• Macromolecular Research
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• v.12 no.1
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• pp.1-10
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• 2004

The structural changes occurring in the isothermal crystallization processes of polyethylene (PE), poly-oxymethylene (POM), and vinylidene fluoridetrifluoroethylene (VDFTrFE) copolymer have been reviewed on the basis of our recent experimental data collected by the time-resolved measurements of synchrotron-sourced wide-angle (WAXS) and small-angle X-ray scatterings (SAXS) and infrared spectra. The temperature jump from the melt to a crystallization temperature could be measured at a cooling rate of 600-1,000 $^{\circ}C$/min, during which we collected the WAXS, SAXS, and infrared spectral data successfully at time intervals of ca. 10 sec. In the case of PE, the infrared spectral data clarified the generation of chain segments of partially disordered trans conformations immediately after the jump. These segments then became transformed into more-regular all-trans-zigzag forms, followed by the formation of an orthorhombic crystal lattice. At this stage, the generation of a stacked lamella structure having an 800-${\AA}$-long period was detected in the SAXS data. This structure was found to transfer successively to a more densely packed lamella structure having a 400-${\AA}$-long period as a result of the secondary crystallization of the amorphous region in-between the original lamellae. As for POM, the formation process of a stacked lamella structure was essentially the same as that mentioned above for PE, as evidenced from the analysis of SAXS and WAXS data. The observation of morphology-sensitive infrared bands revealed the evolution of fully extended helical chains after the generation of lamella having folded chain structures. We speculate that these extended chains exist as taut tie chains passing continuously through the neighboring lamellae. In the isothermal crystallization of VDFTrFE copolymer from the melt, a paraelectric high-temperature phase was detected at first and then it transferred into the ferroelectric low-temperature phase at a later stage. By analyzing the reflection profile of the WAXS data, the structural ordering in the high-temperature phase and the ferroelectric phase transition to the low-temperature phase of the multi-domain structure were traced successfully.

• Polymer(Korea)
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• v.36 no.4
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• pp.507-512
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• 2012

Thin (~650 nm) and ultrathin (~50 nm) films of neat PMMA and PMMA containing 5 wt% of methacryl-polyhedral oligomeric silsesquioxane were prepared in this work. The effects of film thickness and POSS on glass transition temperature ($T_g$) and isothermal physical aging were investigated by means of differential scanning calorimetry (DSC). $T_g$ depression was observed as film thickness was decreased and Ma-POSS molecules were incorporated. Enthalpy relaxation (${\Delta}H_{Relax}$) due to the isothermal physical aging was reduced by ultra-thin film thickness and the addition of Ma-POSS. KWW (Kohlrausch-Williams-Watts) equation was used to fit ${\Delta}H_{Relax}$ vs. aging time data providing the fitting parameters; maximum enthalpy recovery (${\Delta}H_{\infty}$), relaxation time (${\tau}$) and non-exponentiality parameter (${\beta}$).

• Transactions of the Korean Society of Automotive Engineers
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• v.24 no.5
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• pp.605-611
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• 2016

Mg alloy sheet exhibits significant differences in tensile and compressive yield stress depending on the temperature, as well as variations in its hardening behavior. Such unusual behavior makes it difficult to simulate the forming process of Mg alloy sheets. Results of analysis tend to deviate significantly from the experimental data because commercial software do not completely implement the unusual hardening behavior, yield asymmetry and temperature dependent changes in the Mg alloy's material properties. In the previous study, an in-plane tension-compression cyclic tester was developed to predict the cyclic behavior of Mg alloy sheets at an elevated temperature of up to $250^{\circ}C$. A new constitutive equation was suggested to analyze the unusual behavior, and was implemented in the commercial software in the form of user subroutine. In this paper, a stamping process of Mg seat cushion panel for automotive parts was simulated using the experimental data and user subroutine. Based on the analysis, an optimal temperature condition was determined and a stamping die shape at each step was suggested in the non-isothermal stamping of Mg alloy sheets.

• Macromolecular Research
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• v.11 no.1
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• pp.25-35
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• 2003

A series of random poly(ethylene-co-1,4-butylene terephthalate)s (PEBTs), as well as poly(ethylene terephthalate) (PET) and poly(1,4-butylene terephthalate) (PBT), were synthesized by the bulk polycondensation. Their composition, molecular weight, and thermal properties were determined. All the copolymers are crystallizable, regardless of the compositions, which may originate from both even-atomic-numbered ethylene terephthalate and butylenes terephthalate units that undergo inherently crystallization. Non-isothermal crystallization exotherms were measured over the cooling rate of 2.5-20.0 K/min by calorimetry and then analyzed reasonably by the modified Avrami method rather than the Ozawa method. The results suggest that the primary crystallizations in the copolymers and the homopolymers follow a heterogeneous nucleation and spherulitic growth mechanism. However, when the cooling rate increases and the content of comonomer unit (ethylene glycol or 1,4-butylene glycol) increases, the crystallization behavior still becomes deviated slightly from the prediction of the modified Avrami analysis, which is due to the involvement of secondary crystallization and the formation of relatively low crystallinity. Overall, the crystallization rate is accelerated by increasing cooling rate but still depended on the composition. In addition, the activation energy in the non-isothermal crystallization was estimated.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.24-33
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• 2016

The grafting reaction for maleic anhydride (MA) onto high density polyethylene (HDPE) was investigated from solution process with initiators. The chemical modification of neat HDPE was carried out with various contents of MA (3-21 wt.%) and initiator (0.2-1 wt.%) at different temperature ($80-130^{\circ}C$). The grafting degree was obtained from the titration and the highest grafting degree was 3.1%. The grafting degree increased as the content of MA and initiator increased, however, the highest grafting degree was demonstrated for a particular content of MA and initiator. In the non-isothermal crystallization kinetics, the Ozawa model was unsuitable method to investigate the crystallization behavior of MA onto HDPE, whereas the Avrami and Liu models found effective. The crystallization rate was accelerated as the cooling rate increased, but postponed by combination of MA onto neat HDPE backbone.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.2
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• pp.373-380
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• 1988

The effect of sound on the heat transfer from an isothermal cylinder in cross flow is investigated by numerical analysis. The modeling is made for the laminar incompressible flow fluctuating in the range of the Reynolds number, 5.leq.Re.leq.35, by the sinusoidal acoustic field. The instantaneous response of the flow and heat transfer is simulated for various frequencies. It is shown that the heat transfer amplitude decreases and the phase lags behind the flow velocity with increase in the frequency. The time-mean effects of the acoustic field on the flow field and heat transfer, known as the acoustic and thermoacoustic streaming, are analyzed. The time-mean heat transfer coefficients are decreased around the forward stagnation point but increased in the wake region. Such a local difference in heat transfer coefficients is a function of the frequency and becomes greatest at some frequency. However, with balance between the local increase and decrease, the overall heat transfer coefficient is almost unaffected by sound.

• Journal of the Korean Ceramic Society
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• v.43 no.2 s.285
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• pp.69-73
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• 2006

A full retention of the tetragonal phase with coarse grains $(50\~60\;{\mu}m)$ was possible with the specimen $ZrO_2-1.9\;mol\%\;Y_2O_3$. In these coarse grains, $\{101\}_t$ annealing twins were frequently observed, although they do not exist in the usual fine grained specimens. The morphology and growth rate of the isothermally formed individual products are studied at an optical microscopic level. The habit planes of both products are also identified by performing two-surface trace analysis on the grains whose orientations are determined by the Electron Back Scattering Pattern (EBSP) method. The morphologies of isothermal martensite were well-defined thin plates and lenticular types. The growth rate in their longitudinal directions was quite slow and temperature-dependent. A two-surface trace analysis, incorporated with the EBSP method, identified the habit planes near $\{013\}_c$, in agreement with previous reports obtained from TEM works.

• Journal of the Korean Society for Heat Treatment
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• v.33 no.4
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• pp.173-179
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• 2020

The purpose of this study was to investigate comparatively the microstructural characteristics and hardness of discontinuous precipitates (DPs) in Mg-9%Al alloy, which were formed by continuous cooling (CC) from 678 K to RT and isothermal aging (IA) at 413 K, respectively. In as-cast state, the Mg-9%Al alloy consisted of partially divorced eutectic β(Mg₁₇Al₁₂) particles with a small amount of DPs showing (α+β) lamellar morphology adjacent to the β particles. The DPs formed by CC had interlamellar spacings in a broad range of 0.85~2.12 ㎛ (1.51 ㎛ in average) owing to the various formation temperatures in response to continuous cooling process. Meanwhile, the DPs formed by IA had relatively narrower interlamellar spacings of 0.14~0.29 ㎛ (0.21 ㎛ in average), which is associated with the low and constant formation temperature. Thinner and higher volume fraction of β phase layers were noticeable in the DPs formed by IA. Higher hardness values were obtained in the DPs formed by IA than the DPs formed by CC, which may well be ascribed to the finer lamellar structure and higher β phase content of the DPs formed by IA.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.1
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• pp.66-73
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• 2010

This work was focused on the material parameter extraction for the isothermal cyclic deformation analysis for which Chaboche(Combined Nonlinear Isotropic and Kinematic Hardening) and Overlay(Multi Linear Hardening) models are normally used. In this study all the parameters were driven especially based on Overlay theories. A simple method is suggested to find out best material parameters for the cyclic deformation analysis prior to the isothermal LCF(Low Cycle Fatigue) analysis. The parameter extraction was done using 400 series stainless steel data which were published in the reference papers. For simple and quick review of the parameters extracted by suggested method, 1D FORTRAN program was developed, and this program could reduce the time for checking the material data tremendously. For the application to FE code ABAQUS user subroutine for the material models was developed by means of UMAT(User Material Subroutine), and the stabilized hysteresis loops obtained by the numerical analysis were in good harmony with test results.

• Korea-Australia Rheology Journal
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• v.19 no.4
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• pp.201-209
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• 2007

The present paper is concerned with non-isothermal spherical Couette flow of Oldroyd-B fluid in the annular region between two concentric spheres. The inner sphere rotates with a uniform angular velocity while the outer sphere is kept at rest. Moreover, the two spherical boundaries are maintained at fixed temperature values. Hence, the fluid is effect by two heat sources; namely, the viscous heating and the temperature gradient between the two spheres. The viscoelasticity of the fluid is assumed to dominate the inertia such that the latter can be neglected. An approximate analytical solution of the energy and momentum equations is obtained through the expansion of the dynamical fields in power series of Nahme number. The analysis show that, the temperature variation due to the external source appears in the zero order solution and its effect extends to the fluid velocity distribution up to present second order. Viscous heating contributes in the first and second order solutions. In contrast to isothermal case, a first order axial velocity and a second order stream function fields has been appeared. Moreover, at higher orders the temperature distribution depends on the gap width between the two spheres. Finally, there exist a thermal distribution of positive and negative values depend on their positions in the domain region between the two spheres.