properties of cardiac metabolic enzymes of ESC-derived cardiomyocytes, our results are expected to further facilitate the use of ESCs as an experimental model.

• 대한화학회지
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• 제61권3호
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• pp.89-96
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• 2017

This study proposed adsorption of Pb(II) ions from aqueous solution using activated carbon prepared from areca catechu shell (ACS AC) using Timphan Method. The effects of independent variables on adsorption kinetic and isotherm have been investigated by conducting experiments in batch mode at neutral pH. The structural characterization of adsorbent was done by FT-IR and SEM analysis. The Pb(II) adsorption was correlated very well with the pseudo second-order kinetic (PSOKM) and Langmuir isotherm models (LIM). Increasing NaOH mass for activation and adsorption temperature increased weakly all the parameters of adsorption kinetic and isotherm. The Pb(II) ions adsorption capacity of the ACS AC at 27 and $45^{\circ}C$ was 50.51 and 55.25 mg/g, respectively. Thermodynamic parameters were determined, and the results confirmed the Pb(II) ions adsorption should be endothermic and spontaneous process, and both physical and chemical adsorption should be taken place.

• 대한토목학회논문집
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• 제40권1호
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• pp.111-118
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• 2020

한국은 강우로 인해 발생되는 토양침식량을 정량적으로 예측하기 위해서 미국에서 유도된 강우운동에너지식을 지난 40년 동안 사용해왔다. 강우의 특성은 기후, 지역 및 시간에 의존하기 때문에 연구 지역에서 측정된 호우사상으로부터, 토양 침식을 일으키는 강우운동에너지의 특성을 분석해서 연구에 활용하는 것이 필요하다. 본 연구의 목적은 서울 지역의 강우운동에너지의 특성을 분석하기 위한 것으로서 서울에서 3년 동안 측정 한 파시벨 강우자료를 사용하였다. 본 연구는 파시벨로 측정한 자료 중 강우강도에 따른 강우운동에너지의 관계를 규명하는데 중점을 두었으며, 새로운 강우운동에너지식을 제안하였다. 또한, 기존에 국내 및 국외에서 개발된 강우운동에너지식과 본 연구에서 도출한 서울 지점에서의 강우운동에너지의 특성을 비교 분석하였다.

• Environmental Engineering Research
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• 제25권2호
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• pp.186-196
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• 2020

Pillared clays with Zr and Fe/Cu/Zr polycations have been prepared from natural clays found in large deposits of Kazakhstan and assessed as catalysts for the catalytic wet peroxide oxidation (CWPO), using 4-nitrophenol (4-NP) as model compound. The performance of the catalysts was followed by measuring the concentration of 4-NP, H₂O₂ and the total organic carbon (TOC), considering C_4-NP = 5 g L^-1, $C_{H_2O_2}$ = 17.8 g L^-1, C_cat = 2.5 g L^-1, initial pH = 3.0 and T = 50℃. At those selected conditions, the pillared clays showed higher activity than natural clays in the CWPO of 4-NP. The conversion of the model pollutant was complete when Fe/Cu/Zr-PILCs were used, with the TOC removal reaching 78.4% after 24 h with the best Fe/Cu/Zr-PILC. The H₂O₂, 4-NP and TOC time-evolution was well described by a kinetic model based on TOC lumps in three blocks, considering the initial TOC (corresponding to 4-NP), the production of oxidizable intermediates and the formation of refractory products.