• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.533-537
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• 2004

The erodibility of soil is an important factor to scour, especially in fine-grained soils. In this study, the erosion characteristics of kaolinite are quantified through the scour rate tests using the Erosion Function Apparatus called EFA. The basic soil property tests are also performed. The kaolinite samples are prepared by mixing with distilled water and formed to the designed maximum consolidation pressure of 60, 110, 160, 240, 360kPa, respectively. The results of the scour rate tests are presented in a format of a plot showing the relationship between erosion rates and shear stresses. Erosion properties of kaolinite showed a striking contrast according to the maximum consolidation pressure, and a correlation was established between the erosion properties of kaolinite and the soil properties; water content, undrained shear strength, dry density.

• Journal of the Mineralogical Society of Korea
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• v.11 no.2
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• pp.106-116
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• 1998

The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

• Journal of Sensor Science and Technology
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• v.32 no.3
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• pp.154-158
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• 2023

This study aimed to improve the moisture resistance of salt cores by investigating the suitability of a two-dimensional kaolinite colloidal solution and a commercially available SiO₂ ink solution as coating agents. X-ray diffraction analysis (XRD) results showed that the intercalation of urea into kaolinite did not significantly change its layer structure. Scanning electron microscopy (SEM) images revealed that the dip-coating only affected the surface of the salt core, and the texture of the surface is differ depending on the coating solution. The humidity absorption test results showed that both coatings reduced the hygroscopicity of the salt core by more than 50%. However, in the water-solubility test, the kaolinite dissolved with the salt core, whereas the SiO₂-coated salt core left a residue. These results strongly suggest that with the coating of the exfoliated kaolinite solution, salt core will remain stable in humid environments.

• Economic and Environmental Geology
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• v.41 no.2
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• pp.165-172
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• 2008

Kaolinite [$Al_2Si_2O_5(OH)_4$] used in these experiments was synthesized at 250$^{\circ}C$ for 36 hrs by a hydrothermal process from amorphous $Al(OH)_3$ and $SiO_2$. The change of the mineralogical properties of the phase synthesized were observed in the pH range 2 to 9. The synthetic kaolinite were characterized by the analytical methods of XRD, IR, DIA, and FE-SEM. Kaolinite was obtained in a wide range of pH. The phases with high- to midium- defect kaolinite with high thermal stability were obtained from the acidic conditions and high-defect kaolinite with low thermal stability from the basic conditions. These variations of kaolinite properties appears to be related to the pH dependence of kaolinite surface speciation. The peaks intensity and resolution of the kaolinite decrease according to the alkalinity of the solution by the results of the IR testing. And the peak intensity increases in the 60 to 70$^{\circ}C$ range due to dehydration reaction observed by TG-DTA. Such phenomena was the result of increase of unreacted amorphous materials in the high pH condition, which could be identified by FE-SEM.

• Journal of the Korean Ceramic Society
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• v.34 no.2
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• pp.195-201
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• 1997

The present paper describes the effect of dry mixed grinding on kaolinite-aluminum trihydroxide mixture with a planetary ball mill before sintering and its influence on mullite formation during sintering. The size reduction of the mixture is market in the early stage of grinding and the obtained fine particles agglomerate subsequently with an increase of grinding time. The crystal structure of the mixture is collapsed easily into an amorphous one by planetary ball milling, of which amount increases with an increase of grinding time. Only mullite phase except for anatase as an inherent impurity in kaolinite appeared in the sintered body of the mixtures with mixed grinding as relatively lower temperature 1523K, while corundum, cristobalite, and Al-Si spinel phases, besides mullite were formed in the sintered body of the mixture without mixed grinding. Therefore, the mixed grinding treatment is very effective to improve the homogeneous mixing and disp-ersion of the mixture of raw materials on a micro scale and to decrease the thermal decomposition tem-perature by crystal structure change of them so as to obatin direct preparation of mullite with high purity at relatively low temperature.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.2
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• pp.107-113
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• 2010

In this study, the adsorption reactions in the binary component system such as kaolinite-humic acid, kaolinite-americium and humic acid-americium were investigated. After performing the basic physico-chemical properties of the kaolinite, the adsorption reactions of the humic acid on the kaolinite were carried out with varying concentration of humic acid and ion strength, and pH. With increasing HA concentration and pH, the sorption of HA onto KA decreased, while the sorption of HA onto KA increased with increasing ionic stre ngth. Also, with varying pH, the adsorption reactions of the americium-kaolinite and americium-humic acid were studied. In the acid and neutral region, Am easily adsorbed on the HA, while the sorption of Am on the HA in the alkali region decreased because of electrostatic repulsion. The results from these studies make it possible to understand the characteristics of adsorption behaviour of the americium by the humic acid in the water environment.

• Journal of the Korean Geotechnical Society
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• v.37 no.7
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• pp.35-42
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• 2021

An experimental study was carried out on kaolinite-sand mixtures with various proportions of kaolinite content. To investigate physical behaviour of mixtures, index properties and compaction test results were analysed in various aspects. Moreover, to clearly see the interaction between kaolinite and sand particles, the observational analysis through microscopic image analysis device was conducted. The test results showed that an increase in the amount of kaolinite could create a strong bonding structure which resulted in higher specific surface available for activities of kaolinite particles. Also, an increase in the amount of the kaolinite resulted in an increase in the percentage of water sorption. Then it could accelerate the occupation rate of water which tended to take up the space that would have been occupied by solid particles, and accordingly, resulted in the decreased maximum dry unit weight and increased initial void ratio. Based on the microscopic image analysis, the samples were individually classified into three types of mixture such as sand dominant, intermediate fine content, and fine dominant. In addition, the fine and coarse grains seem to interact well in the mixtures with the fine content ranging from 25 to 40%.

• Environmental Engineering Research
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• v.8 no.2
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• pp.91-97
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• 2003

• Economic and Environmental Geology
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• v.15 no.2
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• pp.89-102
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• 1982

Several mines in Jeonnam produce the ores of having high SK number of refractoriness. Among those for 5 mines, this paper deals with the relationahip between SK number and mineral composition of the ore, and with the genesis of the deposits. 1. Byok-Song and Chon-Un Mine: Mineral compositions of the ores are chiastolite, chloritoid(monoclinic), kaolinite, sericite, diaspore, corundum, and quartz. The ores having SK number of 36 or 37, consist chiefly of chiastolite and diaspore and a little amount of kaolinite, sericite, corundum, chloritoid, and quartz. The ores having SK number of 33 or 34 consist of chloritoid, sericite, kaolinite, chiastolite, and diaspore. With increasing the amount of chloritoid and sericite, and decreasing the amount of diaspore and chiastolite, the SK number of the ores decreases. The deposit, originally high alumina-bearing shale of Chon-Un San formation, seems to be formed by contact metamorphism(forming of chiastolite), regional metamorphism(forming of monoclinic chloritoid), and hydrothermal replacement(forming of large crystal of diaspore veinlets). 2. Song-Sauk Mine: Mineral compositions of the ores are chiefly pyrophyllite and quartz and a little amount of kaolinite, dickite, diaspore, and pyrite. Many spherical inclusions containing in pyrophyllite deposits, consist chiefly of diaspore and kaolinite, The inclusions have the high SK number of 38. Amount of spherical inclusions is about 5 % to the whole pyrophyllite ores. The SK number of other pyrophyllite ore is less than 32. Quartz and pyrite are chief minerals lowering the SK number of the ore. The deposits have been formed by hydrothermal processes by replacing the siliceous tuff of Mesozoic age. Spherical inclusions consisting of diaspore and kaolinite, show the selective replacement of hydrothermal solutions to the materials of feldspar in tuff. 3. Seung-San Mine: Mineral compositions of the ores are chiefly kaolinite, dickite, diaspore, and quartz. But some part of the mine consists of alunite deposits. The ores having SK number of 35 or higher consist chiefly of kaolinite and diaspore and a little amount of quartz. With increasing the amount of quartz and decresing the amount of diaspore, the SK number of the ore decreases. The deposits have been formed by hydrothermal processes by replacing the siliceous tuff and quartz porphyry. 4. Wan-Do Mine: Mineral compositions of the ores are chiefly pyrophyllite and quartz. But some ore contains a little amount of diaspore, kaolinite, pyrite, and chloritoid. The ores having high SK number of 36 consist chiefly of diaspore and pyrophyllite. Pyrophyllite ore has a SK number of 32 or lower. Amount of quartz and pyrite decreases the SK number of ores in this mine. Rhyolite was replaced by the action of hydrothermal solutions forming the pyrophyllite deposits.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.85-94
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• 2002

Overall objective of this study was to evaluate the electrochemical characteristics of fine soils during the electrokinetic(EK) remediation. Zeta potential of kaolinite as a function of solution pH and surfactant concentration was investigated to make a relationship with electroosmotic flow direction and rate. During the EK experiments, pH of pore solution, electroosmotic permeability($k_e$), electric conductivity($\delta_e$) and voltage distribution was measured, respectively, The point of zero charge(PZC) of kaolinite was estimated to be about 4.2 and the zeta potential of kaolinite above PZC was more negative as solution pH increased. Sorption of surfactants on the kaolinite altered the zeta potential of kaolinite. resulting from the variation of electrochemical characteristics of kaolinite surface. hs the EK experiment progressed, low pH was predominant over most of the kaolinite specimen and thus resulted in very low mass and charge flow. The $k_e$ and $\delta_e$ was also affected by the variation of voltage drop across the EK column with time. Results from this study implied that zeta potential of kaolinite affected by the pH variation of pore solution and voltage distribution in soil column played important role in the determination of mass and charge flow during EK process. It was also suggested that pH adjustment or addition of suitable sorbates could alter the electrochemical characteristics of soil surface and thus maintain high mass and charge flow rate with time.