• Title/Summary/Keyword: isothermal model

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Automated reduced thermo-mathematical model generation method for satellite considering temperature tolerance and fixed nodes (온도 허용오차와 고정 노드를 고려한 자동화된 위성 축소 열모델 생성 방법)

  • Jimin Nam
    • Journal of Aerospace System Engineering
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    • v.17 no.2
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    • pp.9-15
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    • 2023
  • The task of generating a reduced thermal model of a satellite must be performed at least once in a satellite project to shorten the time of orbital thermal analysis and perform thermal analysis coupled to a launch vehicle. Although there are various methods for generating a reduced thermal model, an intuitive and convenient iso-thermal mesh generation method is used the most widely in practice. However, there is still a lack of research on automation of the isothermal mesh generation method. In this paper, we proposed an automated generation method of satellite reduced thermo-mathematical model based on the isothermal mesh generation method considering temperature tolerance and fixed nodes. The proposed method was validated using three different temperature tolerance cases. The average temperature difference satisfied the guidelines of ECSS.

Thermal Degradation and Cyclodepolymerization of Poly(ethylene terephthalate-co-isophthalate)s

  • Yoo, Dong Il;Shin, Younsook;Youk, Ji Ho
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.75-80
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    • 2001
  • The thermal degradation of poly(ethylene terephthalate-co-isophthalate)s (PETIs) is investigated by using isothermal thermogravimetric analysis at the temperature range of 280-31$0^{\circ}C$. The degradation rate of PETIs is increased as the mole ratio of ethylene isophthaloyl (EI) units in PETIs increases. The activation energies for the thermal degradation of poly(ethylene terephthalate), PETI(5/5), and poly(ethylene isophthalate) are 33.4, 16.6, and 8.9 kcal/mole, respectively. The degradation rate of PETIs is influenced by their volatile cyclic oligomer components formed during the polymerization and the thermal degradation. It is simulated by the rotational isomeric state model that the content of cyclic dimer in PETIs, which is the most volatile cyclic oligomer component, increases with the EI units in PETIs.

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Evaluation of Structure Development of Xanthan and Carob Bean Gum Mixture Using Non-Isothermal Kinetic Model

  • Yoon, Won-Byong;Gunasekaran, Sundaram
    • Food Science and Biotechnology
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    • v.16 no.6
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    • pp.954-957
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    • 2007
  • Gelation mechanism of xanthan-carob mixture (X/C) was investigated based on thermorheological behavior. Three X/C ratios (1:3, 1:1, and 3:1) were studied. Small amplitude oscillatory shear tests were performed to measure linear viscoelastic behavior during gelation. Temperature sweep ($-1^{\circ}C/min$) experiments were conducted. Using a non-isothermal kinetic model, activation energy (Ea) during gelation was calculated. At 1% total concentration, the Ea for xanthan fraction (${\phi}_x$)=0.25, 0.5, and 0.75 were 178, 159, and 123 kJ/mol, respectively. However, a discontinuity was observed in the activation energy plots. Based on this, two gelation mechanisms were presumed-association of xanthan and carob molecules and aggregation of polymer strands. The association process is the primary mechanism to form 3-D networks in the initial stage of gelation and the aggregation of polymer strands played a major role in the later stage.

A Thermodynamic Study on the Binding of Cobalt Ion with Myelin Basic Protein

  • Behbehani, G. Rezaei;Saboury, A.A.;Baghery, A. Fallah
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.736-740
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    • 2008
  • The interaction of myelin basic protein (MBP) from bovine central nervous system with divalent calcium ion was studied by isothermal titration calorimetry at 27 ${^{\circ}C}$ in aqueous solution. The extended solvation model was used to reproduce the enthalpies of $Co^{2+}$-MBP interaction over the whole $Co^{2+}$ concentrations. The solvation parameters recovered from the solvation model were attributed to the structural change of MBP due to the metal ion interaction. It was found that there is a set of three identical and noninteracting binding sites for $Co^{2+}$ ions. The association equilibrium constant is 0.015 ${\mu}M^{-1}$. The molar enthalpy of binding is $\Delta$H = −14.60 kJ $mol^{-1}$.

Equilibria and Dynamics of Toluene and Trichloroethylene onto Activated Carbon Fiber

  • Park, Jee-Won;Lee, Young-Whan;Choi, Dae-Ki;Lee, Sang-Soon
    • Clean Technology
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    • v.8 no.2
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    • pp.93-99
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    • 2002
  • Adsorption dynamics for toluene and trichloroethylene with an isothermal fixed bed of activated carbon fiber were investigated. Equilibrium isotherms were measured by a static method for toluene and trichloroethylene onto activated carbon fiber at temperatures of 298, 323, and 348 K and pressure up to 3 kPa for toluene and 6 kPa for trichloroethylene, respectively. These results were correlated by the Toth equation. And dynamic experiments in an isothermal condition of 298 K were examined. Breakthrough curves reflected the effects of the experimental variables such as partial pressures for adsorbate and interstitial bulk velocities of gas flow. To present the column dynamics, a dynamic model based on the linear driving force (LDF) mass transfer model was applied.

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A New Approach for Thermodynamic Study on the Binding of Human Serum Albumin with Cerium Chloride

  • Rezaei Behbehani, G.;Divsalar, A.;Saboury, A.A.;Faridbod, F.;Ganjali, M.R.
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1262-1266
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    • 2009
  • Thermodynamics of the interaction between Cerium (III) chloride, $Ce^{3+}$, with Human Serum Albumin, HSA, was investigated at pH 7.0 and $27\;{^{\circ}C}$ in phosphate buffer by isothermal titration calorimetry. Our recently solvation model was used to reproduce the enthalpies of HSA interaction by $Ce^{3+}$. The solvation parameters recovered from our new model, attributed to the structural change of HSA and its biological activity. The interaction of HSA with $Ce^{3+}$ showed a set of two binding sites with negative cooperativity. $Ce^{3+}$ interacts with multiple sites on HSA affecting its biochemical and biophysical properties.

Numerical simulation of non-isothermal flow in oil reservoirs using a two-equation model

  • dos Santos Heringer, Juan Diego;de Souza Debossam, Joao Gabriel;de Souza, Grazione;Souto, Helio Pedro Amaral
    • Coupled systems mechanics
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    • v.8 no.2
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    • pp.147-168
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    • 2019
  • This work aims to simulate three-dimensional heavy oil flow in a reservoir with heater-wells. Mass, momentum and energy balances, as well as correlations for rock and fluid properties, are used to obtain non-linear partial differential equations for the fluid pressure and temperature, and for the rock temperature. Heat transfer is simulated using a two-equation model that is more appropriate when fluid and rock have very different thermal properties, and we also perform comparisons between one- and two-equation models. The governing equations are discretized using the Finite Volume Method. For the numerical solution, we apply a linearization and an operator splitting. As a consequence, three algebraic subsystems of linearized equations are solved using the Conjugate Gradient Method. The results obtained show the suitability of the numerical method and the technical feasibility of heating the reservoir with static equipment.

Austenite Grain Growth Prediction Modeling of C-Mn-Mo-Ni Steel HAZ Considering Precipitates (C-Mn-Mo-Ni강 용접열영향부의 석출물을 고려한 오스테나이트 결정립 성장 거동 예측)

  • 서영대;엄상호;이창희;김주학;홍준화
    • Journal of Welding and Joining
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    • v.20 no.5
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    • pp.78-86
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    • 2002
  • A metallurgical model for the prediction of prior austenite grain size considering the dissolution kinetics of M$_3$C precipitates at the heat affected zone of SA508-cl.3 was proposed. The isothermal kinetics of grain growth and dissolution were respectively described by well-known equation, $dD/dT=M({\Delta}F_{eff})^M$ and Whelan's analytical model. The isothermal grain growth experiments were carried out for measure the kinetic parameters of grain growth. The precipitates of the base metal and the specimens exposed to thermal cycle were examined by TEM-carbon extraction replica method. The model was assessed by the comparison of BUE simulation experiments and showed good consistencies. However, there was no difference between the model considering and ignoring $M_3C$ precipitates. It seems considered that pinning force exerted by $M_3C$ Precipitates was lower than driving force for grain growth due to large size and small fraction of precipitates, and mobility of grain boundary was low in the lower temperature range.

A computational study on the removal of the non-isothermal concentrated fume from the semi-enclosed space

  • Chang, Hyuksang;Seo, Moonhyeok;Lee, Chanhyun
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.216-223
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    • 2017
  • For the prediction of the ventilation rate for removing the non-isothermal concentrated fume from the semi-enclosed space, the computational fluid dynamics (CFD) analysis was done. Securing the proper ventilation conditions in emergency state such as in fire is crucial factor for the protection of the resident in the space. In the analysis for the determining the proper ventilation rate, the experimental study had the limitation for simulating the versatile conditions of fume development. The theoretical and computational method had been chosen as the alternate tool for the experimental analysis. In this study, the CFD analysis was done on the defined model which already had been done the experimental analysis by the previous workers. By comparing the prediction on the plume heights and the ventilation rates by the CFD analysis at, and in the parametric model of $1m^3$ with those of the previous experimental works, the feasibility of the computational analysis was evaluated. For the required ventilation rate analyzed by the CFD analysis was over predicted in 7.1% difference with that of the experimental results depending on the different plume height. With the comparison with the analytical Zukoski model at, the CFD analysis on the ventilation was under predicted in 8.3%. By the verification of the feasibility of the CFD analysis, the extended analysis was done for getting the extra information such as the water vapor distribution and $CO^2$ distribution in the semi-enclosed spaces.