• 한국분말재료학회지
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• 제18권4호
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• pp.332-339
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• 2011

Cemented tungsten carbide has been used in cutting tools and die materials, and is an important industrial material. When the particle size is reduced to ultrafine, the hardness and other mechanical properties are improved remarkably. Ultrafine cemented carbide with high toughness and hardness is now widely used. The objective of this study is synthesis of nanostructured WC-Co powders by liquid phase method of tungstate. The precursor powders were obtained by freezen-drying of aqueous solution of soluble salts, such as ammonium metatungstate, cobalt nitrate. the final compositions were WC-10Co. In the case of liquid phase method, it can be observed synthesis of WC-10Co. The properties of powder produced at various temperature, were estimated from the SEM, BET and C/S analyser.

• 한국정밀공학회지
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• 제19권3호
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• pp.80-87
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• 2002

Tungsten carbide microshaft is used as micro-punch, electrode of MEDM (micro-electro-discharge machining), and micro-tool because it has high hardness and high rigidity. In this study, the tungsten carbide microshaft was fabricated using electrochemical machining. Concentration of material removal at the sharp edge and metal corrosion layer affect the shape of the microshaft. Control of microshaft shape was possib1e through conditioning the machining voltage and electrolyte concentration. By applying periodic voltage, material removal rate increased and surface roughness improved. The fabricated microshaft in $H_2 SO_4$ electrolyte maintained sharper end edge and better surface finish than those fabricated by other electrolytes.

• 열처리공학회지
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• 제21권5호
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• pp.235-243
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• 2008

Ni-C composite films were prepared using a combination of microwave plasma CVD and ion beam sputtering deposition working in a codeposition way. The structure of these films was characterized by energy-dispersive X-ray diffraction (EDXRD), transmission electron microscopy (TEM) and Raman spectroscopy. It was found that a nickel carbide phase, $Ni_3C$ (hcp), formed as very fine crystallites over a wide temperature range when Ni-C films were deposited at low $CH_4$ flow rates. The thermal stability of this nonequilibrium carbide $Ni_3C$ was also studied. As a result, the $Ni_3C$ carbide was found to decompose into nickel and graphite at around $400^{\circ}C$. With high $CH_4$ flow rates (> 0.2 sccm), the structure of the Ni-C films became amorphous. The formation behavior of the carbide and amorphous Ni-C phases are discussed in relation to the electrical resistivity of the films.

• KSTLE International Journal
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• 제4권2호
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• pp.56-59
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• 2003

Boron carbide thin coatings were deposited on silicon wafers by DC magnetron sputtering using a ${B}_4$C target with Ar as processing gas. Various amounts of methane gas (${CH}_4$) were added in the deposition process to better understand their influence on tribological properties of the coatings. Reciprocating wear tests employing an oscillating friction wear tester were performed to investigate the tribological behaviors of the coatings in ambient environment. The chemical characteristics of the coatings and worn surfaces were studied using X-ray Photoelectron Spectroscopy (XPS) and Auger Electron Spectroscopy (AES). It revealed that ${CH}_4$addition to Ar processing gas strongly affected the tribologcal properties of sputtered boron carbide coating. The coefficient of friction was reduced approximately from 0.4 to 0.1, and wear resistance was improved considerably by increasing the ratio of ${CH}_4$gas component from 0 to 1.2 vol %. By adding a sufficient amount of ${CH}_4$(1.2 %) in the deposition process, the boron carbide coating exhibited lowest friction and highest wear resistance.

• 한국결정성장학회지
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• 제19권3호
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• pp.125-129
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• 2009

The preparation and characterization of niobium carbide crystallites were investigated in this study, and in particular, the effect of preparation conditions were studied on the synthesis of niobium carbides crystallites. For this purpose, various characterization techniques including x-ray diffraction, BET surface area, and oxygen uptake measurements were employed to characterize the synthesized niobium carbide crystallites. The niobium carbide crystallites were prepared using niobium oxide and methane gas or methane-hydrogen mixture. Using x-ray diffraction a lattice parameter of $4.45{\AA}$ and a crystallite size ranging from $52{\AA}$ to $580{\AA}$ was found. BET surface areas ranged from $3.2\;m^2/g$ to $16.6\;m^2/g$ and oxygen uptake values varied from $0.5{\mu}mol/g$ to $6.1{\mu}mol/g$. It was observed that niobium carbide crystallites were active for ammonia decomposition reaction. While the BET surface area increased with increasing the oxygen uptake, the conversion of ammonia decomposition reaction decreased. These results indicated that the ammonia decomposition over these materials was considered to be structure-sensitive.

• 한국입자에어로졸학회지
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• 제5권4호
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• pp.153-158
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• 2009

Tungsten carbide powder was fabricated with carbothermal reaction by pulsed electric current flowing in compact of tunsten oxide and carbon. The mixed powder of tunsten oxide and carbon was ball-milled into ultrafine powders. The mixed powder of tungsten oxide and carbon was put into carbon mold and heat-treated at $1050{\sim}1200^{\circ}C$ by pulsed electric current flowing. The formation of tungsten carbide powder could be achieved by heat treatment at $1200^{\circ}C$ for 10 minitues.

• 열처리공학회지
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• 제9권3호
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• pp.205-211
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• 1996

Structural studies have been performed on precipitation hardening discovered in $Ll_2$-ordered $Ni_3$(Al,Cr) containing 0.2 and 0.5 mol% of carbon in terms of transmission electron microscopy(TEM). By aging at temperatures around 1073 K after solution treatment at 1423 K, fine polyhedral precipitates appear firstly on the dislocations and then in the matrix. The selected area electron diffraction (SAED) studies revealed that these particles are a $M_{23}C_6$ type carbide which has the cube-cube orientation relationship with the matrix lattice. Weak-beam electron microscopy observations of deformation induced dislocations suggested that the dislocations bypass the carbide particles during deformation.

• 열처리공학회지
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• 제29권3호
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• pp.113-123
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• 2016

In the present work, we investigated the effects of the carbon potential on the formation of carbide at the carburized surface and anti-pitting fatigue strength in the supercarburized steels. Two low carbon steels with different Cr concentrations were adopted and the repeated supercarburizing treatment carried out with the different carbon potential conditions. The microstructure and carbides at the supercarburized surface were observed by using optical microscope and scanning electron microscope. The microhardness test was performed and the hardness distribution and the effective case depth at the supercarburized surface were discussed. The roller pitting fatigue test was carried out and the fatigue strength was evaluated with different the carbon potential conditions. The microstructure of the fatigue specimen surface was observed by means of scanning electron microscope and scanning transmission electron microscope. Depending on the chemical composition of the steels and the carbon potential condition, the resistance of temper softening and pitting failure was influenced due to the carbide distribution and the formation of coarse network carbide. Thus, it was confirmed that the control of the carbide formation is a key factor to improve the anti-pitting fatigue strength in the supercarburized steels.

• 산업기술연구
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• 제6권
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• pp.13-17
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• 1986

The effect of supersaturation on morphology of silicon carbide by chemical vapor deposition using $CH_3SiCl_3-H_2$ gas mixture system was investigated. The experimental results show that the final structure of silicon carbide deposits is coarser as total pressure increases or ${\alpha}$-ratio decreases. It is believed because supersataration of Si-source decreases as total pressure increases or ${\alpha}$-ratio decreases.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.357-357
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• 2006