• Journal of the Korean Applied Science and Technology
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• v.21 no.1
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• pp.51-61
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• 2004

Reaction intermediates PCP/BZA (PBI) and tetramethylene bis(orthophosphate) (TBOP) wer synthesized from polycaprolactone (PCP) and benzoic acid (BZA) and from pyrophosphoric acid and 1,4-butanediol, respectively. Benzoic acid modified polyesters containing phosphorus (APTB-5, -10, -15) were synthesized by polycondensation of the prepared PBI (containing 5, 10, 15wt% of benzoic acid), TBOP, adipic acid, and 1,4-butanediol. The structure and characteristics of APTBs were examined using FT-IR, NMR, GPC, and TGA analysis. The increase of the amount of BZA in the synthesis of APTBs resulted in decrease in average molecular weight and kinematic viscosity. From the TGA analysis of APTBs, it was found that the afterglow decreased with the amount of BZA content at the high temperatures.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.6
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• pp.825-832
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• 2010

The objective of this study is to investigate flow behaviors of polluted air in order to prevent the impact of disaster in a tunnel. This paper presents the experimental results qualitatively in terms of flow characteristics in two kinds of rectangular tunnel models in which each distance from the centerline above the inlet vent to the exhaust vent is 0 and 60 mm, respectively. The olive oil is used as the tracer particles. The flow is tested at the flow rate of $14.16{\times}10^{-4}\;m^3/s$ and the inlet vent velocity of 1.1 m/s with the kinematic viscosity of air. The aspect ratio of the model test section is 10. The average velocity vectors, streamlines, and vorticity distributions are measured and analyzed by the Flow Manager in a particle image velocimetry(PIV) system. The PIV technology gives three different velocity distributions according to observational points of view for understanding the polluted air flow characteristics. The maximum value of mean velocity generally occurs in the inlet and outlet vent regions in the tunnel models.

• Proceedings of the KSME Conference
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• 2003.11a
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• pp.634-639
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• 2003

It has been studied the flow near a rotating disk with surface topography. The system Ekman number is assumed very small, i.e., $E[{\equiv}\frac{\nu}{{\Omega}^{\ast}L^{\ast2}}]<<1$ in which $L^{\ast}$ denotes a disk radius, ${\nu}$ kinematic viscosity of the fluid and ${\Omega}^{\ast}$ angular velocity of the basic state. Disk surface has a sinusoidal topographic variation along radial coordinate, i.e., $z={\delta}cos(2{\pi}{\omega}r)$, where ${\delta}$ and ${\omega}$ are, respectively, nondimensional amplitude and wave number of the disk surface. Analytic solutions, being useful over the parametric ranges of ${\delta}{\sim}O$( $E^{1/2}$ ) and ${\omega}{\leq}O$ ( $E^{1/2}$ ), are secured in a series-function form of Fourier-Bessel type. An asymptotic behavior, when $E{\rightarrow}0$, is clarified as : for a disk with surface roughness, in contrast to the case of a flat disk, the azimuthal velocity increases in magnitude, together with the thickening boundary layer. The radial velocity, however, decreases in magnitude as the amplitude of surface waviness increases. Consequently, the overall Ekman pumping at the edge of the boundary layer remains unchanged, maintaining the constant value equal to that of the flat disk.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.115-115
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• 2011

Biodiesel (BD) was made from animal-fats reacting with methanol and potassium hydroxide in the laboratory. The biodiesel made in the laboratory was sent to K-petro, the government agency, to inspect the quality of animal-fats biodiesel, of which generally the quality was acceptable for heating oil for agricultural hot air heater. Kinematic viscosity and calorific values of the biodiesels were measured. BD20(K), kerosene based biodiesel, showed 18cSt at $-20^{\circ}C$. It seems that BD100 can not be suitable for heating fuel under some temperature. As BD content increased calorific value decreased, up to 40,000J/g for 100% BD, while light oil calorific value was 45,567J/g, showing difference of 5,567J/g, about 12% difference. Several different fuels, BD20, BD50, BD100 and light oil, were prepared and tested for fuel combustion qualities for agricultural hot air heater and their combustion performances were compared and analyzed. Flame dimensions of biodiesels and light oil were almost same shape at the same combustion condition in the burner of the hot air heater. Generally $CO_2$ amounts of BDs are greater than light oil. But,the differences are so small that it is hard to tell there was significant difference existed between the BDs combustion and light oil.

• Applied Chemistry for Engineering
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• v.25 no.6
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• pp.639-644
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• 2014

Domestic vehicle companies have been selling genuine engine oils with higher price than that of the same grade of regular engine oils. In this study, our group investigated the properties of engine oils for 14 kinds of the genuine and equivalent regular engine oil (KS product) species under a fresh as well as used condition recovered after 10,000 km driving. From analytic results, genuine engine oils had similar physical properties to regular engine oils under the fresh condition. But recovered regular engine oils had better properties in lubricity, kinematic viscosity and acid number change than those of recovered genuine engine oils.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2934-2939
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• 2008

We conducted a test of a direct burning of crude Jatropha oil (CJO) in a commercial boiler system. The fuel, crude Jatropha oil is not biodiesel which comes from transeterification process of bio oil, but it is pure plant oil. The higher heating value (HHV) of the CJO is 39.3 MJ/kg (9,380 kcal/kg) and is higher than that of a commercial heating oil, 37.9 MJ/kg. The kinematic viscosity of CJO is 36.2 mm2/s at $40^{\circ}C$ and 8.0 mm2/s at $100^{\circ}C$. The burner used in the test is a commercial burner for a commercial heatingoil and its capacity is 140 kW (120,000 kcal/h). We did a preliminary test whether the combustion is stable or not. The preliminary test was a kind of open air combustion test using the commercial burner with crude Jatropha oil. We found that the combustion can be stable if the crude Jatrophaoil temperature is higher than $90^{\circ}C$. We measured the flue gas concentration by using a gas analyzer. The NOx concentration is $80{\sim}100\;ppm$ and CO concentration is nearly 0 ppm at flue gas O2 concentration of 3.0 and 4.5%.

• Journal of the Korean Chemical Society
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• v.57 no.3
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• pp.377-381
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• 2013

Thevetia peruviana (Yellow Oleander) seed oil was extracted with n-hexane in a soxhlet extractor. The ethanolysis and methanolysis of the oil were carried out with 50% of potassium hydroxide in ethanol and methanol respectively by weight of oil, as catalyst. The biodiesel was tested for biodegradability using E. coli. The percentage yield of the FAEE and FAME were 84.8% and 91.6% respectively. The biodegradability values of 81.4% and 86.2% were obtained for FAEE and FAME respectively after a period of 28 days. Other fuel quality parameters determined are the cetane index of 47.19 (FAEE) and 58.97 (FAME), flash point of $198^{\circ}C$ (FAEE) and $175^{\circ}C$ (FAME), kinematic viscosity at $40^{\circ}C$ of 5.21 $mm^2s^{-1}$ (FAEE) and 5.10 $mm^2s^{-1}$(FAME), pour point of $4^{\circ}C$ (FAEE) and $-2^{\circ}C$ (FAME) and a cloud point of $6^{\circ}C$ (FAEE) and $3^{\circ}C$ (FAME). Thus, Thevetia peruviana oil has a high potential for use in production of environmentally friendly biodiesel.

• Tribology and Lubricants
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• v.16 no.5
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• pp.332-340
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• 2000

The reduction of sulfur content in the diesel fuel has caused the poor lubricity of diesel fuel in the distributor type injection pumps of diesel engines that use the diesel for lubrication of their moving parts. To investigate the reason for poor lubricity of low sulfur diesel fuels, the wear scar diameters by HFRR (High Frequency Reciprocating Rig) were measured on the diesel fuels from Korean markets and the results were compared with their physical and chemical properties. Also, the lubricity change and the improvement effects on lubricity additives for the ultra low sulfur diesel fuel, were made experimentally, that will be regulated to a maximum of 0.005 wt% from about 2005 were evaluated. As a result, a good correlation was found between the wear scar diameter and the polyaromatic compound which includes heterocyclic compound in the diesel fuel. It was also found that the content of polyaromatic compound including heterocyclic compound was affected by the amount of desulfurization treatment fraction. And the lubricity additives with ester base were more effective than that with acid base on the ultra low sulfur diesel fuel. Therefore, it is suggested that the factors affecting the lubricity stated above should be taken into account to improve the lubricity property of the diesel fuel in the refining process.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.162-167
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• 2006

Nanofluid is a kind of new engineering material consisting of nanoparticles dispersed in base fluid. Nanofluids could have various applications such as magnetic fluids, heat exchanger working fluids, lubricants, drug delivery and so on in present study, various nanoparticles, such as MWCNT (Multi-walled Carbon Nanotube), fullerene, copper oxide, and silicon dioxide are used to produce nanofluids. As base fluids, DI-water, ethylene glycol, oil, and silicon oil are used. To investigate the thermo-physical properties of nanofluids, thermal conductivity and kinematic viscosity are measured. Stability estimation of nanofluid is conducted with UV-vis spectrophoto-meter. In this study, the high pressure homogenizer is the most effective method to produce nanofluid with the prepared nanoparticle and base fluid. Excellently stable nanofluids are produced with the magnetron sputtering system. Thermal conductivity of nanofluid increases with increasing particle volume fraction except water-based fullerene nanofluid which has lower thermal conductivity than base fluid due to its lower thermal conductivity, 0.4 W/mK. The experimental results can't be predicted by Jang and Choi model.

• Journal of ILASS-Korea
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• v.28 no.3
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• pp.143-149
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• 2023

Amidst the drive towards carbon neutrality, interest in renewable synthetic e-fuels is rising rapidly. These fuels, generated through the synthesis of atmospheric carbon and green hydrogen, offer a sustainable solution, showing advantages like high energy density and compatibility with existing infrastructure. The physical properties of e-fuels can be different from those of conventional gasoline based on manufacturing methods, which requires investigations into how the physical properties of e-fuels affect the fuel injection characteristics. This study performs a comparative analysis between conventional and Fischer-Tropsch (F-T) synthetic gasoline (e-gasoline) across various fuel temperatures, including the cold start condition. The fuel properties of F-T synthetic and conventional gasoline are analyzed using a gas chromatography-mass spectrometry technique and the injection rates are measured using a Bosch-tube injection rate meter. The F-T synthetic gasoline exhibited higher density and kinematic viscosity, but lower vapor pressure compared to the conventional gasoline. Both fuels showed an increase in injection rate as the fuel temperature decreased. The F-T synthetic gasoline showed higher injection rates compared to conventional gasoline regardless of the fuel temperature.