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Vapor-Liquid Equilibria for the Systems of MTBE-Methanol, MTBE-n-Heptane, n-Heptane-Methanol by Using Head Space Gas Chromatography (Head Space Gas Chromatography를 이용한 MTBE-Methanol, MTBE-n-Heptane, n-Heptane-Methanol계의 기액평형)

  • Lee, Ju-Dong;Lee, Tae-Jong;Park, So-Jin
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.706-713
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    • 1994
  • Isothermal vapor-Liquid equilibrium data have been measured for binary systems MTBE-methanol, MTBE-n-heptane, and methanol-n-heptane at $45^{\circ}C$ and $65^{\circ}C$ by using head space gas chromato-graphy (H.S.G.C). Among these systems a minimum azeotrope was observed in both of MTBE-methanol system and n-heptane-methanol system. Particularly n-heptane-methanol system has a heterogeneous minimum azotrope since it has an immisible region. These equilibrium data were correlated with the excess Gibbs energy model, and the thermodynamic consistency test was also carried out by using Redlich-Kister equation.

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New Construction Scheme for Improving Contrast in Visual Cryptography (시각암호의 휘도 개선을 위한 새로운 구성법)

  • 양신석;김문수;박지환
    • Journal of Korea Multimedia Society
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    • v.4 no.2
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    • pp.136-144
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    • 2001
  • visual cryptography is a simple method in which secret information can be directly decoded in human visual system without any cryptographic computations. This scheme is a kind of secret sharing scheme in which secret of image type is distributed to n random image(we call it share). When the secret image is distributed to n shares, the original pixel is expanded as much as the size of column in basis matrix. It causes the deterioration of contrast in docoded secret image. Therefore, many researches have performed to reduce the size of pixel expansion and to improve the contrast by overlapping the row in basis matrix for (k, n) visual cryptography. In addition, we show that the proposed method can construct the (k, n) visual cryptography with multiple contrasts depending on selecting k out of n slides in a group.

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Comparison between Bi-superconducting Thin Films Fabricated by Co-Deposition and Layer-by-Layer Deposition

  • Yang, Sung-Ho;Park, Yong-Pil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.796-800
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    • 2000
  • Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{y}$(n$\geq$0; BSCCO) thin film is fabricated via two different processes using an ion beam sputtering method i.e. co-deposition and layer-by-layer deposition. A single phase of Bi2212 can be fabricated via the co-deposition process. While it cannot be obtained by the layer-by-layer process. Ultra-low growth rate in our ion beam sputtering system brings out the difference in Bi element adsorption between the two processes and results in only 30% adsorption against total incident Bi amount by layer-by-layer deposition, in contrast to enough Bi adsorption by co-deposition.on.n.

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Comparison between BSCCO Thin Films Fabricated by Co-Deposition and Layer-by-Layer Deposition

  • Lee, Hee-Kab;Park, Yong-Pil;Lee, Joon-Ung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.230-234
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    • 2000
  • Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{y}$(n$\geq$0; BSCCO)thin film is fabricated via two different processes using an ion beam sputtering method i.e. co-deposition and layer-by-layer deposition. A single phase of Bi2212 can be fabricated via the co-deposition process. While it cannot be obtained by the layer-by-layer process. Ultra-law growth rate in our ion beam sputtering system brings out the difference in Bi element adsorption between the two processes and results in only 30% adsorption against total incident Bi amount by layer-by-layer deposition, in contrast to enough Bi adsorption by co-deposition.on.n.

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Effects of Keonbodan (健步丹) on MIA-Induced Osteoarthritis in Rat (건보단(健步丹)이 MIA로 유도된 골관절염 Rat에 미치는 영향)

  • Lee, Eun-Jung;Oh, Min-Seok
    • Journal of Korean Medicine Rehabilitation
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    • v.24 no.2
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    • pp.51-64
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    • 2014
  • Objectives This study was carried out to know the effects of Keonbodan (hereinafter referred to KBD) in osteoarthritis induced by Monosodium iodoacetate(hereinafter referred to MIA) on Wistar rat. Methods Osteoarthritis was induced by injection of MIA into left knee joint cavities of rat. Osteoarthritis rats were divided into 4 groups (normal (n=6), control (n=6), indomethacin (n=6), KBD (n=6) group). The control group was administered normal saline and indomethacin group was administered indomethacin (2 mg/kg). And the KBD group was administered KBD (142 mg/kg). Each groups were administered by orally for 4 weeks. This experiment were carried out in vivo. In vivo, at the end of the experiment (5 weeks after MIA injection), effects on hepatotoxicity and nephrotoxicity, cytokines in serum, arachidonic acid, osteocalcin, MMP-9, TIMP-1 and cartilage volume were evaluated. And histopathological examinations on the articular structures of knee joints were performed. Results 1. In weight-bearing measurement, level of weight was increased. 2. In order to hepatotoxicity and nephrotoxicity, ALT, AST, BUN and creatinine were tested. And there were no significant changes. 3. In serum, levels of TNF-$\alpha$, IL-$1{\beta}$ were significantly decreased. IL-6 was insignificantly decreased. 4. In serum, level of MMP-9 and TIMP-1 was decreased. 5. In serum, level of $LTB_4$, $PGE_2$ and osteocalcin was decreased. 6. In ${\mu}$CT-arthrography, the cartilage volume was greater than that of the control group. 7. The joint damage induced by osteoarthritis was lesser than the control group in histopathologic observation (H&E, Safranin-O staining). Conclusions These results demonstrated that KBD suppressed the osteoarthritis- inducing effects of MIA in rat. And further studies are required to find out more effective substance and anti-osteoarthritic mechanism in the future.

Determination of $Mg^{2+}$ using 5-membered Heterocyclic Compound (5원자 헤테로고리 화합물을 이용한 $Mg^{2+}$의 정량)

  • Seo, Moo Lyong;Lee, Shim Sung;Kim, Jae Sang;Park, Tae Myung
    • Analytical Science and Technology
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    • v.6 no.3
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    • pp.307-311
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    • 1993
  • Ionophore, which contains 5-membered heterocyclic compound, was prepared. $Mg^{2+}$ was determined by salting-out technique using ionophore as a chelating reagent. After $Mg^{2+}$ was extracted into the acetonitrile layer as a Mg-$(Ionophore)_2$ complex from acetate buffered aqueous solution by salting-out extraction technique, absorbance of complex was recorded by atomic absorption spectrophotometry. Optimum pH was between 2.5 and 5.0 for extraction and 1:2([$Mg^{2+}$]/[ionophore]) complex were formed. The range of detection was 0.24ppm~2.4ppm and $Ca^{2+}$ and EDTA were interfered in the determination of $Mg^{2+}$.

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Dietary Self-Efficacy and Dietary Behaviors by Eating Areas according to Perceived Dietary Habit Levels related to Sodium Intake (나트륨 섭취 인지수준에 따른 식사 장소별 식행동 및 식이 자아효능감)

  • Yeon, Jee-Young;Kwon, Kwang-Il;Kim, Jong-Wook;Park, Hye-Kyung
    • The Korean Journal of Food And Nutrition
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    • v.30 no.1
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    • pp.166-174
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    • 2017
  • The purpose of this study was to compare dietary self-efficacy for sodium intake reduction and dietary behaviors by eating areas. Subjects (797 males and 767 females) were classified according to perceived dietary habit levels related to sodium intake (lowest: ${\leq}10$ (n=434), low: $11{\sim}{\leq}13$ (n=471), high: $14{\sim}{\leq}15$ (n=360), highest: $16{\leq}$ (n=299)) using an online survey with a sample that was geographically representative of the population. The highest group was significantly younger and had a higher student proportion than the lowest group. Dining contexts regarding home led to a significantly higher sodium intake in the highest group, but it was eating out for the lowest group. The highest group had a significantly lower intention to reduce sodium intake compared to the lowest group. In the home cooked meals, the highest group displayed a significantly lower cooking frequency, less effort with respect to a low sodium diet and cooking habits related to sodium intake as compared to the lowest group. Also, regarding eating out and food service, the highest group exhibited significantly lower efforts and dietary behaviors to reduce sodium intake than the lowest group. The dietary score for sodium reduction behavior in the highest group was significantly lower compared to the lowest group, for home cooked meals, eating out, as well as food service. Thus, dietary guidelines and nutrition education for the reduction of sodium intake by eating areas need to be developed and provided.

The Effect of Long-term Endurance training and Antioxidant Combined Vitamin Supplementation on blood Antioxidant Enzymes Activity, Lipid Peroxidation and Lipoprotein metabolism (장기간의 지구성 훈련시 항산화 Vitamin 복합 투여가 혈중 항산화 효소 활성도, 지질 과산화 및 지단백 대사에 미치는 영향)

  • Kim Yoo-Sub
    • The Journal of Korean Physical Therapy
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    • v.14 no.4
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    • pp.100-118
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    • 2002
  • This study was to investigate the effect of long-term high intensity endurance training on the activation of antioxidation enzyme activity, lipid peroxidation and lipoprotein metabolism. 15 subjects were divided into, endurance exercise + antioxidation Vitamin supplement(n=5), endurance exercise(n=5), and the control(n=5) groups. The endurance exercise groups(endurance exercise + antioxidation Vitamin supplement and endurance exercise) had 12 week of endurance exercise program. The antioxidation Vitamin supplement group was taken a Vitamin C tablet with 1000mg/day and Vitamin E tablet with 671.14mg/day right after lunch. The results obtained from this study were as follows; 1. Looking at the changes of SOD, Endurance exercise+antioxidation Vitamin supplement group and endurance exercise groups showed the significantly greater decrease in the activation of SOD after 12 weeks of all-out exercise. 2. Looking at the changes of CAT, Endurance exercise+antioxidation Vitamin supplement group revealed subjects tended to increase CAT after all-out exercise although statistically non-significant. Endurance exercise+antioxidation Vitamin supplement group showed the significantly greater increase in the activation of CAT after 12 weeks treatment for all-out exercise. 3. Looking at the changes of GPX, Endurance exercise+antioxidation Vitamin supplement group revealed subjects tended to increase GPX for the rest and after all-out exercise although statistically non-significant. Endurance exercise+antioxidation Vitamin supplement group showed the significantly greater increase in the activation of GPX after 12 weeks treatment for all-out exercise. 4. The MDA change showed the significant decrease after 6 weeks, after 12 weeks for the all-out exercise of Endurance exercise + antioxidation Vitamin supplement group. 5. There was non-significant change in lipoprotein metabolism for the rest and after all-out exercise.

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Evaluation of Creep Reduction Factor for Geosynthetic Strip Reinforcement with Folding Grooves (접힘홈이 형성된 띠형 섬유보강재의 크리프 감소계수 평가)

  • Lee, Kwang-Wu;Cho, Sam-Deok
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.4
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    • pp.213-224
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    • 2018
  • In this study, a series of accelerated creep tests (SIM) was carried out on geosynthetic strip reinforcements with folding grooves having different tensile strengths (15 kN, 25 kN, 35 kN, 50 kN, 70 kN, and 90 kN) to analyze creep characteristics and to assess creep reduction factors. In particular, long-term creep tests were conducted on geosynthetic strip reinforcements with 25 kN tensile strength, which is widely used, to compare and analyze the accelerated creep test results. As a result, the creep reduction factor increased with an increasing design life of reinforcement. In addition, geosynthetic strip reinforcement using the same material and manufacturing method showed similar creep reduction factors at the same design life for different tensile strengths. When both long-term and accelerated creep test data were used, the creep reduction factors from the accelerated test were estimated to be 5.9%~7.1% less than those from the long-term creep test for the design life ranging from 50 to 100 years.

Preparation of Zn-Doped GaN Film by HVPE Method (HVPE법에 의한 Zn-Doped GaN 박막 제조)

  • Kim, Hyang Sook;Hwang, Jin Soo;Chong, Paul Joe
    • Journal of the Korean Chemical Society
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    • v.40 no.3
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    • pp.167-172
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    • 1996
  • For the preparation of single-crystalline GaN film, heteroepitaxial growth on a sapphire substrate was carried out by halide vapor phase epitaxy(HVPE) method. The resulting GaN films showed n-type conductivity. The insulator type GaN film was made by doping with Zn(acceptor dopant), which showed emission peaks around 2.64 and 2.43 eV. The result of this study indicates that GaN can be obtained in an epitaxial structure of MIS(metal-insulator-semiconductor) junction. The observed data are regarded as fundamental in developing GaN epitaxial films for light emitting devices of hetero-structure type.

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