• Title/Summary/Keyword: isothermal

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Thermal Degradation and Cyclodepolymerization of Poly(ethylene terephthalate-co-isophthalate)s

  • Yoo, Dong Il;Shin, Younsook;Youk, Ji Ho
    • Fibers and Polymers
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    • v.2 no.2
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    • pp.75-80
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    • 2001
  • The thermal degradation of poly(ethylene terephthalate-co-isophthalate)s (PETIs) is investigated by using isothermal thermogravimetric analysis at the temperature range of 280-31$0^{\circ}C$. The degradation rate of PETIs is increased as the mole ratio of ethylene isophthaloyl (EI) units in PETIs increases. The activation energies for the thermal degradation of poly(ethylene terephthalate), PETI(5/5), and poly(ethylene isophthalate) are 33.4, 16.6, and 8.9 kcal/mole, respectively. The degradation rate of PETIs is influenced by their volatile cyclic oligomer components formed during the polymerization and the thermal degradation. It is simulated by the rotational isomeric state model that the content of cyclic dimer in PETIs, which is the most volatile cyclic oligomer component, increases with the EI units in PETIs.

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The statistics of isothermal turbulence in stratified medium

  • Lee, Hye-Sueng;Ryu, Dong-Su;Kim, Jong-Soo;Cho, Jung-Yeon
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.67.1-67.1
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    • 2010
  • Understanding the nature of MHD turbulence is of fundamental importance in astrophysics. The results of these studies can be used to develop the star formation theory. While most of previous studies have considered turbulence in uniform media, the stratification of media can play an important role. We performed three-dimensional numerical simulations of isothermal, compressible, MHD turbulence with different plasma beta's and different flow Mach numbers in stratified media to study the effects of stratification on turbulence. We found Statistics of turbulent flow in stratified media is different from in uniform media. In this talk, we present the statistical properties of the MHD turbulence, such as the PDF, power spectrum, and structure function.

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Evaluation of Grain Boundary Property in Oxide Ceramics by Isothermal Capacitance Trasient Spectroscopy (ICTS법을 이용한 산화물 세라믹스에서의 입계물성평가)

  • 김명철;한응학;강영석;박순자
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.529-537
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    • 1994
  • The principle of the Isothermal Capacitance Transient Spectroscopy[ICTS] were explained to measure the electronic trap levels in oxide ceramics. The measurement apparatus and the theory of the ICTS were described in detail. The trap energy evaluation was performed for the ZnO varistor and BaTiO3 ceramics. The grain boundary interface trap levels were detected at -5$0^{\circ}C$~6$0^{\circ}C$ in the case of ZnO varistor and PTCR samples, and the bulk trap levels were detected at 2$0^{\circ}C$~60~ in BaTiO3. The trap energy levels of the above samples could be directly determined by ICTS measurement.

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Dark Conductivity in Semi-Insulating Crystals of CdTe:Sn

  • Makhniy, V.P.;Sklyarchuk, V.M.;Vorobiev, Yu.V.;Horley, P.P.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.15 no.2
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    • pp.243-248
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    • 2015
  • We prepared semi-insulating CdTe for radiation detectors by isothermal annealing of single crystals grown by Bridgeman technique in a sealed quartz container filled with Sn vapor. The resistivity of CdTe:Sn samples thus obtained was of order of $10^{10}Ohm{\cdot}cm$ at room temperature with electrons lifetime of $2{\times}10^{-8}$ s, which is appropriate for the applications desired. Analysis of electric transport characteristics depending on temperature, sample thickness and voltage applied revealed the presence of traps with concentration of about $(4-5){\times}10^{12}cm^{-3}$ with the corresponding energy level at 0.8 - 0.9 eV counted from the bottom of conduction band. The conductivity was determined by electron injection from electrodes in space charge limited current mode.

A NOTE ON THE UNSTEADY FLOW OF DUSTY VISCOUS FLUID BETWEEN TWO PARALLEL PLATES

  • AJADI SURAJU OLUSEGUN
    • Journal of applied mathematics & informatics
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    • v.18 no.1_2
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    • pp.393-403
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    • 2005
  • We study the isothermal flow of a dusty viscous incompressible conducting fluid between two types of boundary motions- oscillatory and non-oscillatory, under the influence of gravitational force. Within the frame work of some physically realistic approximations and suitable boundary conditions, closed form solutions were obtained for the velocity profiles and the skin friction of the particulate flow. These results show that for a constant pressure gradient, only the velocity profile of the fluid and the skin friction are unaffected by gravity, while magnetic field is seen to affect both the fluid, particle velocities and the skin friction. Thus, our results are extension of previous results in literature, and graphical demonstration of some these solutions have been presented.

Elastic Moduli Determination of MgO Using Ultrasonic Interferometry (초음파 간섭법을 이용한 MgO 단결정의 체적탄성률 측정)

  • Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.13 no.3
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    • pp.138-146
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    • 2000
  • Using the ultrasonic interferometry on the single crystal MgO-periclase, adiabatic bulk moduli were determined to be 163.2 GPa and 162.6 GPa from (100) and (110) lattice plane measurements, respectively. Density was measured on polycrystalline MgO by the X-ray diffraction technique. Results from this study were compared with the previously reported values. Further, the present results were converted to the isothermal bulk moduli and, then compared with the published data available including the energy dispersive X-ray diffraction result which was performed on the same single crystal MgO. The principle and techniques ultrasonic interferometry were introduced too.

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Field Application of Power Cable Diagnosis System (전력케이블 열화진단기법의 현장적용)

  • Kim, Ju-Yong;Han, Jae-Hong;Song, Il-Keun;Kim, Sang-Jun;Lee, Jae-Bong;Oh, Jae-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.148-151
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    • 2002
  • In order to prevent the failures of underground distribution power cables we need to measure insulation condition in the field. Until now we used DC high voltage as a power source for the cable diagnosis but it was not proper method to the XLPE insulation cables because DC high voltage can affect sound insulation and can't diagnose exactly insulation degradation. For these reasons we imported isothermal relaxation current measurement system called by KDA-1 from germany but it's reliability did not proved in our URD cables. DC voltage decay measurement system was developed by domestic company but they don't have field experience. In this paper we tried to prove reliability of these two systems in the field. Through the field diagnosis and Ac breakdown test the two systems showed similar results.

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Microstructural Change in Rheocast AZ91D Magnesium Alloys with Stirring Rate and Isothermal Stirring Temperature (교반속도 및 등온교반온도에 따른 AZ91D 마그네슘합금 반응고 주조재의 미세조직 변화)

  • Yim, Chang-Dong;Shin, Kwang-Seon
    • Journal of Korea Foundry Society
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    • v.23 no.3
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    • pp.130-136
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    • 2003
  • Rheocasting of AZ91D magnesium alloys yielded the microstructure consisted of the spherical primary particles in the matrix which is different from conventional casting. Rheocast ingots were produced under various processing conditions using batch type rheocaster. Morphology of primary particles was changed from rosette-shape to spherical shape with increasing stirring rate$(V_s)$ and decreasing isothermal stirring temperature$(T_s)$. With increasing $V_s$, more effective shearing between the particles occurred rather than the agglomeration and clustering, so the primary particle size decreased. But with decreasing $T_s$, primary particle size increased mainly due to sintering and partially Ostwald ripening. The sphericity of primary particles increased with increasing $V_s$ and decreasing $T_s$ due to enhanced abrasion among the primary particles. The uniformity of primary particle size increased with increasing Vs and $T_s$.

Isothermal Age-hardening Behavior in the Commercial Dental Au-Ag-Cu-Pd Alloy (시판 치과용 Au-Ag-Cu-Pd 합금의 등온시효경화거동)

  • Kim, Hyung-Il;Jang, Myoung-Ik;Lee, You-Sik
    • Journal of Biomedical Engineering Research
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    • v.17 no.2
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    • pp.247-254
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    • 1996
  • The relationship between the isothermal age-hardening behavior and the phase transformation in the commercial dental Au-Ag-Cu-Pd alloy was investigated Age-hardening was mostly attributed to the lattice distortions of the supersaturated w phase resulting from the transformation to the metastable phasel which were more distinct at lower aging temperature. The lattice distortions resulting from the transformation of the metastable phases to the equilibrium phases also made a contribution to the age-hardening.

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A Study on the Precipitation of σ Phase in Super Duplex Stainless Steel (슈퍼 2상 스테인리스강의 σ상 석출에 관한 연구)

  • Gang, Chang-Yong;Klm, Ick-Soo
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.5
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    • pp.286-291
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    • 2001
  • This study was carried out to investigate the influence of ${\sigma}$ phase on the microstructure and mechanical properties in super duplex stainless steel. The precipitation of ${\sigma}$ phase during isothermal heat treatment showed the type S curves with a certain incubation period. The precipitation of ${\sigma}$ phase was precipitated at ferrite phase and interface of ferrite and austenite. Under the state of isothermal transformation, the precipitation of ${\sigma}$ phase was stimulated by applied stress. With increasing of volume fraction of precipitated ${\sigma}$ phase, tensile strength was increased and elongation was decreased with linear relationship, while in case of precipitated ${\sigma}$ phase was 5% over, impact value was rapidly decreased.

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